Structural diversification of porous light metal complexes using charge-separated neutral ligands

• Project/Area Number: 24550068
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Hokkaido University
• Principal Investigator: NORO Shin-ichiro 北海道大学, 電子科学研究所, 准教授 (70373347)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000); Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
• Keywords: 多孔性材料 / 金属錯体 / 軽金属イオン / ガス分離 / 二酸化炭素 / 多孔性金属錯体 / 分離 / 柔軟性構造 / 吸着

Outline of Final Research Achievements

We performed the basic study on the design and synthesis of porous light metal complexes. It was revealed that the ligands with pyridine-N-oxide moieties are effective for the structural diversification of porous light metal complexes.

Research Products

• [Journal Article] Porous coordination polymers with ubiquitous and biocompatible metals and a neutral bridging ligand (2015)
  • Author(s): Shin-ichiro Noro, Junya Mizutani, Yuh Hijikata, Ryotaro Matsuda, Hiroshi Sato, Susumu Kitagawa, Kunihisa Sugimoto, Yasutaka Inubushi, Kazuya Kubo, and Takayoshi Nakamura
  • Journal Title: Nature Communications Volume: 6 Issue: 1 Pages: 5851-5851
  • DOI: 10.1038/ncomms6851
  • NAID: 120005745622
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Dynamic induction of enantiomeric excess from a prochiral azobenzene dimer under circularly polarized light (2015)
  • Author(s): K. Rijeesh, P. K. Hashim, Shin-ichiro Noro, and Nobuyuki Tamaoki
  • Journal Title: Chemical Science Volume: 6 Issue: 2 Pages: 973-980
  • DOI: 10.1039/c4sc01993h
  • NAID: 120005567743
  • Peer Reviewed / Open Access
• [Journal Article] Mesophases and Ionic Conductivities of Simple Organic Salts of M(m-Iodobenzoate) (M = Li+, Na+, K+, Rb+, and Cs+) (2015)
  • Author(s): Manami Endo, Yuta Nakane, Kiyonori Takahashi, Norihisa Hoshino, Takashi Takeda, Shin-ichiro Noro, Takayoshi Nakamura, and Tomoyuki Akutagawa
  • Journal Title: Journal of Physical Chemistry B Volume: 119 Issue: 4 Pages: 1768-1777
  • DOI: 10.1021/jp5112026
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Selective carbon dioxide adsorption of ε-Keggin-type zincomolybdate-based purely-inorganic 3D frameworks (2015)
  • Author(s): Zhenxin Zhang, Masahiro Sadakane, Shin-ichiro Noro, Toru Murayama, Takashi Kamachi, Kazunari Yoshizawa, and Wataru Ueda
  • Journal Title: Journal of Materials Chemistry A Volume: 3 Issue: 2 Pages: 746-755
  • DOI: 10.1039/c4ta05496b
  • Peer Reviewed / Open Access
• [Journal Article] Supramolecular cations of (m-halogenated-anilinium)(dibenzo[18]crown-6) in Keggin [SMo12O402−] polyoxometallates (2015)
  • Author(s): J. Xiong, K. Kubo, S. Noro, T. Akutagawa, and N. Nakamura
  • Journal Title: CrystEngComm. Volume: 17 Issue: 4 Pages: 856-861
  • DOI: 10.1039/c4ce01988a
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Three-dimensional Architectures of [MnIICrIII(oxalate)3]; Complexes with Cage Type Networks Surrounding Supramolecular Cations (2015)
