| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Outline of Final Research Achievements |
In this study, we have succeeded in the syntheses of neutral Z-shaped heteropolynuclear Pt complexes and Pt-Fe complex bearing 1,1'-bis(diphenylphosphino)ferrocene as a redox-active ligand. Structures and photophysical properties of these complexes were elucidated. We have also succeeded in the syntheses of imidoylamidinato Pt(II) complexes by the reaction of [Pt(bpy)(RCN)2](2+) (R = Me, Et, Ph) generated in a nitrile solution with 1H-pyrazole-1-carboxamidine. These complexes exhibit bright yellow or yellow-green luminescence in the solid state and mechanochromic behavior.
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