| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Outline of Final Research Achievements |
In order to obtain mixed-valent platinum and ruthenium one-dimensional chains containing redox-active ligands, platinum and ruthenium dinuclear complexes have been synthesized from amidate-hanging platinum mononuclear complexes. It was succeeded in introducing dioxolene ligands into amidate-bridged platinum and rhodium dinuclear complexes. It was also succeeded in obtaining ten kinds of novel one-dimensional chains formed by unbridged platinum and rhodium bonds, where four of them show paramagnetic.
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