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A Study of Chemical Reactions in Laser-induced Microplasmas

Research Project

Project/Area Number 24540540
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Plasma science
Research InstitutionOsaka City University

Principal Investigator

SHIRAFUJI Tatsuru  大阪市立大学, 大学院工学研究科, 教授 (10235757)

Research Collaborator TAKAHASHI Kenji  金沢大学, 自然システム学系, 教授 (00216714)
TOCHIKUBO Fumiyoshi  首都大学東京, 大学院理工学研究科, 教授 (90244417)
MURAKAMI Tomoyuki  東京工業大学, 大学院総合理工学研究科, 助教 (20323818)
TANAKA Kenji  大阪市立大学, 大学院工学研究科, 助教 (20254386)
GOTO Tetsuo  ライトタッチ研究会/ホワイトネット事務局, 代表
KANBAYASHI Hideo  医療法人けやき通り歯科, 理事長/院長
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsプラズマ / Er:YAGレーザ / 水 / 滅菌 / ラジカル / 化学反応 / 発光分光 / シミュレーション / レーザ / 液中 / キャビテーション / Er:YAG / 歯科 / 過酸化水素 / OHラジカル / 医療 / マイクロプラズマ / 低侵襲
Outline of Final Research Achievements

We have found that inactivation of the strepococcus mutans is possible by the treatment of a tooth using an Er:YAG laser and water, and that concentration of hydrogen peroxide increases by Er:YAG laser irradiation to water. Although we could not have definite evidences for proving generation of plasma in water by Er:YAG laser, we have clarified that OH radicals are generated through a dissociative recombination of hydronium ions and low energy electrons even after excitation period according to the results of our numerical simulation of gas-phase plasma reactions including water vapor.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (39 results)

All 2015 2014 2013 2012 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (34 results) (of which Invited: 5 results) Remarks (3 results)

  • [Journal Article] Contribution of electrons, Ar(3P0,2), H2O+, and H3O+ to production of OH(A2Σ+) in a micro dielectric barrier discharge of Ar/H2O2014

    • Author(s)
      T. Shirafuji and T. Murakami
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 54 Issue: 1S Pages: 01AC03-01AC03

    • DOI

      10.7567/jjap.54.01ac03

    • NAID

      210000144737

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Numerical simulation of electric double layer with dielectric barrier discharge -Effects of ion transport parameters in liquid-2014

    • Author(s)
      T.Shirafuji, A.Nakamura, and F.Tochikubo
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 3S2 Pages: 1-6

    • DOI

      10.7567/jjap.53.03dg04

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 3D integrated micro-solution plasma in 3D-printed artificial dielectric materials2015

    • Author(s)
      Y. Ogura, N. Sotoda, K. Tanaka, and T. Shirafuji
    • Organizer
      The 7th International Symposium on Advanced Plasma Science and Its Applications for Nitrides and Nanomaterials / The 8th International Conference on Plasma-Nano Technology & Science
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2015-03-26 – 2015-03-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] On the differences in temporal behavior of OH(A) in 3D integrated micro-solution plasma using Ar and He2015

    • Author(s)
      N. Sotoda, Y. Ogura, K. Tanaka, and T. Shirafuji
    • Organizer
      The 7th International Symposium on Advanced Plasma Science and Its Applications for Nitrides and Nanomaterials / The 8th International Conference on Plasma-Nano Technology & Science
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2015-03-26 – 2015-03-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] Single-bubble plasma generated in a capillary tube, and its mobile characterisitcs2015

    • Author(s)
      K. Obana, R. Tashiro, K. Tanaka, and T. Shirafuji
    • Organizer
      The 7th International Symposium on Advanced Plasma Science and Its Applications for Nitrides and Nanomaterials / The 8th International Conference on Plasma-Nano Technology & Science
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2015-03-26 – 2015-03-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] Analysis of degradation products after treatment of methylene blue aqueous solution with 3D integrated micro-solution plasma2015

    • Author(s)
      A. Nomura, Y. Hayashi, K. Tanaka, M. Goto, and T. Shirafuji
    • Organizer
      The 7th International Symposium on Advanced Plasma Science and Its Applications for Nitrides and Nanomaterials / The 8th International Conference on Plasma-Nano Technology & Science
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2015-03-26 – 2015-03-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] バイオ応用に向けた大気圧及び液中の非平衡プラズマ生成2015

    • Author(s)
      白藤 立,田中 健司,立花 亮,田辺 利住,中西 猛,北村 昌也
    • Organizer
      「バイオインターフェース先端マテリアルの創生」第5回シンポジウム/第3回バイオ・メディカル・フォーラム
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Year and Date
      2015-01-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] 液体との界面を有するプラズマの時間分解発光分光計測2015

    • Author(s)
      田代 龍太郎,尾花 和彦,田中 健司,白藤 立
    • Organizer
      「バイオインターフェース先端マテリアルの創生」第5回シンポジウム/第3回バイオ・メディカル・フォーラム
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Year and Date
      2015-01-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] 液体プラズマの有機物分解への応用2015

