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Control of planar, axial and helical chiralities based on the asymmetric ring-closing metathesis

Research Project

Project/Area Number 24550121
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Synthetic chemistry
Research InstitutionOsaka Prefecture University

Principal Investigator

Kamikawa Ken  大阪府立大学, 理学(系)研究科(研究院), 教授 (40316021)

Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywordsasymmetric synthesis / 有機化学 / 面不斉 / 軸不斉 / らせん不斉 / 不斉閉環メタセシス / クロム錯体 / 閉環メタセシス / 不斉配位子
Outline of Final Research Achievements

The molybdenum-catalyzed asymmetric ring-closing metathesis (ARCM) of the various Cs-symmetric (π-arene)chromium substrates proceeded smoothly and the corresponding bridged planar-chiral (π-arene)chromium complexes were obtained in excellent yields with excellent enantioselectivity of up to >99% ee. With a proper substituent, such as N-indolyl or 1-naphthyl, at the 2-positions of the η6-1,3-diisopropenylbenzene ligands, both biarylic axial chirality and π-arene-based planar-chirality could be simultaneously induced in the ARCM products via the double desymmetrization. The axial chirality thus induced was retained even after the removal of the chromium-carbonyl fragment, and the metal-free axially chiral biaryl/heterobiaryl compounds were obtained in up to >99% ee with complete retention of the enantiomeric purity. The overall protocol presented in this report can be regarded as a novel method of catalytically preparing axially chiral heterobiaryls/biaryl

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (51 results)

All 2016 2015 2014 2013 2012 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 4 results) Presentation (39 results) (of which Int'l Joint Research: 5 results,  Invited: 6 results) Remarks (1 results)

  • [Journal Article] Stereoselective synthesis of N-arylindoles and related compounds with axially chiral N–C bond2016

    • Author(s)
      Kinoshita, S.; Kamikawa, K.
    • Journal Title

      Tetrahedron

      Volume: - Issue: 34 Pages: 1-6

    • DOI

      10.1016/j.tet.2015.11.053

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ring-Closing Metathesis of (η5-Alkenylcyclopentadienyl)(alkenylphosphine)manganese(I) Dicarbonyl Complexes2015

    • Author(s)
      Tseng, Y.-Y.; Kamikawa, K.; Wu, Q.; Takahashi, T.; Ogasawara, M.
    • Journal Title

      Adv. Synth. Catal.

      Volume: 357 Issue: 10 Pages: 2255-2264

    • DOI

      10.1002/adsc.201500343

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Simultaneous Induction of Axial and Planar-Chirality in Arene-Chromium Complexes by Molybdenum-Catalyzed Enantioselective Ring-Closing Metathesis2015

    • Author(s)
      K. Kamikawa, S. Arae, W.-Y. Wu, C. Nakamura, T. Takahashi, M. Ogasawara
    • Journal Title

      Chemistry-A European Journal

      Volume: 21 Issue: 13 Pages: 4954-4957

    • DOI

      10.1002/chem.201500226

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Double Helicene by a Palladium-Catalyzed Cross-Coupling Reaction: Structure and Pysical Properties2015

    • Author(s)
      Kashihara, H.; Asada, T.; Kamikawa, K.
    • Journal Title

      Chem. Eur. J.

      Volume: 21 Issue: 17 Pages: 6521-6527

    • DOI

      10.1002/chem.201500074

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Phosphine-Olefin Ligands Based on a Planar-Chiral(π-Arene)chromium Scaffold : Design, Synthesis, and Application in Asymmetric Catalysis2014

    • Author(s)
      M. Ogasawara, Y.-Y. Tseng, S. Arae, T. Morita, T. Nakaya, W.-Y. Wu, T. Takahashi, K. Kamikawa
    • Journal Title

      the Journal of the American Chemical Society

      Volume: 136 Issue: 26 Pages: 9377-9384

    • DOI

      10.1021/ja503060e

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Recent Development of Helicene Synthesis2014

    • Author(s)
      Kamikawa, K.
    • Journal Title

      J. Synth. Org. Chem. Jpn.

      Volume: 72 Pages: 58-67

    • NAID

      130003395371

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Recent Development of Helicene Synthesis2014

    • Author(s)
      Kamikawa, K
    • Journal Title

      J. Syn. Org. Chem. Jpn.

      Volume: 72 Pages: 58-67

    • NAID

      130003395371

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 暮らしの中のクロムから有機合成反応まで2014

    • Author(s)
      神川憲
    • Journal Title

      化学と教育

      Volume: 62

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Azahelicene N-Oxide by Palladium Catalyzed Direct C-H Annulation of the Pendant Z-Bromovinyl Side2013

    • Author(s)
      Kaneko, E.; Matsumoto, Y.; Kamikawa, K
    • Journal Title

      Chem. Eur. J.

