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Interconversion between Naturally-derived Hydrogen Donors and Hydrogen with Renewability at Room Temperature under Atmospheric Pressure in Water

Research Project

Project/Area Number 24550077
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionOsaka University

Principal Investigator

SUENOBU Tomoyoshi  大阪大学, 工学(系)研究科(研究院), 助教 (90271030)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords触媒・化学プロセス / 水素 / 二酸化炭素排出削減 / 再生可能エネルギー / 金属錯体 / 分散型電力供給網 / 光エネルギー変換 / 反応機構 / 光物性 / 天然由来 / 過酸化水素 / 再生可能
Outline of Final Research Achievements

It is highly required to replace fossil fuels by sustainable, renewable, and clean energy resources such as hydrogen (H2). In spite of the availability and usefulness of H2, storage and transportation of H2 are seriously difficult, because H2 gas is explosive and its volumetric energy density is quite low. In high-pressure H2 tank systems, energy-consuming cryogenically-cooling equipment is required to store pressurized hydrogen in a liquid form. Hence, low-cost and energy-efficient storage of hydrogen is definitely needed for stationary and portable applications in the hydrogen-delivery infrastructure in a small-scale micro-grid for the electric power supply in the near future. In this context, catalytic dehydrogenation and hydrogenation reactions of organic and inorganic molecules, especially naturally-derived compounds, in a reversible way have been studied and made possible from the viewpoint of a hydrogen donor as sustainable and renewable energy resources.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (34 results)

All 2015 2014 2013 2012 Other

All Journal Article (17 results) (of which Peer Reviewed: 16 results,  Open Access: 4 results,  Acknowledgement Compliant: 6 results) Presentation (12 results) (of which Invited: 1 results) Book (1 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Catalytic hydrogen production from paraformaldehyde and water using an organoiridium complex2015

    • Author(s)
      Tomoyoshi Suenobu, Yusuke Isaka, Satoshi Shibata and Shunichi Fukuzumi
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 9 Pages: 1670-1672

    • DOI

      10.1039/c4cc06581f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Influence of pH on the decay of β-carotene radical cation in aqueous Triton X-100: A laser flash photolysis study2015

    • Author(s)
      Ali El-Agamey, Maha A. El-Hagrasy, Tomoyoshi Suenobu and Shunichi Fukuzumi
    • Journal Title

      J. Photochem. Photobiol. B

      Volume: 146 Pages: 68-73

    • DOI

      10.1016/j.jphotobiol.2015.02.026

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bottom-up and top-down methods to improve catalytic reactivity for photocatalytic production of hydrogen peroxide from water and dioxygen with a ruthenium complex and water oxidation catalysts2015

    • Author(s)
      Yusuke Isaka, Satoshi Kato, Dachao Hong, Tomoyoshi Suenobu, Yusuke Yamada, Shunichi Fukuzumi
    • Journal Title

      J. Mater. Chem. A

      Volume: 3 Issue: 23 Pages: 12404-12412

    • DOI

      10.1039/c5ta02446c

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Size-selective incorporation of donor-acceptor linked dyad cations into zeolite Y and long-lived charge separation2015

    • Author(s)
      Shunichi Fukuzumi, Akinori Itoh, Kei Ohkubo and Tomoyoshi Suenobu
    • Journal Title

      RSC Adv.

      Volume: 5 Issue: 56 Pages: 45582-45585

    • DOI

      10.1039/c5ra06165b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Long-Lived Charge Separation and Applications in Artificial Photosynthesis2014

    • Author(s)
      Shunichi Fukuzumi, Kei Ohkubo and Tomoyoshi Suenobu
    • Journal Title

      Acc. Chem. Res.

      Volume: 47 Issue: 5 Pages: 1455-1464

    • DOI

      10.1021/ar400200u

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formation of the Long-Lived Charge-Separated State of the 9-Mesityl-10-methylacridinium Cation Incorporated into Mesoporous Aluminosilicate at High Temperatures2014

    • Author(s)
      Shunichi Fukuzumi, Akinori Itoh, Tomoyoshi Suenobu and Kei Ohkubo,
    • Journal Title

      J. Phys. Chem. C.

      Volume: 118 Issue: 41 Pages: 24188-24196

    • DOI

      10.1021/jp508155u

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Catalytic oxidation of formic acid by dioxygen with an organoiridium complex2014

    • Author(s)
      Satoshi Shibata, Tomoyoshi Suenobu and Shunichi Fukuzumi
    • Journal Title

      Catal. Sci. Technol.

