Synthesis of Reactive Metal Complexes Bearing New Tripodal Ligand and Their Application to the Activation of Small Molecules
| Project/Area Number |
24550039
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | 三脚型四座配位子 / 遷移金属錯体 / チオエーテル配位子 / シリル配位子 / リン配位子 / 酸化反応 / ヒドロシリル化反応 / ホスフィン配位子 / 白金錯体 / ヒドロシリル化 / ルテニウム錯体 / パラジウム錯体 / １１族金属錯体 |
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| Outline of Final Research Achievements |
We synthesized dimethylpalladium complex, group 11 metal complexes and dichlororuthenium complex bearing a new tripodal tetradentate phosphine ligand, P[C6H4-2-S(i-Pr)]3 (1). Palladium and platinum complexes bearing a new tripodal tetradentate silyl ligand, －Si(C6H4-2-SR)3 (2), were also synthesized. Their structures and reactivities were elucidated and catalytic reactions of PhCH2CH2OH with HSiEt3 using [Ag2(1)2]2(ClO4) or [Au2(1)2]2(OTf), catalytic oxidation of and catalytic hydrosilylation of 4-phenyl-1-butene with HSi(OEt)3 using [PtCl(2)] were found.
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Report
(4 results)
Research Products
(45 results)
