Development of the oxidative asymmetric catalysis by using transition metal complexes
| Project/Area Number |
24550128
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | The Institute of Physical and Chemical Research |
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Principal Investigator |
SOHTOME Yoshihiro 独立行政法人理化学研究所, 袖岡有機合成化学研究室, 研究員 (50431888)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Keywords | 遷移金属錯体 / 酸化 / 酸素 / 有機合成化学 / 不斉触媒 / 遷移金属 / 不斉合成 |
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| Outline of Final Research Achievements |
In order to develop catalytic systems that can be applied to various asymmetric reactions, the development of catalytic reactions based on new concepts is significant. Here, we have successfully developed two distinct aerobic oxidative functionalizations of N-Boc oxindoles including α-hydroxylation and oxidative hetero carbon-carbon bond-forming reactions by exploiting use of our original Pd complex.
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Report
(4 results)
Research Products
(15 results)
