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Mechanism of a simultaneous metal-insulator and spin-state transition in Pr-Ca-Co-O system

Research Project

Project/Area Number 24540355
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionIwate University

Principal Investigator

Naito Tomoyuki  岩手大学, 工学部, 准教授 (40311683)

Co-Investigator(Kenkyū-buntansha) 藤代 博之  岩手大学, 工学部, 教授 (90199315)
Co-Investigator(Renkei-kenkyūsha) FUJISHIRO HIROYUKI  岩手大学, 工学部, 教授 (90199315)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywordsコバルト酸化物 / 金属絶縁体転移 / スピン状態転移 / 磁場効果 / 金属・絶縁体転移 / X線吸収分光
Outline of Final Research Achievements

A spin-state (SS) transition of trivalent Co ion occurs simultaneously metal-insulator (MI) transition in Pr-Ca-Co-O system. The motivation of this study is to clarify the mechanism of this MI-SS transition. The obtained important results are listed below. 1) the valence change of Pr ion from 3+ to 4+ on cooling, which was observed by the X-ray absorption spectroscopy at SPring-8, induced the transition. In addition, the valence of Tb ion also changed at the transition. 2) The MI-SS transition was fully suppressed by a strong magnetic field, in which the valence change of Pr ion was induced by the magnetic field.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (24 results)

All 2016 2015 2014 2013 2012 Other

All Int'l Joint Research (1 results) Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (15 results) (of which Int'l Joint Research: 1 results) Remarks (2 results)

  • [Int'l Joint Research] チェコ科学アカデミー(チェコ)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Electrical resistivity anomaly in (Pr1-yMy)1-xCaxCoO3 epitaxial films (M=Y, Gd) fabricated by pulsed laser deposition2016

    • Author(s)
      Y. Noda, H. Fujishiro, T. Naito, A. Ito, T. Goto, J. Hejtmanek, Z. Jirak
    • Journal Title

      AIP Advances

      Volume: 6 Issue: 2

    • DOI

      10.1063/1.4942558

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Magnetic-field-induced insulator-metal transition in (Pr1-yYy)0.7Ca0.3CoO3 at ultrahigh magnetic fields2015

    • Author(s)
      S. Lee, Y-H. Matsuda, T. Naito, D. Nakamura, S. Takeyama
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 84 Issue: 4 Pages: 044703-044703

    • DOI

      10.7566/jpsj.84.044703

    • NAID

      210000133517

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Suppression of the metal-insulator transition by magnetic field in (Pr1-yYy)0.7Ca0.3CoO3 (y = 0.0625)2014

    • Author(s)
      T. Naito, H. Fujishiro, T. Nishizaki, N. Kobayashi, J. Hejtmanek, K. Knizek, Z. Jirak
    • Journal Title

      Journal of Applied Physics

      Volume: 115 Issue: 23

    • DOI

      10.1063/1.4884435

    • NAID

      120005478503

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Simultaneous valence shift of Pr and Tb ions at the spin-state transition in (Pr1-yTby)0.7Ca0.3CoO32013

    • Author(s)
      H. Fujishiro, T. Naito, D. Takeda, N. Yoshida, T. Watanabe, K. Nitta, J. Hejtmanek, K. Knizek, and Z. Jirak
    • Journal Title

      Physical Review B

      Volume: 87 Issue: 15

    • DOI

      10.1103/physrevb.87.155153

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Spin-state crossover and low-temperature magnetic state in yttrium-doped Pr0.7Ca0.3CoO32013

    • Author(s)
      K. Knizek, J. Hejtmanek, M. Marysko, P. Novak, E. Santava, Z. Jirak, T. Naito, H. Fujishiro, and Clarina de la Cruz
    • Journal Title

      Physical Review B

      Volume: 88 Issue: 22

    • DOI

      10.1103/physrevb.88.224412

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Valence shift of Pr ion from 3+ to 4+ in (Pr1-yYy)0.7Ca0.3CoO3 estimated by X-ray absorption spectroscopy2012

    • Author(s)
      H. Fujishiro, T. Naito, S. Ogawa, N. Yoshida, K. Nitta, J. Hejtmanek, K. Knizek, Z. Jirak
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 81 Issue: 6 Pages: 064709-064709

    • DOI

      10.1143/jpsj.81.064709

    • NAID

      210000109574

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Epitaxial growth of (Pr1-yYy)1-xCaxCoO3 films by pulsed laser deposition2015

    • Author(s)
      Y. Noda, H. Fujishiro, T. Naito, A. Ito, T. Goto
    • Organizer
      14th International Union of Materials Research Societies-International Conference on Advanced Materials
    • Place of Presentation
      International Convention Center, Jeju, Korea
    • Year and Date
      2015-10-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 140テスラまでの超強磁場磁化測定による(Pr1-yYy)0.7Ca0.3CoO3 (y=0.075, 0.1)の磁場誘起スピン転移の観測と温度依存性2015

