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An experimental study on a new type of relaxation time characterizing the glass transition

Research Project

Project/Area Number 24540434
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Biophysics/Chemical physics
Research InstitutionKyoto Institute of Technology

Principal Investigator

SARUYAMA Yasuo  京都工芸繊維大学, 工芸科学研究科, 教授 (50162532)

Co-Investigator(Kenkyū-buntansha) YAO Haruhiko  京都工芸繊維大学, 大学院工芸科学研究科, 准教授 (60212271)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsガラス転移 / 緩和時間 / 温度変調 / 非線形誘電測定 / 温度変調非線形誘電測定法 / 温度変調誘電測定法 / 温度変調非線形誘電測定
Outline of Final Research Achievements

The molecular mechanism of the glass transition has not been understood. This work is aimed to elucidate the glass transition mechanism through experimental studies to measure the time (tau_tau) necessary for the relaxation time of the alpha process to reach the new value after quick temperature change and its temperature dependence. A new experimental instrument, temperature modulated non-linear dielectric spectroscopy, has been developed. It was found that the tau_tau was ca. 1 s around the glass transition temperature and its temperature dependence was close to Arrhenius type. These results were obtained firstly in the world and will stimulate the studies on the glass transition in future.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (7 results)

All 2015 2014 2013 2012

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (5 results) (of which Invited: 2 results)

  • [Journal Article] Temperature-modulation spectroscopy of non-equilibrium systems2015

    • Author(s)
      T. Odagaki, Y. Saruyama, T. Ueno
    • Journal Title

      J.Non-Cryst. Solids

      Volume: 407 Pages: 57-65

    • DOI

      10.1016/j.jnoncrysol.2014.07.047

    • NAID

      40020325015

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Non-linear dielectric responses of a model glass former under oscillating temperature2012

    • Author(s)
      T. Odagaki
    • Journal Title

      Journal of Physical Society of Japan

      Volume: 81 Issue: 10 Pages: 1047141-5

    • DOI

      10.1143/jpsj.81.104714

    • NAID

      40019447581

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 温度変調誘電測定法の開発とガラス転移への応用(II) –電場周波数依存性2015

    • Author(s)
      吉内友章、漆谷雅弘、辰巳創一、八尾晴彦、猿山靖夫
    • Organizer
      高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27 – 2015-05-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 温度変調誘電測定法によるガラス転移温度域における非線形測定2014

    • Author(s)
      吉内友章、八尾晴彦、猿山靖夫、小田垣孝
    • Organizer
      物理学会 2014秋期大会
    • Place of Presentation
      中部大学
    • Year and Date
      2014-09-07 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Temperature Modulated Dielectric Measurement as a Tool to Study Non-linear Response around the Glass Transition Temperature2013

    • Author(s)
      Yasuo SARUYAMA, Masahiro URUSHIDANI, Haruhiko YAO
    • Organizer
      7th International Discussion Meeting on Relaxations in Complex Systems
    • Place of Presentation
      Barcelona, Spain
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 温度変調誘電測定法の開発とガラス転移への応用2013

    • Author(s)
      漆谷雅弘、及川孝、八尾晴彦、猿山靖夫
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Temperature Modulated Dielectric Measurement as a Tool to Study Non-linear Response around the Glass Transition Temperature2013

    • Author(s)
      Yasuo SARUYAMA, Masahiro URUSHIDANI, Haruhiko YAO
    • Organizer
      7th International Discussion Meeting on Relaxations in Complex Systems
    • Place of Presentation
      Universitat Politecnica de Catalunya
    • Related Report
      2012 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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