Synthesis and Properties of Electron-deficient Aluminum Cluster Compounds Based on Bottom-up Approach
| Project/Area Number |
24550048
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
AGOU Tomohiro 京都大学, 化学研究所, 助教 (90466798)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | アルミニウム / 有機典型元素化学 / 有機金属化学 / 分子活性化 / 低配位化学種 / 有機元素化学 / クラスター / アルミレン / ジアルメン |
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| Outline of Final Research Achievements |
We have synthesized barrelene-type organoaluminum compounds bearing an Al-Al single bond and elucidated their reactivities as synthetic equivalents of highly reactive Al=Al doubly-bonded species. Reactions of the barrelene-type organoaluminum compounds with unsaturated compounds as well as transition metal complexes afforded the corresponding electron-deficient organoaluminum species and complexes bearing aluminum-transition metal bonds.
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Report
(4 results)
Research Products
(27 results)
