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Structural diversification of porous light metal complexes using charge-separated neutral ligands

Research Project

Project/Area Number 24550068
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionHokkaido University

Principal Investigator

NORO Shin-ichiro  北海道大学, 電子科学研究所, 准教授 (70373347)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords多孔性材料 / 金属錯体 / 軽金属イオン / ガス分離 / 二酸化炭素 / 多孔性金属錯体 / 分離 / 柔軟性構造 / 吸着
Outline of Final Research Achievements

We performed the basic study on the design and synthesis of porous light metal complexes. It was revealed that the ligands with pyridine-N-oxide moieties are effective for the structural diversification of porous light metal complexes.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (25 results)

All 2015 2014 2012

All Journal Article (12 results) (of which Peer Reviewed: 12 results,  Open Access: 8 results,  Acknowledgement Compliant: 6 results) Presentation (13 results) (of which Invited: 5 results)

  • [Journal Article] Porous coordination polymers with ubiquitous and biocompatible metals and a neutral bridging ligand2015

    • Author(s)
      Shin-ichiro Noro, Junya Mizutani, Yuh Hijikata, Ryotaro Matsuda, Hiroshi Sato, Susumu Kitagawa, Kunihisa Sugimoto, Yasutaka Inubushi, Kazuya Kubo, and Takayoshi Nakamura
    • Journal Title

      Nature Communications

      Volume: 6 Issue: 1 Pages: 5851-5851

    • DOI

      10.1038/ncomms6851

    • NAID

      120005745622

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Dynamic induction of enantiomeric excess from a prochiral azobenzene dimer under circularly polarized light2015

    • Author(s)
      K. Rijeesh, P. K. Hashim, Shin-ichiro Noro, and Nobuyuki Tamaoki
    • Journal Title

      Chemical Science

      Volume: 6 Issue: 2 Pages: 973-980

    • DOI

      10.1039/c4sc01993h

    • NAID

      120005567743

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Mesophases and Ionic Conductivities of Simple Organic Salts of M(m-Iodobenzoate) (M = Li+, Na+, K+, Rb+, and Cs+)2015

    • Author(s)
      Manami Endo, Yuta Nakane, Kiyonori Takahashi, Norihisa Hoshino, Takashi Takeda, Shin-ichiro Noro, Takayoshi Nakamura, and Tomoyuki Akutagawa
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 119 Issue: 4 Pages: 1768-1777

    • DOI

      10.1021/jp5112026

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Selective carbon dioxide adsorption of ε-Keggin-type zincomolybdate-based purely-inorganic 3D frameworks2015

    • Author(s)
      Zhenxin Zhang, Masahiro Sadakane, Shin-ichiro Noro, Toru Murayama, Takashi Kamachi, Kazunari Yoshizawa, and Wataru Ueda
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 3 Issue: 2 Pages: 746-755

    • DOI

      10.1039/c4ta05496b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Supramolecular cations of (m-halogenated-anilinium)(dibenzo[18]crown-6) in Keggin [SMo12O402−] polyoxometallates2015

    • Author(s)
      J. Xiong, K. Kubo, S. Noro, T. Akutagawa, and N. Nakamura
    • Journal Title

      CrystEngComm.

      Volume: 17 Issue: 4 Pages: 856-861

    • DOI

      10.1039/c4ce01988a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Three-dimensional Architectures of [MnIICrIII(oxalate)3]; Complexes with Cage Type Networks Surrounding Supramolecular Cations2015

    • Author(s)
      Toru Endo, Kazuya Kubo, Masashi Yoshitake, Shin-ichiro Noro, Norihisa hoshino, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      rystal Growth & Design

      Volume: 15 Issue: 3 Pages: 1186-1193

    • DOI

      10.1021/cg501560z

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Systematic Syntheses and Metalloligand Doping of Flexible Porous Coordination Polymers Composed of a Co(III)-Metalloligand2015

    • Author(s)
      Atsushi Kobayashi, Yui Suzuki, Tadashi Ohba, Tomohiro Ogawa, Takeshi Matsumoto, Shin-ichiro Noro, Ho-Chol Chang, and Masako Kato
    • Journal Title

      Inorganic Chemistry

      Volume: 54 Issue: 6 Pages: 2522-2535

    • DOI

      10.1021/ic5021302

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Finite Winding (H<sub>2</sub>O)<sub>12</sub> Chain Stabilized by One-Dimensional Coordination Polymer2014

    • Author(s)
      Shin-ichiro Noro, Kei Hasegawa, Kazuya Kubo, and Takayoshi Nakamura
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 87 Issue: 5 Pages: 623-625

    • DOI

      10.1246/bcsj.20140005

    • NAID

      130004153293

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Flexible Coordination Polymers Composed of Luminescent Ru(II)-Metalloligands : Importance of Position of Coordination Site in Metalloligands2014

    • Author(s)
      A.Kobayashi, T.Ohba, E.Saitoh, Y.Suzuki, S.-i.Noro, H.-C.Chang, M.Kato
    • Journal Title

      Inorg. Chem.

