| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Outline of Final Research Achievements |
The chemistry of heavier main group elements has been developed with respect to weak multiple-bond (pi-bonding) utilizing the kinetic stabilization method. However, organoelement compounds containing weak sigma-bonds were less explored due to their instability.
In this project, we investigated on weak sigma bonds containing group 16 elements. 1) Bis-silyl/germyltellurides were prepared using pure and isolated reagents, 2) Imidazolium-selone/-tellone having weak polar bonding system were successfully synthesized, 3) an Enesulfenic acid which is regarded as a sulfur analogue of reactive peroxide was isolated.
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