| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
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| Outline of Final Research Achievements |
In this study, we prepared chiral polysilsesquioxanes (PSQs) by introduction of chiral molecules, such as 1-phenylethyl isocyanates, into ammonium-group-containing ladder-like PSQ. Then, induction behavior of chirality was investigated from these chiral PSQs to anionic dye compounds, porphyrin and pyrene derivatives. In addition, we prepared carboxylate- and sulfonate-group-containing PSQs, which serve as a basis of anionic chiral ladder-like PSQs.
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