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Study of the spin transition in ferropericlase based on X-ray diffraction experiments at ultra-high pressures and high temperatures

Research Project

Project/Area Number 24540520
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionUniversity of Hyogo

Principal Investigator

MATSUI Masanori  兵庫県立大学, 生命理学研究科, 名誉教授 (90125097)

Co-Investigator(Kenkyū-buntansha) HIGO Yuji  公益財団法人高輝度光科学研究センター, 利用研究促進部門, 研究員 (10423435)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords放射光実験 / スピン転移 / 超音波測定 / フェロペリクレイス / 超高圧高温 / 下部マントル / 地球内部
Outline of Final Research Achievements

The elastic wave velocities of (Mg0.8,Fe0.2)O and (Mg0.5,Fe0.5)O ferropericlases have been measured up to 50 GPa, by combining ultrasonic interferometry, in situ synchrotron X-ray diffraction, and X-ray radiographic techniques in a Kawai-type, multi-anvil, high-pressure apparatus and sintered diamond anvils. The sample was heated in a cylindrical TiB2 (+BN) tube, and experimental data were recorded after heating the sample to 1073 K under a fixed press load to minimize non-hydrostatic components due to local deviatoric stresses. The travel times were measured based on the reflections from the sintered diamond cube, the polycrystalline Al2O3 buffer rod, and the sample. An abrupt change in ultrasonic echo from the sample was observed at pressures higher than about 40 GPa in (Mg0.5,Fe0.5)O ferropericlase, suggesting a result of high-spin to low-spin phase transition in the Fe ions.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (15 results)

All 2014 2013 2012 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results,  Open Access: 1 results) Presentation (5 results)

  • [Journal Article] High-pressure and high-temperature phase diagram for Fe0.9Ni0.1-Halloy2014

    • Author(s)
      Shibazaki Y., Terasaki H., Ohtani E., Tateyama R., Nishida K., Funakoshi K., Higo Y.
    • Journal Title

      Physics of the Earth and Planetary Interiors

      Volume: 228 Pages: 192-201

    • DOI

      10.1016/j.pepi.2013.12.013

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Over 1 Mbar generation in the Kawai-type multianvil apparatus and its application to compression of (Mg0.92Fe0.08) SiO3 nerovskite and stishovite2014

    • Author(s)
      D. Yamazaki, et al.
    • Journal Title

      Phys. Earth Planet. Inter.

      Volume: 228 Pages: 262-267

    • DOI

      10.1016/j.pepi.2014.01.013

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Stability of hydrous silicate at high pressures and water transport to the deep lower mantle2014

    • Author(s)
      Nishi, M., Irifune, T., Tsuchiya, J., Tange, Y., Nishihara, Y., Fujino, K. and Higo, Y
    • Journal Title

      Nature Geoscience

      Volume: 7 Issue: 3 Pages: 224-227

    • DOI

      10.1038/ngeo2074

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structures and stabilities of cristobalite-helium phases at high pressures2014

    • Author(s)
      M. Matsui, T. Sato, N. Funamori
    • Journal Title

      American Mineralogist

      Volume: 99 Issue: 1 Pages: 184-189

    • DOI

      10.2138/am.2014.4637

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] High pressure study of transition metal monoxides MnO and CoO : Structure and electrical resistance2013

    • Author(s)
      E. Ito, et al.
    • Journal Title

      Phys. Earth Planet. Inter.

      Volume: 228 Pages: 170-175

    • DOI

      10.1016/j.pepi.2013.12.009

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unusual pressure effect on the shear modulus in MgAl2O4 spinel2013

    • Author(s)
      Y. Zou, S. Greaux, T. Irifune, B. Li, Y. Higo
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 117 Issue: 46 Pages: 24518-24526

    • DOI

      10.1021/jp404901a

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Mantle wedge infiltrated with saline fluids from dehydration and decarbonation of subducting slab2013

    • Author(s)
      Kawamoto, T., Yoshikawa, M., Kumagai, Y., Mirabueno, M. H. T., Okuno, M., Kobayashi, T.
    • Journal Title

      Proc. Nat. Acad. Sci. USA

      Volume: 110 Issue: 8-9 Pages: 9663-9668

    • DOI

      10.2138/am.2012.3958

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] P-V-T equation of state for ε-iron up to 80 GPa and 1900 K using the Kawai-type high pressure apparatus equipped with sintered diamond anvils2013

    • Author(s)
      D. Yamazaki, E. Ito, T. Yoshino, A. Yoneda, X. Guo, B. Zhang, W. Sun, A. Shimojuku, N. Tsujino, T. Kunimoto, Y. Higo, K. Funakoshi
    • Journal Title

      Geophysical Research Letters

      Volume: 39 Issue: 20

    • DOI

      10.1029/2012gl053540

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Elasticity and sound velocities of polycrystalline Mg3Al2(SiO4)3 garnet up to 20 GPa and 1700 K2012

    • Author(s)
      Y. Zou
    • Journal Title

      J. Appl. Phys.

      Volume: 112 Issue: 1 Pages: 14910-14910

    • DOI

      10.1063/1.4736407

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Simultaneous sound velocity and density measurements of NaCl at high temperatures and high pressures: application as a primary pressure standard2012

    • Author(s)
      M. Matsui
    • Journal Title

      Amer. Mineral.

      Volume: 97 Issue: 10 Pages: 1670-1675

    • DOI

      10.2138/am.2012.4136

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] MgSiO3メルトの構造とそれらの温度圧力依存の第一原理計算2014

    • Author(s)
      松井 正典
    • Organizer
      日本地球惑星科学連合2014年大会
    • Place of Presentation
      パシフィコ横浜会議センター(神奈川県横浜市)
    • Year and Date
      2014-05-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] 焼結ダイヤモンドを用いた下部マントル条件下での弾性波速度測定技術開発

    • Author(s)
      肥後祐司、舟越賢一、入舩徹男、松井正典
    • Organizer
      第54回高圧討論会
    • Place of Presentation
      朱鷺メッセ新潟コンベンションセンター(新潟県新潟市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 高圧下におけるクリストバライト-ヘリウムI及びII相の結晶構造と安定性

    • Author(s)
      松井 正典、佐藤 友子、船守 展正
    • Organizer
      日本鉱物科学会2013年年会
    • Place of Presentation
      筑波大学第一エリア(茨城県つくば市)
    • Related Report
      2013 Research-status Report
  • [Presentation] NaCl圧力スケール

    • Author(s)
      松井 正典
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学会館(大阪府)
    • Related Report
      2012 Research-status Report
  • [Presentation] 下部マントル構成鉱物の弾性波速度測定

    • Author(s)
      肥後 祐司
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学会館(大阪府)
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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