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Step free energy and line tention on single crystal surface

Research Project

Project/Area Number 24550016
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical chemistry
Research InstitutionShinshu University

Principal Investigator

SUZUKI Takaomi  信州大学, 学術研究院工学系, 准教授 (20196835)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords結晶成長 / 固体表面 / 表面自由エネルギー
Outline of Final Research Achievements

Specific surface free energy (SSFE) is significant value to discuss morphology of single crystal. The relationship between the growth rate of crystal face and the SSFE is relative and the relationship is well known as Wulff’s relationship. Although experimental determination of the SSFE of crystal is performed and accepted in the field of colloid and interface research field, experimental determination of the SSFE of crystal surface is believed to be difficult or impossible.
Contact angle of liquid is used to determine SSFE of single crystal. Distribution of the contact angle of liquid on crystal face is very wide, because free energy of steps on the crystal face varies the SSFE of ideally flat surface. The step free energy was studied and compared with line tension in this research. Polished quartz crystal was used in order to discuss the SSFE of crystal face with less steps. Step free energy on z face of quartz was positive, but that on m face was negative.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (18 results)

All 2014 2013 2012

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (16 results) (of which Invited: 1 results)

  • [Journal Article] Specific Surface Free Energy of As-grown and Polished Faces of Synthetic Wuartz2014

    • Author(s)
      Takaomi Suzuki, Keiko Takahashi, Masayuki Kawasaki, Toshihiko Kgami
    • Journal Title

      Journal of Crystallization Process and Technology

      Volume: 4 Issue: 04 Pages: 177-184

    • DOI

      10.4236/jcpt.2014.44022

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Thermodynamic Interpretation of Morphology Individuality of Natural and Synthesized Apatite Single Crystals2013

    • Author(s)
      Takaomi Suzuki, Haruka Takemae, Mika Yoshida
    • Journal Title

      J. Crystallization Process and Technology

      Volume: 3 Issue: 04 Pages: 119-122

    • DOI

      10.4236/jcpt.2013.34019

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 表面自由エネルギー密度からみたアルカリハライド単結晶表面の微細構造2014

    • Author(s)
      山田祐也、鈴木孝臣
    • Organizer
      第56回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学神楽坂校舎(東京都新宿区)
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] タングステン表面粗さと表面自由エネルギー密度の関係2014

    • Author(s)
      城月晃、太子敏則、干川圭吾、鈴木孝臣
    • Organizer
      第56回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学神楽坂校舎(東京都新宿区)
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] 合成アパタイト単結晶の表面自由エネルギー密度2014

    • Author(s)
      塚越彩乃、吉田美佳、鈴木孝臣
    • Organizer
      第56回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学神楽坂校舎(東京都新宿区)
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Specific Surface Free Energy of Crucible Material for Sapphire Crystal Synthesis2013

    • Author(s)
      Takaomi Suzuki, Kou Shirotsuki, Toshinori Taishi, Keigo Hoshikawa
    • Organizer
      17th International Conference of Crystal Growth and Epitaxy
    • Place of Presentation
      University of Warsaw (Poland)
    • Related Report
      2013 Research-status Report
  • [Presentation] Characteristic Void alignment in Sapphire Crystals Grown by the Vertical Bridgman Method2013

    • Author(s)
      Junya Osada, Takaomi Suzuki, Toshinori Taishi, Keigo Hoshikawa
    • Organizer
      17th International Conference of Crystal Growth and Epitaxy
    • Place of Presentation
      University of Warsaw (Poland)
    • Related Report
      2013 Research-status Report
  • [Presentation] Specific surface free energy of inorganic salt2013

    • Author(s)
      Yuya Yamada, Takaomi Suzuki
    • Organizer
      17th International Conference of Crystal Growth and Epitaxy
    • Place of Presentation
      University of Warsaw (Poland)
    • Related Report
      2013 Research-status Report
  • [Presentation] Thermodynamic interpretation of the morphology individuality of inorganic oxide single crystal2013

    • Author(s)
      Mika Yoshida, Takaomi Suzuki
    • Organizer
      17th International Conference of Crystal Growth and Epitaxy
    • Place of Presentation
      University of Warsaw (Poland)
    • Related Report
      2013 Research-status Report
  • [Presentation] Determination of Specific Surface Free Energy of Inorganic Crystal Using Contact Angle of Liquid2013

    • Author(s)
      Takaomi Suzumki
    • Organizer
      Collaborative Conference on Crystal Growth
    • Place of Presentation
      Cancun, Mexico
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] The Specific Surface Free Energy of Synthesized Quartz2013

    • Author(s)
      K.Takahashi, T.Suzuki
    • Organizer
      Collaborative Conference on Crystal Growth
    • Place of Presentation
      Cancun, Mexico
    • Related Report
      2013 Research-status Report
  • [Presentation] Specific Surface Free Energy and Morphology of Barium Chlorapatite Single Crystals2013

    • Author(s)
      M.Yoshida, T.Suzuki
    • Organizer
      Collaborative Conference on Crystal Growth
    • Place of Presentation
      Cancun, Mexico
    • Related Report
      2013 Research-status Report
  • [Presentation] 硫酸塩鉱物結晶の表面自由エネルギー密度とモルフォロジー2013

    • Author(s)
      神谷竜士、鈴木孝臣
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 無機塩単結晶の表面自由エネルギー密度とモルフォロジー2013

    • Author(s)
      山田祐也・鈴木孝臣・中山雅基
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 無機酸化物単結晶の表面自由エネルギー密度2013

    • Author(s)
      吉田美佳、鈴木孝臣
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Measurement of specific surface free energy of barium sulfate2012

    • Author(s)
      Ryushi Kamiya, Takaomi Suzuki
    • Organizer
      The 7th International Workshop on Modeling in Crystal Growth
    • Place of Presentation
      Taiwan
    • Related Report
      2012 Research-status Report
  • [Presentation] Inference of radius of critical nucleus of natural crystal used specific surface free energy2012

    • Author(s)
      Jun Koyasu, Takaomi Suzuki
    • Organizer
      The 7th International Workshop on Modeling in Crystal Growth
    • Place of Presentation
      Taiwan
    • Related Report
      2012 Research-status Report
  • [Presentation] 無機酸化物単結晶におけるステップ自由エネルギー2012

    • Author(s)
      吉田美佳、鈴木孝臣
    • Organizer
      第42回結晶成長国内会議
    • Place of Presentation
      九州大学
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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