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Study of quantum phase transition in valence mapping under multiple extreme conditions for 4f electron system

Research Project

Project/Area Number 24540389
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionJapan Synchrotron Radiation Research Institute

Principal Investigator

KAWAMURA Naomi  公益財団法人高輝度光科学研究センター, 利用研究促進部門, 副主幹研究員 (40393318)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords強相関電子系 / 量子相転移 / 価数揺動 / X線吸収分光 / X線発光分光 / 高圧 / 量子臨界現象
Outline of Final Research Achievements


X-ray spectroscopy measurements under multiple extreme conditions such as low temperature, high magnetic field, and high pressure were performed to understand quantum phase transition in strongly correlated 4f electron system from a viewpoint of valence fluctuation. The spectrum with high precision and high energy-resolution was actualized and the method of valence estimation with a precise system was established. Valence estimation was mainly performed for Ce and Yb compounds, and the valence values were superimposed on the phase diagram made by the measurement of physical properties such as electric resistivity and magnetic susceptibility so that the correlation between the quantum critical phenomenon and valence state can be investigated. The method developed by this research project can be basically adopted for all rare-earth compounds. Therefore, a new insight for the correlation between the physical properties and the valence state will be obtained in near future.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (15 results)

All 2015 2014 2013 2012 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 3 results,  Acknowledgement Compliant: 2 results) Presentation (10 results) (of which Invited: 1 results)

  • [Journal Article] Pressure-Induced Valence Crossover and Novel Metamagnetic Behavior near the Antiferromagnetic Quantum Phase Transition of YbNi3Ga92015

    • Author(s)
      K. Matsubayashi, T. Hirayama, T. Yamashita, S. Ohara, N. Kawamura, M. Mizumaki, N. Ishimatsu, S. Watanabe, K. Kitagawa, Y. Uwatoko
    • Journal Title

      Phys. Rev. Lett.

      Volume: 114 Issue: 8 Pages: 086401-086401

    • DOI

      10.1103/physrevlett.114.086401

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Study of Electronic and Magnetic States Probed by X-Ray Absorption Spectroscopy under High Pressure2015

    • Author(s)
      河村直己
    • Journal Title

      The Review of High Pressure Science and Technology

      Volume: 25 Issue: 1 Pages: 38-48

    • DOI

      10.4131/jshpreview.25.38

    • NAID

      130005129838

    • ISSN
      0917-639X, 1348-1940
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] High Pressure Properties for Electrical Resistivity and Ce Valence State of Heavy-Fermion Antiferromagnet Ce2NiGa122014

    • Author(s)
      N. Kawamura, R. Sasaki, K. Matsubayashi, N. Ishimatsu, M. Mizumaki, Y. Uwatoko, S. Ohara, and S. Watanabe
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 568 Issue: 4 Pages: 042015-042015

    • DOI

      10.1088/1742-6596/568/4/042015

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Simultaneous Pressure-Induced Magnetic and Valence Transitions in Type-I Clathrate Eu8Ga16Ge302014

    • Author(s)
      T. Onimaru
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 83 Issue: 1 Pages: 013701-013701

    • DOI

      10.7566/jpsj.83.013701

    • NAID

      210000132902

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Chemical effects of high-resolution YbLγ4 emission spectra: a possible probe for chemical analysis2013

    • Author(s)
      Hisashi Hayashi, Noriko Kanai, Naomi Kawamura, Yasuhiro H. Matsuda, Kentaro Kuga, Satoru Nakatsuji, Tetsuro Yamashita, and Shigeo Ohara
    • Journal Title

      X-Ray Spectrom.

      Volume: 42 Issue: 6 Pages: 450-455

    • DOI

      10.1002/xrs.2502

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Ce2NiGa12の量子臨界現象とX線吸収によるCeの価数評価2015

    • Author(s)
      河村直己,松林和幸,石松直樹,水牧仁一朗,上床美也,大原繁男,渡辺真仁
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学 (東京都・新宿区)
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 希土類元素に対するX線吸収の2p→4f遷移とその共鳴X線発光スペクトル2014

    • Author(s)
      河村直己,新田清文,水牧仁一朗,石松直樹,松林和幸,松田康弘,内藤智之,藤代博之,上床美也,大原繁男,渡辺真仁
    • Organizer
      日本物理学会2014年秋季大会
    • Place of Presentation
      中部大学 (愛知県・春日井市)
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Cerium Valence State of Heavy-Fermion Antiferromagnet Ce2NiGa12 Probed by X-ray Absorption Spectroscopy at High Pressure2014

    • Author(s)
      N. Kawamura, K. Matsubayashi, N. Ishimatsu, M. Mizumaki, Y. Uwatoko, S. Ohara, and S. Watanabe
    • Organizer
      The 27th International Conference on Low Temperature Physics
    • Place of Presentation
      Palais Rouge (ブエノスアイレス・アルゼンチン)
    • Year and Date
      2014-08-06 – 2014-08-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ce2NiGa12におけるCe L3-吸収端での高圧下X線吸収測定2014

    • Author(s)
      河村直己, 松林和幸, 石松直樹, 水牧仁一朗, 上床美也, 大原繁男, 渡辺真仁
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学(神奈川県)
    • Related Report
      2013 Research-status Report
  • [Presentation] X線吸収分光法によるPrTi2Al20のPr価数の圧力変化2013

    • Author(s)
      河村直己, 松林和幸, 石松直樹, 水牧仁一朗, 酒井明人, 中辻知, 上床美也, 渡辺真仁
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学(徳島県)
    • Related Report
      2013 Research-status Report
  • [Presentation] 二次元検出器を用いた共鳴X線発光分光測定の高速化2013

    • Author(s)
      河村直己
    • Organizer
      第26回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      名古屋大学 (愛知県)
    • Related Report
      2012 Research-status Report
  • [Presentation] X線吸収・発光分光によるYbNi3Ga9のYb価数の温度-圧力相図の作成II2013

    • Author(s)
      河村直己
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学 (広島県)
    • Related Report
      2012 Research-status Report
  • [Presentation] Valence fluctuation study by using X-ray absorption and emission spectroscopy at Yb L3-edge in YbNi3X9 (X=Al and Ga)2012

    • Author(s)
      Naomi Kawamura
    • Organizer
      The 19th International Conference on Magnetism
    • Place of Presentation
      Busan Exhibition Covention Center (釜山市,韓国)
    • Related Report
      2012 Research-status Report
  • [Presentation] X線吸収・発光分光によるYbNi3Ga9のYb価数の温度-圧力相図の作成2012

    • Author(s)
      河村直己
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学 (神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 高圧力下でのX線吸収分光法による電子状態・磁気状態の研究

    • Author(s)
      河村直己
    • Organizer
      未来を拓く高圧力科学技術セミナーシリーズ(39)「高圧力と分光測定技術」
    • Place of Presentation
      日本大学(東京都)
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2020-05-15  

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