      Volume: 19 Issue: 36 Pages: 11837-11841

    • DOI

      10.1002/chem.201302083

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Kinetic Resolution of Planar-Chiral (h6-Arene)chromium Complexes by Molybdenum-Catalyzed
Asymmetric Ring-Closing Metathesis2012

    • Author(s)
      Ogasawara, M.; Wu, W.-Y. Arae, S.;T.; Watanabe, S.; Morita, Takahashi, T.; Kamikawa, K.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51 Issue: 12 Pages: 2951-2955

    • DOI

      10.1002/anie.201108292

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Chemistry of Dynamic hapto6-(Arene)chromium Complexes2012

    • Author(s)
      Wu, W.-Y. ; Kamikawa, K.
    • Journal Title

      Bull. Jpn. Soc. Coord. Chem.

      Volume: 60 Pages: 24-31

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 鈴木-宮浦クロスカップリングを用いた新規ダブルヘリセン類の合成およびその物性2016

    • Author(s)
      柏原 仁志・麻田 俊雄・神川 憲
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] パラジウム触媒C-H活性化反応を活用したアリールカルバゾール類の合成2016

    • Author(s)
      宇和 紘志・曾 雅怡・神川 憲
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pd 触媒を用いた脱水素型C-Hカップリング反応によるアザヘリセン類の合成2016

    • Author(s)
      河野 兆治・松本 裕貴・神川 憲
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Development of Highly Efficient Planar-Chiral Phosphine-Olefin Ligands Based on Transition Metal Complexes and Their Application to Asymmetric Reactions2016

    • Author(s)
      TSENG, Ya-Yi; KAMIKAWA, Ken; TAKAHASHI, Tamotsu; OGASAWARA, Masamichi
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ir触媒を用いるビアリールカルボン酸クロライドとアルキンとの環化反応による置換ヘリセン類の合成2016

    • Author(s)
      傳 浩聡・永田 智也・神川 憲・三浦 雅博
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis the planar chiral phosphine-olefin ligand based on the transition metal scaffold and application in asymmetric catalysis2015

    • Author(s)
      TSENG, Ya-Yi; KAMIKAWA, Ken; TAKAHASHI, Tamotsu; OGASAWARA, Masamichi
    • Organizer
      The International Chemical Congress of PACIFIC BASIN SOCIETIES 2015 (PACIFICHEM 2015)
    • Place of Presentation
      Honolulu (America)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis the planar chiral phosphine-olefin ligand based on a transition metal scaffold and application in asymmetric catalysis2015

    • Author(s)
      KAMIKAWA, Ken; TSENG, Ya-Yi; TAKAHASHI, Tamotsu; OGASAWARA, Masamichi
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      リーガロイヤルホテル京都(京都府・京都市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Azahelicene by Palladium-Catalyzed Dehydrogenative C-H Coupling Reaction2015

    • Author(s)
      KONO, Choji; MATSUMOTO, Yuki, KAMIKAWA, Ken
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      リーガロイヤルホテル京都(京都府・京都市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Catalytic Asymmetric Synthesis of Axially Chiral Phosphinobiaryl by C-H Functionalization2015

    • Author(s)
      YASUDA, Rie; KAMIKAWA, Ken
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      リーガロイヤルホテル京都(京都府・京都市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Carbazoles by Palladium Catalyzed C-H Arylation2015

    • Author(s)
      UWA, Koji; TSENG, Ya-Yi Tseng; KAMIKAWA, Ken
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      リーガロイヤルホテル京都(京都府・京都市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ring-Closing Metathesis of (h5-Alkenylcyclopentadienyl) (Alkenylphophine)manganese(I) Dicarbonyl Complexes and Their Application to Asymmetric Reactions2015

    • Author(s)
      TSENG, Ya-Yi; KAMIKAWA, Ken; OGASAWARA, Masamichi; TAKAHASHI, Tamotsu;
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      リーガロイヤルホテル京都(京都府・京都市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 面不斉遷移金属錯体を基盤とするホスフィンーオレフィン配位子の設計および不斉触媒反応への応用2015