    • Author(s)
      山本 純平,野村 彩乃,田中 健司,中西 猛,北村 昌也,白藤 立,林 結衣,後藤 元信
    • Organizer
      「バイオインターフェース先端マテリアルの創生」第5回シンポジウム/第3回バイオ・メディカル・フォーラム
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Year and Date
      2015-01-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水蒸気含有プラズマ中の気相反応シミュレーション2015

    • Author(s)
      白藤 立,田中 健司
    • Organizer
      「バイオインターフェース先端マテリアルの創生」第5回シンポジウム/第3回バイオ・メディカル・フォーラム
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Year and Date
      2015-01-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Comparison of Reaction Kinetics in Atmospheric Pressure Dielectric Barrier Discharges in Ar/H2O and He/H2O gas mixtures2014

    • Author(s)
      T. Shirafuji
    • Organizer
      第24回日本MRS年次大会
    • Place of Presentation
      横浜開港記念会館(神奈川県横浜市)
    • Year and Date
      2014-12-10 – 2014-12-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] 人工多孔質体を用いた気液混合媒質中プラズマの生成2014

    • Author(s)
      小倉 悠平,外田 直也,姫野 勇大,田中 健司,白藤 立
    • Organizer
      Plasma Conference 2014
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2014-11-18 – 2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] Comparison of temporal variation in emission intensity of OH(A) in after-glow period of Ar/H2O and He/H2O gas-mixture plasmas in water2014

    • Author(s)
      T. Shirafuji
    • Organizer
      The 67th Annual Gaseous Electronics Conference
    • Place of Presentation
      Raleigh Convention Center and Marriott City Center, Raleigh, North Carolina (U.S.A.)
    • Year and Date
      2014-11-03 – 2014-11-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水蒸気を含むAr及びHeガスのDBD中におけるOHラジカルの生成反応2014

    • Author(s)
      白藤 立
    • Organizer
      電気学会プラズマ・パルスパワー・放電合同研究会
    • Place of Presentation
      コンパルホール(大分県大分市)
    • Year and Date
      2014-10-24 – 2014-10-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 市販ソルバーを用いたプラズマシミュレーション2014

    • Author(s)
      白藤 立
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 多孔質誘電体内の水中ヘリウムプラズマの発光分光計測2014

    • Author(s)
      外田 直也, 小倉 悠平, 田中 健司, 白藤 立
    • Organizer
      電気学会プラズマ研究会
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水と接するArプラズマの発光分光計測2014

    • Author(s)
      尾花 和彦, 田代 龍太郎, 田中 健司, 白藤 立
    • Organizer
      電気学会プラズマ研究会
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] 三次元集積化マイクロソリューションプラズマを用いたメチレンブルー分子分解における放電ガス種依存性2014

    • Author(s)
      野村 彩乃, 田中 健司, 白藤 立
    • Organizer
      電気学会プラズマ研究会
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Characterization of decomposition products after 3D integrated micro-solution plasma treatment of methylene blue aqueous solution2014

    • Author(s)
      T. Shirafuji, A. Nomura, Y. Hayashi, K. Tanaka, and Motonobu Goto
    • Organizer
      The 12th Asia Pacific Conference on Plasma Science and Technology / The 26th Symposium on Plasma Science for Materials
    • Place of Presentation
      Adelaide Convention Centre, Adelaide, South Australia (Australia)
    • Year and Date
      2014-08-31 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] MALDI-TOF MS analysis of products via 3D integrated micro-solution plasma treatment of methylene blue aqueous solution2014

    • Author(s)
      A. Nomura, Y. Himeno, Y. Hayashi, K. Tanaka, M. Goto, and T. Shirafuji
    • Organizer
      The 15th IUMRS-International Conference in Asia
    • Place of Presentation
      福岡大学(福岡県福岡市)
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] 新しいプラズマのかたち “水中でものをつくる”2014

    • Author(s)
      白藤 立
    • Organizer
      日本真空学会関西支部 & 日本表面科学会関西支部合同セミナー 2014「大気圧プラズマ~その基礎と新しい医療を目指した取り組み~」
    • Place of Presentation
      大阪大学豊中キャンパス(大阪府豊中市)
    • Year and Date
      2014-07-01
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 3D integrated micro-solution plasma for the treatment of water -Effects of discharge gases-2014

    • Author(s)
      A. Nomura, Y. Himeno, K. Tanaka, and T. Shirafuji
    • Organizer
      The 26th Symposium on Plasma Physics and Technology
    • Place of Presentation
      Czech Technical University, Prague (Czech Republic)
    • Year and Date
      2014-06-16 – 2014-06-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Numerical simulation of electric double layer in contact with DBD -Effects of mobility and diffusion coefficient of liquid ions-2014

    • Author(s)
      T. Shirafuji
    • Organizer
      The 5th International Conference on Plasma Medicine
    • Place of Presentation
      奈良県新公会堂(奈良県奈良市)
    • Year and Date
      2014-05-18 – 2014-05-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Plasma chemistry in 3D integrated micro-solution plasma2014

