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STM/STS and break-junction tunneling spectroscopy of layered nitro-chloride superconductors

Research Project

Project/Area Number 24540377
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionHiroshima University

Principal Investigator

EKINO Toshikazu  広島大学, 総合科学研究科, 教授 (40185103)

Research Collaborator SUGIMOTO Akira  広島大学, 大学院総合科学研究科, 助教
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords層状窒化物 / 高温超伝導 / STM/STS / Break-Junction tunneling / ナノスケール電子状態 / エネルギーギャップ / 非従来型超伝導機構 / Tunneling spectroscopy / 走査トンネル顕微鏡/分光 / 鉄系超伝導 / 超伝導 / トンネル分光 / STM/STS / 破断接合 / 鉄系超伝導物質 / 層状超伝導 / ZrNCl / FeSe / 超伝導エネルギーギャップ
Outline of Final Research Achievements

We investigated the electronic properties of the layered nitro-chloride superconductors by means of low-temperature ultra-high-vacuum scanning microscopy/spectroscopy (STM/STS) and break-junction tunneling spectroscopy (BJTS) with clean surface conditions. The STM measurements clarified the electronic inhomogeneity in sub-nanometer scale of the crystal surface. The averaged-superconducting gap values, which are much larger than the BCS prediction, were found to be independent of the critical temperatures Tc. From a series of the experiments, it is pointed out that the possible enhancement of Tc above 30 K should occur when the electronic inhomogeneity of the sample is being suppressed. Both the inhomogeneity and the huge magnitude of the gap size confirmed in the present research resemble those of the high-Tc cuprates except for the gap symmetry which can be described by the conventional picture in the nitro-chloride superconductors.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (42 results)

All 2015 2014 2013 2012 Other

All Journal Article (18 results) (of which Peer Reviewed: 18 results,  Acknowledgement Compliant: 5 results,  Open Access: 1 results) Presentation (19 results) (of which Invited: 2 results) Book (2 results) Remarks (3 results)

  • [Journal Article] Break-junction tunneling spectroscopy of superconducting FeSexTe1-x2015

    • Author(s)
      T. Ekino, K. Nagasaka. Y. Sakai, A. Sugimoto, A.M. Gabovich
    • Journal Title

      Physics Procedia

      Volume: オンライン準備中 Pages: 65-68

    • DOI

      10.1016/j.phpro.2015.05.123

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] The spatial distributions of large gap-like structure on Fe(Se,Te) single crystals observed by STM/STS2015

    • Author(s)
      A. Sugimoto, Y. Sakai, K. Nagasaka, T. Ekino
    • Journal Title

      Physica C

      Volume: 印刷中 Pages: 23-27

    • DOI

      10.1016/j.physc.2015.04.007

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Observation of the gap distribution on multi-layered cuprate superconductor Ba2Ca4Cu5O10(O1-xFx)2 by STM/STS2014

    • Author(s)
      A. Sugimoto, T. Ekino, K. Tanaka, K. Mineta, K. Tanabe, K. Tokiwa
    • Journal Title

      Physics Procedia

      Volume: 58 Pages: 78-81

    • DOI

      10.1016/j.phpro.2014.09.023

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dynamics and mechanism of oxygen annealing in Fe1+yTe0.6Se0.4 single crystal2014

    • Author(s)
      Y. Sun, Y. Tsuchiya, T. Taen, T. Yamada, S. Pyon, A. Sugimoto, T. Ekino, Z.Shi, T. Tamegai
    • Journal Title

      Scientific reports

      Volume: 4 Issue: 1

    • DOI

      10.1038/srep04585

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Tunneling STM/STS and break-junction spectroscopy of the layered nitro-chloride superconductors MNCl (M = Ti, Hf, Zr)2014

    • Author(s)
      T. Ekino, A. Sugimoto, A.M. Gabovich, Z. Zheng, S. Zhang, S. Yamanaka
    • Journal Title

