| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Outline of Final Research Achievements |
Carbazole dimers and trimers were systematically synthesized, and the structure-property relationships, namely the effects of connecting positions and spacers on the properties were disclosed. Various oligomers composed of carbazole and thiophene were also systematically synthesized, and the effects of connecting positions and numbers of aromatics on the properties were elucidated.
Acyclic host compounds (molecular receptors) possessing ethynylcarbazole moieties at 1,8-positions of carbazole were systematically synthesized, and the complexation behavior with some acceptors was investigated. Conjugated macrocycles composed of carbazole and triazole moieties were successfully synthesized by click reactions, and their self-association and complexation with anions such as iodide ion were clarified.
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