Creation of Novel Group 16 Element Compounds having Weak Chemical Bonds
| Project/Area Number |
24550063
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Rikkyo University (2013-2014)
Kitasato University (2012) |
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Principal Investigator |
MINOURA Mao 立教大学, 理学部, 教授 (30274046)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 典型元素 / 有機元素化学 / 相変化メモリ / 結晶構造解析 / テルル / スルフェン酸 / カルコゲン / 硫黄 / 元素化学 / シグマ結合 / 互変異性化 / セレン / 結晶構造 |
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| Outline of Final Research Achievements |
The chemistry of heavier main group elements has been developed with respect to weak multiple-bond (pi-bonding) utilizing the kinetic stabilization method. However, organoelement compounds containing weak sigma-bonds were less explored due to their instability.
In this project, we investigated on weak sigma bonds containing group 16 elements. 1) Bis-silyl/germyltellurides were prepared using pure and isolated reagents, 2) Imidazolium-selone/-tellone having weak polar bonding system were successfully synthesized, 3) an Enesulfenic acid which is regarded as a sulfur analogue of reactive peroxide was isolated.
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Report
(4 results)
Research Products
(15 results)