  • Author(s): Toru Endo, Kazuya Kubo, Masashi Yoshitake, Shin-ichiro Noro, Norihisa hoshino, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: rystal Growth & Design Volume: 15 Issue: 3 Pages: 1186-1193
  • DOI: 10.1021/cg501560z
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Systematic Syntheses and Metalloligand Doping of Flexible Porous Coordination Polymers Composed of a Co(III)-Metalloligand (2015)
  • Author(s): Atsushi Kobayashi, Yui Suzuki, Tadashi Ohba, Tomohiro Ogawa, Takeshi Matsumoto, Shin-ichiro Noro, Ho-Chol Chang, and Masako Kato
  • Journal Title: Inorganic Chemistry Volume: 54 Issue: 6 Pages: 2522-2535
  • DOI: 10.1021/ic5021302
  • Peer Reviewed
• [Journal Article] Finite Winding (H₂O)₁₂ Chain Stabilized by One-Dimensional Coordination Polymer (2014)
  • Author(s): Shin-ichiro Noro, Kei Hasegawa, Kazuya Kubo, and Takayoshi Nakamura
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 87 Issue: 5 Pages: 623-625
  • DOI: 10.1246/bcsj.20140005
  • NAID: 130004153293
  • ISSN: 0009-2673, 1348-0634
  • Peer Reviewed
• [Journal Article] Flexible Coordination Polymers Composed of Luminescent Ru(II)-Metalloligands : Importance of Position of Coordination Site in Metalloligands (2014)
  • Author(s): A.Kobayashi, T.Ohba, E.Saitoh, Y.Suzuki, S.-i.Noro, H.-C.Chang, M.Kato
  • Journal Title: Inorg. Chem. Volume: 53 Issue: 6 Pages: 2910-2921
  • DOI: 10.1021/ic402683j
  • Peer Reviewed
• [Journal Article] Crystal structures, CO2 adsorption, and dielectric properties of [Cu(II)2(R-benzoate)4(pyrazine)]∞ polymers (R = m-F, 2,3-F2, m-Cl, and m-CH3) (2014)
  • Author(s): Kiyonori Takahashi, Norihisa Hoshino, Takashi Takeda, Shin-ichiro Noro, Takayoshi Nakamura, Sadamu Takeda and Tomoyuki Akutagawa
  • Journal Title: Dalton Transactions Volume: 43 Issue: 24 Pages: 9081-9089
  • DOI: 10.1039/c4dt00258j
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Crystal Structures, Dielectric, and CO_2-Adsorption Properties of One-Dimensional [Cu(II)_2(Adamantane-1-carboxylate)_4(pyrazine)]_∞ Coordination Polymers with Polar Ligands (2014)
  • Author(s): Kiyonori Takahashi, Norihisa Hoshino, Shin-ichiro Noro, Takayoshi Nakamura, and Tomoyuki Akutagawa
  • Journal Title: Science of Advanced Materials Volume: (In press)(掲載確定) Issue: 7 Pages: 1425-1431
  • DOI: 10.1166/sam.2014.1831
  • Peer Reviewed
• [Journal Article] Molecular Assembly and Ferroelectric Response of Benzenecarboxamides Bearing Multiple -CONHC14H29 Chains (2014)
  • Author(s): Yuta Shishido, Hayato Anetai, Takashi Takeda, Norihisa Hoshino, Shin-ichiro Noro, Takayoshi Nakamura, Tomoyuki Akutagawa
  • Journal Title: J. Phys. Chem. C. Volume: 118 Issue: 36 Pages: 21204-21214
  • DOI: 10.1021/jp506035h
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Presentation] Synthesis, structure, and host-guest properties of light metal coordination polymer using pyridine-N-oxide-based ligand (2014)
