| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
|
|---|
| Outline of Final Research Achievements |
We synthesized dimethylpalladium complex, group 11 metal complexes and dichlororuthenium complex bearing a new tripodal tetradentate phosphine ligand, P[C6H4-2-S(i-Pr)]3 (1). Palladium and platinum complexes bearing a new tripodal tetradentate silyl ligand, －Si(C6H4-2-SR)3 (2), were also synthesized. Their structures and reactivities were elucidated and catalytic reactions of PhCH2CH2OH with HSiEt3 using [Ag2(1)2]2(ClO4) or [Au2(1)2]2(OTf), catalytic oxidation of and catalytic hydrosilylation of 4-phenyl-1-butene with HSi(OEt)3 using [PtCl(2)] were found.
|