      Journal of Physics Conference Series

      Volume: 507 Issue: 1 Pages: 012010-012010

    • DOI

      10.1088/1742-6596/507/1/012010

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Variable electronic stripe structures of the parent iron-chalcogenide superconductor Fe1+dTe observed by STM-STS2014

    • Author(s)
      A. Sugimoto T. Ekino, A. M. Gabovich
    • Journal Title

      Physical Review B

      Volume: 90 Issue: 22

    • DOI

      10.1103/physrevb.90.224503

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Observation of the gap distribution on multi-layered cuprate superconductor Ba2Ca4Cu5O10(O1-x, Fx)2 by STM/STS2014

    • Author(s)
      A. Sugimoto, T. Ekino, K. Tanaka, K. Mineta, K. Tanabe, K. Tokiwa
    • Journal Title

      Physics Procedia

      Volume: (印刷中)

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] STM/STS and break-junction tunneling spectroscopy of FeSe1-xTex2013

    • Author(s)
      T. Ekino, A. Sugimoto, A.M. Gabovich
    • Journal Title

      Low Temperature Physics

      Volume: 39 Issue: 3 Pages: 343-353

    • DOI

      10.1063/1.4795173

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Scanning tunnelling spectroscopy of superconducting β-ZrNClx2013

    • Author(s)
      T. Ekino, A. Sugimoto, A.M. Gabovich, Z. Zheng, S. Yamanaka
    • Journal Title

      Physica C

      Volume: 494 Pages: 89-94

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Tunneling break-junction measurements of the superconducting gap in Y2C32013

    • Author(s)
      T. Ekino, A. Sugimoto, A.M. Gabovich, H. Kinoshita, J. Akimitsu
    • Journal Title

      Physica C

      Volume: 484 Pages: 52-55

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Scanning-tunneling microscopy and break-junction spectroscopy on the superconducting Fe (Se,Te) single crystal2013

    • Author(s)
      R. Ukita, A. Sugimoto, T. Ekino
    • Journal Title

      Physica C

      Volume: 484 Pages: 22-26

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Nano-scale stripe structures on FeTe Observed by low-temperature STM/STS2013

    • Author(s)
      A. Sugimoto, R. Ukita, T. Ekino
    • Journal Title

      Physics Procedia

      Volume: 45 Pages: 85-88

    • DOI

      10.1016/j.phpro.2013.04.058

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Scanning-tunneling microscopy/spectroscopy and break-junction tunneling spectroscopy of FeSe1-xTex2013

    • Author(s)
      T. Ekino, A. Sugimoto, A. M. Gabovich
    • Journal Title

      Low Temperature Physics

      Volume: 39 Pages: 343-353

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Tunneling Break-Junction Measurements of the Superconducting Gap in Y2C32013

    • Author(s)
      Toshikazu Ekino, Hiroyuki Kinoshita, Akutagawa, Akira Sugimoto, and Jun Akimitsu
    • Journal Title

      Physica C

      Volume: 484 Pages: 53-56

    • DOI

      10.1016/j.physc.2012.03.044

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Scanning-tunneling microscopy and break-junction spectroscopy on the superconducting Fe(Se,Te) single crystal2013

    • Author(s)
      Ryuichi Ukita, Akira Sugimoto, Toshikazu Ekino
    • Journal Title

      Physica C

      Volume: 484 Pages: 22-26

    • DOI

      10.1016/j.physc.2012.03.034

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Superconducting beta-ZrNClx probed by scanning-tunnelling and break-junction spectroscopy2013

    • Author(s)
      Toshikazu Ekino, Akira Sugimoto, Alexander M. Gabovich, Zhanfeng Zheng, Shoji Yamanaka
    • Journal Title

      Physica C

      Volume: 未

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Nano-scale stripe structures on FeTe Observed by low-temperature STM/STS2013

    • Author(s)
      Akira Sugimoto, Ryuichi Ukita, Toshikazu Ekino
    • Journal Title

      Physics Procedia

      Volume: 未

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] STM/STS Observation on Layered Nitride Superconductor alpha-(DDA)x TiNCl2012