    • Author(s)
      チェン ヤーイー・神川憲・高橋保・小笠原正道
    • Organizer
      第5回CSJ化学フェスタ2015
    • Place of Presentation
      タワーホール船橋(東京都・江戸川区)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] パラジウム触媒下のクロスカップリング反応によりダブルヘリセンの合成および構造と物性2015

    • Author(s)
      柏原 仁志・麻田 俊雄・神川 憲
    • Organizer
      基礎有機化学討論会
    • Place of Presentation
      愛媛大学(愛媛県・松山市)
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of Planar Chiral Phosphine-Olefin Ligands Based on a Transition Metal Scaffold and Application in Asymmetric Catalysis2015

    • Author(s)
      TSENG, Ya-Yi; KAMIKAWA, Ken; TAKAHASHI, Tamotsu; OGASAWARA Masamichi
    • Organizer
      第116回 触媒討論会
    • Place of Presentation
      三重大学(三重県・津市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] パラジウム触媒C-H結合活性化反応によるN-アリールカルバゾールの合成2015

    • Author(s)
      宇和 紘志・曾 雅怡・神川 憲
    • Organizer
      第62回有機金属討論会
    • Place of Presentation
      関西大学(大阪府・吹田市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pd 触媒を用いた脱水素型C-Hカップリング反応によるアザヘリセン類の合成2015

    • Author(s)
      河野 兆治・松本 裕貴・神川 憲
    • Organizer
      第62回有機金属討論会
    • Place of Presentation
      関西大学(大阪府・吹田市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] モリブデン触媒不斉閉環メタセシスによる面不斉シクロペンタジエニル-マンガン錯体の触媒的不斉合成2015

    • Author(s)
      小笠原 正道・曾 雅怡・常 寧輝・呉 猜・呉 威毅・高橋 保・神川 憲
    • Organizer
      第62回有機金属討論会
    • Place of Presentation
      関西大学(大阪府・吹田市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] C-H官能基化による軸不斉ホスフィノビアリール類の触媒的不斉合成2015

    • Author(s)
      安田 理恵・神川 憲
    • Organizer
      第62回有機金属討論会
    • Place of Presentation
      関西大学(大阪府・吹田市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] エナンチオ選択的C-Hオレフィン化による軸不斉化合物の触媒的不斉合成2015

    • Author(s)
      安田理恵、神川憲
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2015-03-27 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] (πーアレーン)クロム錯体をプラットホームとした不斉閉環メタセシス反応によるP-キラルホスフィンの触媒的不斉合成2015

    • Author(s)
      小笠原正道、池端亮介、Ya-Yi Tseng、呉威毅、荒江祥江、安田理恵、高橋保、神川憲
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2015-03-27 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Syntehsis of Planar Chiral Phophine-Olefin Ligands Based on a Transition Metal Scaffold and Application in Asymmetric Catalysis2015

    • Author(s)
      Ya-Yi Tseng, Masamichi Ogasawara, Sachie Arae, Tamotsu Takahashi, Ken Kamikawa
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2015-03-27 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] ダブルヘリセン骨格に基づくねじれた多環芳香族炭化水素の合成と構造2015

    • Author(s)
      柏原仁志、神川憲
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2015-03-27 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Cpマンガン錯体におけるエンド型閉環メタセシス反応および不斉合成への応用2014

    • Author(s)
      チェンヤーイー、荒江祥江、ウチェン、神川憲、高橋保、小笠原正道
    • Organizer
      第61回有機金属化学討論会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Research-status Report
  • [Presentation] (ハプト6ーアレーン)クロム錯体をプラットホームとした不斉閉環メタセシス反応によるP-キラルホスフィンの触媒的不斉合成2014

    • Author(s)
      小笠原正道、荒江祥江、チェンヤーイー、池端亮介、呉威毅、高橋保、神川憲
    • Organizer
      第61回有機金属化学討論会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Research-status Report
  • [Presentation] ヘリセン骨格に基づいたねじれたグラフェンの合成2014

    • Author(s)
      柏原仁志、神川憲
    • Organizer
      第61回有機金属化学討論会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis of highly effeicent phosphine-olefin ligands based on planar-chiral (arene)chromium complex and their application to asymmetric reactions2014

