| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Outline of Final Research Achievements |
Cyanamide ions are soft and sterically less demanding anions and act as versatile bridging ligands with a variety of coordination modes. This study aimed at development of novel cluster core expansion reactions of cyanamido-bridged small clusters to construct clusters with three-dimensional higher-order structures. The novel findings obtained in this study include (1) core expansion reaction of dinuclear ruthenium complex by linking terminal nitrogen atoms of cyanamido ligands, (2) observation of reversible coordination mode change between N,N- and N,N'-cyanamido ligands, and (3) cluster core transformation reactions from a tetranuclear palladium complex to tri- and pentanuclear clusters.
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