    • Author(s)
      Akira Sugimoto, Ryuichi Ukita, Toshikazu Ekino, Zhanfeng Zheng and Shoji Yamanaka
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 400 Issue: 2 Pages: 022112-022112

    • DOI

      10.1088/1742-6596/400/2/022112

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Tunnelling measurements of Nb3Sn break junctions below and above the superconducting critical temperature2015

    • Author(s)
      T. Ekino
    • Organizer
      4th International Symposium on Energy Challenges and Mechanics-working on small scales
    • Place of Presentation
      Aberdeen, Scotland, United Kingdom
    • Year and Date
      2015-08-11 – 2015-08-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Break-junction tunnelling spectroscopy of superconducting FeSexTe1-x (x = 0.4-0.5) with our STM/STS results2014

    • Author(s)
      T. Ekino, A. Sugimoto, Y. Sakai, K. Nagasaka, A.M. Gabovich
    • Organizer
      ISS2014 国際超電導シンポジウム
    • Place of Presentation
      船堀タワーホール、東京
    • Year and Date
      2014-11-25 – 2014-11-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] The spatial distributions of large pseudo gap on Fe(Se,Te) single crystals observed by STM/STS2014

    • Author(s)
      A. Sugimoto, Y. Sakai, K. Nagasaka, T. Ekino
    • Organizer
      ISS2014 国際超電導シンポジウム
    • Place of Presentation
      船堀タワーホール、東京
    • Year and Date
      2014-11-25 – 2014-11-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 層状窒化物超伝導体NaxTiNClの電子状態密度の観測2014

    • Author(s)
      坂井優太、杉本暁、Shuai Zhang、田中将嗣、Haikui Zhu、 山中昭司、浴野稔一
    • Organizer
      2014年度物理学会秋季大会
    • Place of Presentation
      中部大学 春日井キャンパス
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] STM-STSによる鉄カルコゲナイド 超伝導体FeSexTe1-xにおける過剰鉄 スポット形状と電子状態の観測2014

    • Author(s)
      杉本 暁, 坂井優太, 浴野稔一
    • Organizer
      2014年度物理学会秋季大会
    • Place of Presentation
      中部大学 春日井キャンパス
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] STS/STM of the layered iron-chalcogenide and nitro-chloride superconductors2014

    • Author(s)
      T. Ekino
    • Organizer
      AnalytiX-2014
    • Place of Presentation
      Dalian international convention center, Dalian, China
    • Year and Date
      2014-04-25 – 2014-04-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Superconducting gap of b-HfNCl and related compounds investigated by scanning tunneling microscopy/spectroscopy and break-junction tunneling2013

    • Author(s)
      Toshikazu EKINO
    • Organizer
      International conference on Nanoscience and technology
    • Place of Presentation
      パリ国際会議場(フランス)
    • Related Report
      2013 Research-status Report
  • [Presentation] Tunneling STM/STS and break junction spectroscopy of the layered superconductors b-MNClx (M = Hf or Zr)2013

    • Author(s)
      Toshikazu EKINO
    • Organizer
      European Conference on Applied Superconductivity
    • Place of Presentation
      ジェノバ国際会議場(イタリア)
    • Related Report
      2013 Research-status Report
  • [Presentation] Superconducting gap of beta-HfNCl investigated by scanning tunneling microscopy/spectroscopy and break-junction tunneling2013

    • Author(s)
      Toshikazu Ekino
    • Organizer
      International Conference on Nanoscience and Nanotechnology 2013
    • Place of Presentation
      Paris Palais des Congres、パリ、フランス
    • Related Report
      2012 Research-status Report
  • [Presentation] Tunneling STM/STS and break junction spectroscopy of the layered superconductors β-MNClx (M = Hf or Zr)2013

    • Author(s)
      Toshikazu Ekino
    • Organizer
      European Conference on Applied Superconductivity 2013
    • Place of Presentation
      Magazzini del Cotone、ジェノヴァ、イタリア
    • Related Report
      2012 Research-status Report
  • [Presentation] 鉄カルコゲナイド超伝導体及びその母物質 における局所状態密度の変調構造(2)2013

