Development of Highly Active Self-Assembled Solid Catalysts
| Project/Area Number |
24550126
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | The Institute of Physical and Chemical Research |
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Principal Investigator |
YAMADA Yoichi M. A. 独立行政法人理化学研究所, 環境資源科学研究センター, 副チームリーダー (50317723)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
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| Keywords | ナノ粒子触媒 / 合金触媒 / カップリング反応 / 水素化反応 / 空気酸化反応 / アセタール化反応 / マイクロリアクター / 触媒膜 / 酸化反応 / 有機合成化学 / 固定化触媒 / 高分子金属触媒 / シリコン基板 / 有機金属化学 / 触媒 |
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| Outline of Final Research Achievements |
A variety of highly active supported catalyst was developed. A Co-Pd alloy nanoparticle catalyst was developed and applied to the aerobic oxidation of alcohols. A Ni-Ru-Pt-Au alloy nanoparticle catalysts were prepared and applied to the hydrogenation of alkenes bearing a functional group.
A self-assembled catalyst of a polymeric imidazole and Pd was applied to the Mizoroki-Heck reaction. The local structure of the catalyst was revealed with XAFS and some analyses.
A catalytic acid membrane-installed microflow reactor was prepared and applied to the acetal formnation.
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Report
(4 results)
Research Products
(55 results)