    • Author(s)
      池田暁彦,李受妍,松田康弘,嶽山正二郎,金道浩一,内藤智之
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Year and Date
      2015-09-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pr-Ca-Co-O系の磁場中金属・絶縁体-スピン状態転移とPr価数変化2015

    • Author(s)
      内藤智之,藤代博之,河村直己,水牧仁一朗,J. Hejtmanek,K. Knizek,Z. Jirak
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学早稲田キャンパス
    • Year and Date
      2015-03-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 金属絶縁体-スピン状態同時転移を生じる (Pr1-yYy)1-xCaxCoO3系物質の単結晶薄膜化と物性評価2015

    • Author(s)
      野田裕介,内藤智之,藤代博之,伊藤暁彦,後藤孝
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学早稲田キャンパス
    • Year and Date
      2015-03-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Magnetic-field driven Pr-valence change at simultaneous metal-insulator and spin-state transition in (Pr1-yREy)1-xCaxCoO3 (RE=rare earth elements)2014

    • Author(s)
      T. Naito, D. Takeda, T. Watanabe, H. Fujishiro, N. Kawamura, M. Mizumaki, J. Hejtmanek,K. Knizek,Z. Jirak
    • Organizer
      59th Conference on Magnetism and Magnetic Materials
    • Place of Presentation
      Hilton Hawaiian Village Conference Center
    • Year and Date
      2014-11-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Pr-Ca-Co-O系の金属・絶縁体-スピン状態転移への磁場効果2014

    • Author(s)
      内藤智之,藤代博之,西嵜照和,小林典男,J. Hejtmanek,K. Knizek,Z. Jirak
    • Organizer
      2014年第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス
    • Year and Date
      2014-09-17
    • Related Report
      2014 Research-status Report
  • [Presentation] (Pr1-yYy)1-xCaxCoO3における磁場誘起Pr価数変化と金属・絶縁体-スピン状態転移2014

    • Author(s)
      内藤智之,武田大輝,藤代博之,寺島拓,松田康弘,木原工,徳永将史,稲見俊哉
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学湘南キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 超強磁場における(Pr1-yYy)0.7Ca0.3CoO3の磁場誘起 絶縁体金属転移2014

    • Author(s)
      イスヨン,松田康弘,中村大輔,嶽山正二郎,内藤智之
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学湘南キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] (Pr1-yREy)1-xCaxCoO3(RE:希土類元素)の金属・絶縁体-スピン状態転移に対するCoサイト置換効果2013

    • Author(s)
      内藤智之,武田大輝,渡辺卓真,藤代博之,新田清文
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] (Pr, RE)-Ca-Co-O系酸化物の金属‐絶縁体転移における(Pr, RE)イオンの価数と熱伝導率、音速の変化2013

    • Author(s)
      武田大輝,内藤智之,藤代博之,新田清文
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Metal-insulator and spin-state transition in polycrystalline (Pr1-yREy)1-xCaxCoO3(RE: rare earth elements) in magnetic fields)2013

    • Author(s)
      T. Naito, H. Fujishiro, T. Nishizaki, N. Kobayashi, J. Hejtmanek, K Knizek, and Z. Jirak
    • Organizer
      The 58th Annual Magnetism and Magnetic Materials (MMM) Conference
    • Place of Presentation
      Sheraton Denver
    • Related Report
      2013 Research-status Report
  • [Presentation] (Pr, RE)-Ca-Co-O系酸化物の金属-絶縁体転移におけるPrサイトへのRE置換効果2013

    • Author(s)
      武田大輝,内藤智之,藤代博之,新田清文
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学東広島キャンパス(広島県)
    • Related Report
      2012 Research-status Report
  • [Presentation] Pr-Ca-Co-O系酸化物のMI転移におけるCo吸収端変化2012

    • Author(s)
      藤代博之,内藤智之,武田大輝,渡辺卓真,吉田直樹,新田清文
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学常盤台キャンパス(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] (Pr, Tb)-Ca-Co-O系酸化物の金属-絶縁体転移におけるPr, Tbイオンの価数シフト2012

    • Author(s)
      武田大輝,内藤智之,渡辺卓真,吉田直樹,藤代博之,新田清文
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学常盤台キャンパス(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] (Pr1-yYy)1-xCaxCoO3の磁場中金属・絶縁体-スピン状態転移II2012

    • Author(s)
      内藤智之,藤代博之,西嵜照和,徳永将史
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学常盤台キャンパス(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Remarks] 藤代研HPフレーム

    • URL

      http://ikebehp.mat.iwate-u.ac.jp/

    • Related Report
      2013 Research-status Report
  • [Remarks] 藤代研HPフレーム

    • URL

      http://ikebehp.mat.iwate-u.ac.jp/

    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2022-02-21  

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