    • Author(s)
      Ya-Yi Tsenga, Ken Kamikawa, Tamotsu Takahashi, Masamichi Ogasawara
    • Organizer
      248th ACS National Meeting and Exposition
    • Place of Presentation
      アメリカ、サンフランシスコ
    • Year and Date
      2014-08-10 – 2014-08-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis of Helicene by C-H Bond Activation Reaction2014

    • Author(s)
      Ken Kamikawa
    • Organizer
      41st International Conference of Coordination Chemistry
    • Place of Presentation
      シンガポール
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Phosphine-Olefin Lignads Based on a Planar-Chiral (p-Arene)Chromium Scaffold: Design, Synthesis, and Application in Asymmetric Catalysis2014

    • Author(s)
      Ya-Yi Tsenga, Ken Kamikawa, Tamotsu Takahashi, Masamichi Ogasawara
    • Organizer
      41st International Conference of Coordination Chemistry
    • Place of Presentation
      シンガポール
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] 面不斉遷移金属錯体を基軸とする立体選択的有機合成反応2014

    • Author(s)
      神川憲
    • Organizer
      第336回触媒化学センターコロキウム
    • Place of Presentation
      北海道大学触媒化学センター
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Endo-Mode Ring Closing Metathesis in Cp Manganese Complex2014

    • Author(s)
      Tseng, Y.-Y.; Kamikawa, K.; ,Takahashi, T.; Ogasawara, M.
    • Organizer
      第94日本化学会春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Catalytic Enantioselective Synthesis of Planar-Chiral (π-Arene) chromium Complexes by Mo-Catalyzed Ring-Closing Metathesis2014

    • Author(s)
      Wu, W.-Y.; Tseng, Y.-Y.; Arae, S.; Nakamura, C.; Morita, T.; Takahashi, T.; Ogasawara, M.; Kaikawa, K.
    • Organizer
      第94日本化学会春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 平面と非平面構造を合わせ持つ「ねじれたグラフェンシー ト」の合成2014

    • Author(s)
      柏原仁志、神川憲
    • Organizer
      第94日本化学会春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis of Helicences by C-H Bond Activation Reactions2013

    • Author(s)
      Kamikawa, K.
    • Organizer
      International Symposium on Catalyst and Fine Chemicals 2013 (C&FC2013)
    • Place of Presentation
      中国人民大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Control of Axially Chiral N-C Bond: Stereoselective Synthesis of Axially Chiral N-Aryl Indoles2013

    • Author(s)
      K. Kamikawa
    • Organizer
      日加国際交流シンポジウム:次世代の遷移金属触媒・合成反応プロセス
    • Place of Presentation
      滋賀
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 面不斉(η6-アレーン)クロム骨格を有するホスフィン―オレフィン二座配位子ライブラリーの構築と応用2013

    • Author(s)
      神川憲,仲谷岳志,森田友貴,曾雅怡,荒江祥永,呉威毅,高橋保,小笠原正道
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Related Report
      2012 Research-status Report
  • [Presentation] 不斉閉環メタセシスによるクロムアレーン錯体の非対称化を鍵とするC-N軸不斉化合物の不斉合成2013

    • Author(s)
      神川憲,中村千浩, 荒江祥永, 呉威毅, 高橋保, 小笠原正道
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Related Report
      2012 Research-status Report
  • [Presentation] パラジウム触媒を用いたZ-ブロモビニル側鎖の直接的C-H環化反応によるアザヘリセンN-オキシドの合成2013

    • Author(s)
      松本裕貴, 神川憲
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Related Report
      2012 Research-status Report
  • [Presentation] Stereoselective Synthesis of N-Aryl Indole and Related Compounds with Axially Chiral N-C by Planar Chiral (Arene)chromium Complexes2012

    • Author(s)
      K. Kamikawa
    • Organizer
      2nd International Conference on Molecular & Functional Catalysis (ICMFC-2)
    • Place of Presentation
      Sigapore
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Stereoselective Synthesis of N-Aryl Indole and Related Compounds with Axially Chiral N-C by Planar Chiral (Arene)chromium Complexes.2012

    • Author(s)
      K. Kamikawa
    • Organizer
      17th Malaysian Chemical Congress 2012
    • Place of Presentation
      Kuala Lumpur, Malaysia
    • Related Report
      2012 Research-status Report
    • Invited
  • [Remarks] 大阪府立大学 神川研究室

    • URL

      http://www.c.s.osakafu-u.ac.jp/~kamikawa/index.html

    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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