      Volume: 53 Issue: 6 Pages: 2910-2921

    • DOI

      10.1021/ic402683j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structures, CO2 adsorption, and dielectric properties of [Cu(II)2(R-benzoate)4(pyrazine)]∞ polymers (R = m-F, 2,3-F2, m-Cl, and m-CH3)2014

    • Author(s)
      Kiyonori Takahashi, Norihisa Hoshino, Takashi Takeda, Shin-ichiro Noro, Takayoshi Nakamura, Sadamu Takeda and Tomoyuki Akutagawa
    • Journal Title

      Dalton Transactions

      Volume: 43 Issue: 24 Pages: 9081-9089

    • DOI

      10.1039/c4dt00258j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Crystal Structures, Dielectric, and CO_2-Adsorption Properties of One-Dimensional [Cu(II)_2(Adamantane-1-carboxylate)_4(pyrazine)]_∞ Coordination Polymers with Polar Ligands2014

    • Author(s)
      Kiyonori Takahashi, Norihisa Hoshino, Shin-ichiro Noro, Takayoshi Nakamura, and Tomoyuki Akutagawa
    • Journal Title

      Science of Advanced Materials

      Volume: (In press)(掲載確定) Issue: 7 Pages: 1425-1431

    • DOI

      10.1166/sam.2014.1831

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Assembly and Ferroelectric Response of Benzenecarboxamides Bearing Multiple -CONHC14H29 Chains2014

    • Author(s)
      Yuta Shishido, Hayato Anetai, Takashi Takeda, Norihisa Hoshino, Shin-ichiro Noro, Takayoshi Nakamura, Tomoyuki Akutagawa
    • Journal Title

      J. Phys. Chem. C.

      Volume: 118 Issue: 36 Pages: 21204-21214

    • DOI

      10.1021/jp506035h

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Synthesis, structure, and host-guest properties of light metal coordination polymer using pyridine-N-oxide-based ligand2014

    • Author(s)
      Rika Ochi, Shin-ichiro Noro, Kazuya Kubo, Takayoshi Nakamura
    • Organizer
      The 15th Ries-Hokudai International Symposiym 響
    • Place of Presentation
      シャトレーゼガトーキングダムサッポロ(北海道札幌市)
    • Year and Date
      2014-12-16 – 2014-12-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 柔らかい金属錯体の合理的合成・制御法の開発と吸着・分離機能2014

    • Author(s)
      野呂真一郎
    • Organizer
      近畿大学錯体化学セミナー
    • Place of Presentation
      近畿大学(大阪府東大阪市)
    • Year and Date
      2014-11-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 表面固溶化法による金属錯体のゲスト分子吸着分離特性の精密制御2014

    • Author(s)
      野呂真一郎
    • Organizer
      2014年日本化学会中国四国支部大会
    • Place of Presentation
      山口大学(山口県山口市)
    • Year and Date
      2014-11-08 – 2014-11-09
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Rational Design and Realization of Ubiquitous and Biocompatible Metal-Based Porous Coordination Polymers2014

    • Author(s)
      Shin-ichiro Noro
    • Organizer
      Core-to-Core/Leverhulme Trust Joint Workshop, Sapporo 2014 “Organic Electronics of Highly-Correlated Molecular Systems”
    • Place of Presentation
      グランドパーク小樽(北海道小樽市)
    • Year and Date
      2014-10-24 – 2014-10-25
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Porous Light Metal Coordination Polymers with Charge-Polarized Neutral Ligand2014

    • Author(s)
      Shin-ichiro Noro, Junya Mizutani, Yuh Hijikata, Kazuya Kubo, Takayoshi Nakamura
    • Organizer
      4th International Conference on Metal-Organic Frameworks & Open Framework Compounds
    • Place of Presentation
      神戸コンベンションセンター(兵庫県神戸市)
    • Year and Date
      2014-09-28 – 2014-10-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] 電荷分極したピリジン-N-オキシド構造を有する配位子を用いた高分子状軽金属錯体の合成と構造2014

    • Author(s)
      越智里香、野呂真一郎、久保和也、中村貴義
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学(東京都文京区)
    • Year and Date
      2014-09-18 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 表面固溶化法による多孔性金属錯体の二酸化炭素吸着分離特性制御2014

    • Author(s)
      野呂真一郎、石橋秀規、久保和也、中村貴義
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学(東京都新宿区)
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] New Synthetic Strategy for Construction of Light Metal Porous Coordination Polymer2014

    • Author(s)
      Shin-ichiro Noro, Takayoshi Nakamura
    • Organizer
      41th International Conference on Coordination Chemistry
    • Place of Presentation
      Suntec city (Singapore)
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 電荷分極型中性配位子を用いた多孔性軽金属錯体の合成と吸着・分離特性2014

    • Author(s)
      野呂真一郎、水谷純也、土方優、久保和也、中村貴義
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(名古屋市千種区)
    • Related Report
      2013 Research-status Report
  • [Presentation] 高選択的ガス分離能を有する多孔性金属錯体の開発2014

    • Author(s)
      野呂真一郎
    • Organizer
      野口遵研究助成金講演会
    • Place of Presentation
      如水会館(東京都千代田区)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 特異構造を有する高分子状金属錯体のガス分離特性2014

    • Author(s)
      野呂真一郎
    • Organizer
      東京理科大学総合研究機構分子連関相乗系研究部門平成25年度成果報告会
    • Place of Presentation
      東京理科大学(東京都新宿区)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 電荷分極型中性配位子による軽金属錯体の構造多様化の試み2012

    • Author(s)
      水谷純也、野呂真一郎、久保和也、中村貴義
    • Organizer
      日本化学会北海道支部2012夏季研究発表会
    • Place of Presentation
      旭川工業高等専門学校(旭川市)
    • Related Report
      2012 Research-status Report
  • [Presentation] 電荷分極型中性配位子を有する多孔性軽金属錯体の合成と構造2012

    • Author(s)
      水谷純也、野呂真一郎、久保和也、中村貴義
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山市)
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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