      Volume: 4 Issue: 10 Pages: 3636-3639

    • DOI

      10.1039/c4cy00957f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Long-lived Electron Transfer State of 2-Phenyl-4-(1-naphthyl)quinolinium Ion Incorporated into Nanosized Mesoporous Silica-alumina Acting as a Robust Photocatalyst in Water2013

    • Author(s)
      Yusuke Yamada
    • Journal Title

      Chem. Commun.

      Volume: 49 Issue: 45 Pages: 5132-5134

    • DOI

      10.1039/c3cc41575a

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Assembly and Stepwise Oxidation of Interpenetrated Coordination Cages Based on Phenothiazine2013

    • Author(s)
      Marina Frank, Jakob Hey, Ilker Balcioglu, Yu-Sheng Chen, Dietmar Stalke, Tomoyoshi Suenobu, Shunichi Fukuzumi, Holm Frauendorf and Guido H. Clever
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 52 Issue: 38 Pages: 10102-10106

    • DOI

      10.1002/anie.201302536

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Direct Synthesis of Hydrogen Peroxide from Hydrogen and Oxygen by Using a Water-Soluble Iridium Complex and Flavin Mononucleotide2013

    • Author(s)
      Satoshi Shibata, Tomoyoshi Suenobu and Shunichi Fukuzumi
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 52 Issue: 47 Pages: 12327-12331

    • DOI

      10.1002/anie.201307273

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Production of Hydrogen Peroxide as a Sustainable Solar Fuel from Water and Dioxygen2013

    • Author(s)
      Satoshi Kato, Jieun Jung, Tomoyoshi Suenobu and Shunichi Fukuzumi
    • Journal Title

      Energy Environ. Sci.

      Volume: 6 Issue: 12 Pages: 3756-3764

    • DOI

      10.1039/c3ee42815j

    • Related Report
      2013 Research-status Report
  • [Journal Article] Hydrogen Storage and Evolution Catalysed by Metal Hydride Complexes2013

    • Author(s)
      Shunichi Fukuzumi and Tomoyoshi Suenobu
    • Journal Title

      Dalton Trans.

      Volume: 42 Issue: 1 Pages: 18-28

    • DOI

      10.1039/c2dt31823g

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Formation of a long-lived electron-transfer state in mesoporous silica-alumina composites enhances photocatalytic oxygenation reactivity2012

    • Author(s)
      Shunichi Fukuzumi
    • Journal Title

      Proc. Natl. Acad. Sci. U. S. A.

      Volume: 109 Issue: 39 Pages: 15572-15577

    • DOI

      10.1073/pnas.1119994109

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Catalytic interconversion between hydrogen and formic acid at ambient temperature and pressure2012

    • Author(s)
      Yuta Maenaka, Tomoyoshi Suenobu, Shunichi Fukuzumi
    • Journal Title

      Energy & Environmental Science

      Volume: 5 Issue: 6 Pages: 7360-7367

    • DOI

      10.1039/c2ee03315a

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Water-soluble mononuclear cobalt complexes with organic ligands acting as precatalysts for efficient photocatalytic water oxidation2012

    • Author(s)
      Dachao Hong, Jieun Jung, Jiyun Park, Yusuke Yamada, Tomoyoshi Suenobu, Yong-Min Lee, Wonwoo Nam and Shunichi Fukuzumi
    • Journal Title

      Energy Environ. Sci.

      Volume: 5 Issue: 6 Pages: 7606-7616

    • DOI

      10.1039/c2ee21185h

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Borderline of One-Step Hydrogen Atom Transfer Versus Stepwise Sc^<3+>-Coupled Electron Transfer from Benzyl Alcohol Derivatives to a Non-Heme Iron(IV)-Oxo Complex2012

    • Author(s)
      Yuma Morimoto; Jiyun Park; Tomoyoshi Suenobu; Yong-min Lee; Wonwoo Nam; Shunichi Fukuzumi
    • Journal Title

      Inorganic Chemistry

      Volume: 51 Issue: 18 Pages: 10025-10036

    • DOI

      10.1021/ic3016723

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hydrogen Evolution from Aliphatic Alcohols and 1,4-Selective Hydrogenation of NAD+ Catalyzed by a [C,N] and a [C,C] Cyclometalated Organoiridium Complex at Room Temperature in Water2012

    • Author(s)
      Yuta Maenaka, Tomoyoshi Suenobu, and Shunichi Fukuzumi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Issue: 22 Pages: 9417-9427

    • DOI

      10.1021/ja302788c

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] シアノ架橋遷移金属多核錯体を水の酸化触媒として用いる水と酸素からの過酸化水素の光触媒生成反応2015