    • Author(s)
      杉本 暁、浴野稔一
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Superconducting beta-ZrNClx probed by scanning-tunnelling and break-junction spectroscopy2012

    • Author(s)
      Toshikazu Ekino
    • Organizer
      International Symposium on Superconductivity(ISS) 2012
    • Place of Presentation
      タワーホール船堀、東京
    • Related Report
      2012 Research-status Report
  • [Presentation] 鉄カルコゲナイド超伝導体及びその母物質 における局所状態密度の変調構造2012

    • Author(s)
      杉本 暁、浴野稔一
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Research-status Report
  • [Presentation] STM, scanning and break-junction spectroscopy of Fe(X(=Se, S), Te)2012

    • Author(s)
      Toshikazu Ekino
    • Organizer
      International Conference on Nanoscience and Nanotechnology 2012
    • Place of Presentation
      Universite Paris-Sorbonne, パリ
    • Related Report
      2012 Research-status Report
  • [Presentation] STM/STS and break junction tunneling spectroscopy of the layered nitro-chloride superconductors

    • Author(s)
      Toshikazu EKINO
    • Organizer
      International workshop on Novel superconductors and super materials
    • Place of Presentation
      品川グランドセントラルタワー
    • Related Report
      2013 Research-status Report
  • [Presentation] STM/STSによる頂点フッ素系多層超伝導体Ba2Ca4Cu5(O,F)xにおけるギャップ分布観測

    • Author(s)
      杉本暁、田中勝大、峰田恭平、田辺健治、常磐和靖、浴野稔一
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 層状窒化物超伝導体NaxTiNClの STM / STS観測

    • Author(s)
      坂井優太、杉本暁、S.Zhang、田中将嗣、H.Zhu、山中昭司、浴野稔一
    • Organizer
      日本物理学会年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Research-status Report
  • [Presentation] STM-STSを用いた鉄カルコゲナイド超伝導体FeSe_x_Te_1-x_の局所障壁高さとトンネル スペクトルの観測

    • Author(s)
      杉本暁、坂井優太、浴野稔一
    • Organizer
      日本物理学会年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Research-status Report
  • [Presentation] STM/STS of the Layered Iron-chalcogenide and Nitro-chloride Superconductors

    • Author(s)
      Toshikazu EKINO
    • Organizer
      AnalytiX-2014
    • Place of Presentation
      大連国際会議場(中国)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Book] Gap structures of A-15 alloys from the superconducting and normal-state break-junction tunneling, in Superconductors- Matrials, Properties and Applictions, ed. A.M. Gabovich2015

    • Author(s)
      T.Ekino, A. Sugimoto, Y. Sakai, A.M. Gabovich, J. Akimitsu
    • Publisher
      InTech publishing
    • Related Report
      2014 Annual Research Report
  • [Book] Superconductivity: Theory, Materials and Applications, ed. by V.R. Romanovski Chapter 1."Tunneling Spectroscopy of Novel Layered Superconductors: MgB2, Li0.48(THF)xHfNCl and Related Substances"2012

    • Author(s)
      Tomoaki Takasaki, Toshikazu Ekino, Alexander M. Gabovich, Akira Sugimoto, Shoji Yamanaka, Jun Akimitsu
    • Total Pages
      109
    • Publisher
      Nova Science Publishers, Inc., New York
    • Related Report
      2012 Research-status Report
  • [Remarks] 広島大学大学院総合科学研究科超伝導電子物性_浴野研究室

    • URL

      http://home.hiroshima-u.ac.jp/ekinolab/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 広島大学大学院総合科学研究科超伝導電子物性_浴野研究室

    • Related Report
      2013 Research-status Report
  • [Remarks] 広島大学総合科学研究科総合物理研究領域超伝導物性研究室

    • URL

      http://home.hiroshima-u.ac.jp/ekinolab/

    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2020-05-15  

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