| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
Luminescent transition metal complexes have been explored not only as the photosensitizers but also as the luminescent materials for light emitting diodes because of their phosphorescence and because the feasible control over the luminescent properties, molecular size, and solubility by applied ligands. In this research, a series of novel luminescent copper complexes having thiophenol derivatives was prepared. The photophysical measurements clarified that their luminescent properties are strongly affected by the coexisting pyridyl ligands. The research upon the luminescent copper halogeno coordination polymers reveals that the mixed-ligand coordination polymers work as antenna system with the specific combination of bridging ligands.
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