| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
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| Outline of Final Research Achievements |
In order to investigate various molecular transformations by visible light, we focused on synthesizing photoactive complexes composed of visible-light sensitizer and a reactive metal center linked by a bridging ligand. We focused on applying the photocatalysis to cross-coupling reactions and polymerization. The photoactive catalysts such as Ru(II)-polypyridyl-Pd monoacetato and -Pd monomethyl complexes were developed and applyed to cross-coupling reaction of cinnamyl alcohol with arenes and styrene polymerization, respectively. We studied the plausible reaction mechanism together with the basic photochemical properties of the photosensitizers and the photocatalysts.
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