Versatile Synthesis of Three Dimensionally Extended pi-Electron Systems Using Partially Functionalized Derivatives of Tetrathienylmethane
| Project/Area Number |
24550049
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Senshu University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Keywords | オリゴチオフェン / デンドリマー / 拡張パイ電子系化合物 / 三次元拡張パイ電子系 / 合成有機化学 / 構造有機化学 / 拡張π電子系化合物 / 材料科学 / 有機合成化学 / 機能性有機分子 |
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| Outline of Final Research Achievements |
In order to explore the synthetic route to the various three dimensionally (3D) extended pi-electron systems using tetra(2-thienyl)methane (1) framework, mono-, di-, and tri-bromo derivatives of 1 have been synthesized and isolated. These three partially brominated derivatives of 1 were isolated in gram scale which were enough amount as the starting materials for the new 3D-extended pi-electron systems. For instance, the dendritic molecule was synthesized in which four tetra(2-thienyl)methane moiety were incorporated into the central tetra(2-thienyl)methane framework.
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Report
(4 results)
Research Products
(19 results)