    • Author(s)
      T. Shirafuji
    • Organizer
      The 2nd International Workshop on Solution Plasma and Molecular Technologies
    • Place of Presentation
      Korea Aerospace University, Gyeonggi-si, Gyeonggi-do (Korea)
    • Year and Date
      2014-05-14 – 2014-05-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 水蒸気を含む Ar ガスの DBD 中における OH ラジカル生成反応2014

    • Author(s)
      白藤 立, 村上 朝之
    • Organizer
      電気学会プラズマ研究会
    • Place of Presentation
      足利工業大学(栃木県足利市)
    • Year and Date
      2014-05-09 – 2014-05-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Time-resolved optical emission spectroscopy on micro-solution plasma in a single bubble in a capillary tube2014

    • Author(s)
      R. Tashiro, K. Obana, and T. Shirafuji
    • Organizer
      The 8th International Conference on Reactive Plasmas / The 31st Symposium on Plasma Processing
    • Place of Presentation
      福岡国際会議場, 福岡県福岡市
    • Related Report
      2013 Research-status Report
  • [Presentation] Solution microplasma: generation, diagnostics and application2013

    • Author(s)
      T. Shirafuji
    • Organizer
      The 7th International Workshop on Microplasmas 2013
    • Place of Presentation
      The Fragrant Hill Hotel, Beijing, China
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Numerical simulation of spatiotemporal behavior of electric double layer in aqueous solution in contact with gas-phase plasma sheath2013

    • Author(s)
      T. Shirafuji and A. Nakamura
    • Organizer
      The 21st International Symposium on Plasma Chemistry
    • Place of Presentation
      Cairns Convention Centre, Cairns, Australia
    • Related Report
      2013 Research-status Report
  • [Presentation] Numerical simulation of electric double layer in contact with dielectric barrier discharge -Effects of frequency-2013

    • Author(s)
      T. Shirafuji, A. Nakamura, and F. Tochikubo
    • Organizer
      The 9th Asian-European International Conference on Plasma Surface Engineering
    • Place of Presentation
      Ramada Plaza Jeju Hotel, Jeju, Korea
    • Related Report
      2013 Research-status Report
  • [Presentation] Numerical simulation of electric double layer in contact with dielectric barrier discharge -Effects of ion transport parameters in liquid-2013

    • Author(s)
      T. Shirafuji, A. Nakamura, and F. Tochikubo
    • Organizer
      The 35th International Symposium on Dry Process
    • Place of Presentation
      Ramada Plaza Jeju Hotel, Jeju, Korea
    • Related Report
      2013 Research-status Report
  • [Presentation] Confirmation of sterilization effects and OES study of Er:YAG laser irradiation on hydroxyapatite2013

    • Author(s)
      T. Shirafuji, J. Ueda, R. Tashiro, K. Takahashi, H. Kambayashi, and T. Goto
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      同志社大学(京田辺キャンパス), 京都府京田辺市
    • Related Report
      2013 Research-status Report
  • [Presentation] Time-resolved OES study of a single-bubble plasma generated in a capillary tube2013

    • Author(s)
      K. Obana, R. Tashiro, and T. Shirafuji
    • Organizer
      International Conference on Surface Engineering
    • Place of Presentation
      Haeundae Grand Hotel, Busan, Korea
    • Related Report
      2013 Research-status Report
  • [Presentation] Electrochemical simulation of plasma/liquid interface2013

    • Author(s)
      A. Nakamura and T. Shirafuji
    • Organizer
      International Conference on Surface Engineering
    • Place of Presentation
      Haeundae Grand Hotel, Busan, Korea
    • Related Report
      2013 Research-status Report
  • [Presentation] On the possibility of plasma generation in water using Er:YAG laser and its application to non-invasive sterilization2013

    • Author(s)
      J. Ueda, T. Shirafuji, H. Kambayashi, K. Takahashi and T. Goto
    • Organizer
      The 30th Symposium on Plasma Processing
    • Place of Presentation
      アクトシティ浜松
    • Related Report
      2012 Research-status Report
  • [Presentation] Possibility of plasma generation and sterilization in water using an Er:YAG laser2013

    • Author(s)
      T. Shirafuji, K. Takahashi, H. Kambayashi and T. Goto
    • Organizer
      The 5th International Symposium on Advanced Plasma Science and Its Applications for Nitrides and Nanomaterials
    • Place of Presentation
      Nagoya University
    • Related Report
      2012 Research-status Report
  • [Presentation] 液中マイクロプラズマの化学反応解析2012

    • Author(s)
      白藤 立
    • Organizer
      局所高密度励起の化学と応用
    • Place of Presentation
      東京工業大学
    • Related Report
      2012 Research-status Report
    • Invited
  • [Remarks] 研究室Webページ

    • URL

      http://t-shirafuji.jp/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 研究室Webページ

    • URL

      http://t-shirafuji.jp/

    • Related Report
      2013 Research-status Report
  • [Remarks] 研究室Webページ

    • URL

      http://www.t-shirafuji.jp/

    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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