  • Author(s): Rika Ochi, Shin-ichiro Noro, Kazuya Kubo, Takayoshi Nakamura
  • Organizer: The 15th Ries-Hokudai International Symposiym 響
  • Place of Presentation: シャトレーゼガトーキングダムサッポロ（北海道札幌市）
  • Year and Date: 2014-12-16 – 2014-12-17
• [Presentation] 柔らかい金属錯体の合理的合成・制御法の開発と吸着・分離機能 (2014)
  • Author(s): 野呂真一郎
  • Organizer: 近畿大学錯体化学セミナー
  • Place of Presentation: 近畿大学（大阪府東大阪市）
  • Year and Date: 2014-11-21
  • Invited
• [Presentation] 表面固溶化法による金属錯体のゲスト分子吸着分離特性の精密制御 (2014)
  • Author(s): 野呂真一郎
  • Organizer: 2014年日本化学会中国四国支部大会
  • Place of Presentation: 山口大学（山口県山口市）
  • Year and Date: 2014-11-08 – 2014-11-09
  • Invited
• [Presentation] Rational Design and Realization of Ubiquitous and Biocompatible Metal-Based Porous Coordination Polymers (2014)
  • Author(s): Shin-ichiro Noro
  • Organizer: Core-to-Core/Leverhulme Trust Joint Workshop, Sapporo 2014 “Organic Electronics of Highly-Correlated Molecular Systems”
  • Place of Presentation: グランドパーク小樽（北海道小樽市）
  • Year and Date: 2014-10-24 – 2014-10-25
  • Invited
• [Presentation] Porous Light Metal Coordination Polymers with Charge-Polarized Neutral Ligand (2014)
  • Author(s): Shin-ichiro Noro, Junya Mizutani, Yuh Hijikata, Kazuya Kubo, Takayoshi Nakamura
  • Organizer: 4th International Conference on Metal-Organic Frameworks & Open Framework Compounds
  • Place of Presentation: 神戸コンベンションセンター（兵庫県神戸市）
  • Year and Date: 2014-09-28 – 2014-10-01
• [Presentation] 電荷分極したピリジン-N-オキシド構造を有する配位子を用いた高分子状軽金属錯体の合成と構造 (2014)
  • Author(s): 越智里香、野呂真一郎、久保和也、中村貴義
  • Organizer: 錯体化学会第64回討論会
  • Place of Presentation: 中央大学（東京都文京区）
  • Year and Date: 2014-09-18 – 2014-09-20
• [Presentation] 表面固溶化法による多孔性金属錯体の二酸化炭素吸着分離特性制御 (2014)
  • Author(s): 野呂真一郎、石橋秀規、久保和也、中村貴義
  • Organizer: 第65回コロイドおよび界面化学討論会
  • Place of Presentation: 東京理科大学（東京都新宿区）
  • Year and Date: 2014-09-03 – 2014-09-05
• [Presentation] New Synthetic Strategy for Construction of Light Metal Porous Coordination Polymer (2014)
  • Author(s): Shin-ichiro Noro, Takayoshi Nakamura
  • Organizer: 41th International Conference on Coordination Chemistry
  • Place of Presentation: Suntec city (Singapore)
  • Year and Date: 2014-07-21 – 2014-07-25
• [Presentation] 電荷分極型中性配位子を用いた多孔性軽金属錯体の合成と吸着・分離特性 (2014)
  • Author(s): 野呂真一郎、水谷純也、土方優、久保和也、中村貴義
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学（名古屋市千種区）
• [Presentation] 高選択的ガス分離能を有する多孔性金属錯体の開発 (2014)
  • Author(s): 野呂真一郎
  • Organizer: 野口遵研究助成金講演会
  • Place of Presentation: 如水会館（東京都千代田区）
  • Invited
• [Presentation] 特異構造を有する高分子状金属錯体のガス分離特性 (2014)
  • Author(s): 野呂真一郎
  • Organizer: 東京理科大学総合研究機構分子連関相乗系研究部門平成25年度成果報告会
  • Place of Presentation: 東京理科大学（東京都新宿区）
  • Invited
• [Presentation] 電荷分極型中性配位子による軽金属錯体の構造多様化の試み (2012)
  • Author(s): 水谷純也、野呂真一郎、久保和也、中村貴義
  • Organizer: 日本化学会北海道支部2012夏季研究発表会
  • Place of Presentation: 旭川工業高等専門学校（旭川市）
• [Presentation] 電荷分極型中性配位子を有する多孔性軽金属錯体の合成と構造 (2012)
  • Author(s): 水谷純也、野呂真一郎、久保和也、中村貴義
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山大学（富山市）