    • Author(s)
      井坂 祐輔・末延 知義・山田 裕介・福住 俊一
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      千葉/日本大学
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] サイズ制御したナノ粒子触媒を用いた水と酸素からの過酸化水素生成光触媒反応2014

    • Author(s)
      井坂祐輔・末延知義・山田裕介・福住俊一
    • Organizer
      第26回 配位化合物の光化学討論会
    • Place of Presentation
      東京/首都大学
    • Year and Date
      2014-08-06 – 2014-08-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高い太陽光エネルギー変換効率を有する水と酸素からの過酸化水素生成光触媒反応2014

    • Author(s)
      井坂祐輔、末延知義、福住俊一
    • Organizer
      日本化学会第94回春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機イリジウム錯体を触媒として用いる常温水中における補酵素NADHによるユビキノン補酵素類縁体の還元反応2014

    • Author(s)
      柴田悟志、末延知義、福住俊一
    • Organizer
      日本化学会第94回春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機イリジウム錯体を触媒とする含水溶媒中におけるギ酸による酸素の2電子および4電子還元反応2014

    • Author(s)
      柴田悟志、末延知義、福住俊一
    • Organizer
      日本化学会第94回春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機イリジウム錯体およびフラビン補酵素類縁体を触媒として用いる常圧水素と酸素からの過酸化水素生成反応機構2013

    • Author(s)
      柴田悟志、末延知義、福住俊一
    • Organizer
      錯体化学討論会
    • Place of Presentation
      沖縄
    • Related Report
      2013 Research-status Report
  • [Presentation] Toward Catalytic Interconversion between Hydrogen and Chemical Fuels with Metal Complexes at Ambient Temperature

    • Author(s)
      Tomoyoshi SUENOBU
    • Organizer
      錯体化学会 第62回討論会 シンポジウム
    • Place of Presentation
      富山大学 五福キャンパス(富山)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 水を電子源とする酸素の光触媒還元による選択的過酸化水素生成反応における酸の加速効果

    • Author(s)
      加藤 慧、末延知義、福住俊一
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京工業大学 大岡山キャンパス(東京都)
    • Related Report
      2012 Research-status Report
  • [Presentation] 常温水中における有機イリジウム錯体およびフラビン補酵素類縁体を触媒として用いる水素と酸素からの選択的過酸化水素生成反応

    • Author(s)
      柴田悟志、末延知義、福住俊一
    • Organizer
      第45回 酸化反応討論会
    • Place of Presentation
      名古屋市立大学病院(愛知県)
    • Related Report
      2012 Research-status Report
  • [Presentation] Acceleration effect of rare-earth metal ions on selective formation of hydrogen peroxide in photocatalytic reduction of dioxygen by water as an electron source

    • Author(s)
      KATO, Satoshi, SUENOBU, Tomoyoshi, FUKUZUMI, Shunichi
    • Organizer
      International Symposium on Rare Earths in 2012
    • Place of Presentation
      沖縄ハーバービュークラウンプラザ(沖縄県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 有機イリジウム錯体を触媒として用いる常温常圧水中におけるフラビン補酵素類縁体の水素による還元と選択的過酸化水素生成

    • Author(s)
      柴田悟志、末延知義、福住俊一
    • Organizer
      日本化学会 第93春季年会
    • Place of Presentation
      立命館大学 草津キャンパス(滋賀県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 有機イリジウム錯体または水酸化イリジウム共存下での水を電子源とする酸素の光還元反応による選択的過酸化水素生成

    • Author(s)
      加藤慧、末延知義、福住俊一
    • Organizer
      日本化学会 第93春季年会
    • Place of Presentation
      立命館大学 草津キャンパス(滋賀県)
    • Related Report
      2012 Research-status Report
  • [Book] 人工光合成 -システム構築に向けての最新技術動向と展望-2013

    • Author(s)
      末延知義、福住俊一
    • Total Pages
      264
    • Publisher
      シーエムシー出版株式会社
    • Related Report
      2013 Research-status Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www-etchem.mls.eng.osaka-u.ac.jp/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 研究室HP

    • URL

      http://www-etchem.mls.eng.osaka-u.ac.jp/

    • Related Report
      2013 Research-status Report
  • [Remarks] 研究室HP

    • URL

      http://www-etchem.mls.eng.osaka-u.ac.jp/

    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] 過酸化水素製造方法、過酸化水素製造用キットおよび燃料電池2012

    • Inventor(s)
      福住 俊一、末延 知義、加藤 慧、洪 達超
    • Industrial Property Rights Holder
      福住 俊一、末延 知義、加藤 慧、洪 達超
    • Industrial Property Rights Type
      特許
    • Filing Date
      2012-06-25
    • Acquisition Date
      2015-02-27
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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