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Application of surface-enhanced infrared absorption spectroscopy to technologically important reactions at solid-liquid interfaces

Research Project

Project/Area Number 24550143
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials chemistry
Research InstitutionHokkaido University

Principal Investigator

OSAWA Masatoshi  北海道大学, 触媒化学研究センター, その他 (00108466)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords表面増強赤外分光 / 固液界面 / 電気化学 / 電極触媒 / バイオインターフェース / 脂質二分子膜 / 不斉合成触媒 / 反応機構 / 燃料電池 / 自己集積単分子 / 表面反応機構 / 第一原理計算 / 防錆油 / 界面活性剤
Outline of Final Research Achievements

Surface-enhanced infrared absorption spectroscopy (SEIRAS), based on an effect in which infrared absorption of molecules adsorbed on metal surfaces, has been demonstrated to be a very powerful tool in studying fundamental phenomena and reactions at the electrochemical interface at a molecular scale. This project aimed at expanding the application of SEIRAS to other solid/solution interfaces, especially to technologically important interfaces. The capability of SEIRAS has been demonstrated through the analyses of electrocatalytic formic acid/formate oxidation in direct fuel cells, the dynamics of solvated cations with electrified surfaces, structures and reactions of lipid bilayers and protein membranes, adsorption of corrosion inhibitors on metal surfaces, and others.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (82 results)

All 2015 2014 2013 2012 Other

All Journal Article (23 results) (of which Peer Reviewed: 21 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (56 results) (of which Invited: 18 results) Remarks (3 results)

  • [Journal Article] Effect of Hydrogen on The Orientation of Cinchonidine Adsorbed on Platinum: An ATR-SEIRAS Study2015

    • Author(s)
      K. Motobayashi, R. Tomioka, T. Uchida, and M. Osawa
    • Journal Title

      Chemistry Letters

      Volume: 44

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical and infrared spectroscopic study of the self-assembled monolayer of a cyano-bridged dimeric triruthenium complex on gold surface2014

    • Author(s)
      Zhang, H.; Sasaki, Y.; Abe, M.; Zhang, Y.; Ye, S.; Osawa, M.; Uosaki, K.
    • Journal Title

      J. Electroanal. Chem.

      Volume: 714-715 Pages: 51-55

    • DOI

      10.1016/j.jelechem.2013.12.012

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The effect of pH on the electrocatalytic oxidation of formic acid/formate on platinum: A mechanistic study by surface-enhanced infrared spectroscopy coupled with cyclic voltammetry2014

    • Author(s)
      J. Joo, T. Uchida, A. Cuesta, M.T.M. Koper, M. Osawa
    • Journal Title

      Electrochimica Acta

      Volume: 129 Pages: 127-136

    • DOI

      10.1016/j.electacta.2014.02.040

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Biomimetic Environment to Study E-coli Complex I through Surface-Enhanced IR Absorption Spectroscopy2014

    • Author(s)
      S. Kriegel, T. Uchida, M. Osawa, T. Friedrich, and P. Hellwig
    • Journal Title

      Biochemistry

      Volume: 53 Issue: 40 Pages: 6340-6347

    • DOI

      10.1021/bi500955a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 電極界面におけるイオンの水和殻崩壊過程の時間分解赤外分光観察2014

    • Author(s)
      山方啓, 大澤雅俊, 森田明弘
    • Journal Title

      Electrochemistry

      Volume: 82 Pages: 771-776

    • Related Report
      2014 Annual Research Report
  • [Journal Article] SEIRAS studies of water structure at the gold electrode surface in the presence of supported lipid bilayer2014

    • Author(s)
      T. Uchida, M. Osawa, J. Lipkowski
    • Journal Title

      J. Electroanal. Chem.

      Volume: 716 Pages: 51-55

    • DOI

      10.1016/j.jelechem.2013.10.015

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of the Cyano Complex of Oxo-Centered Triruthenium Core [Ru3(μ3-O)(μ-CH3COO)6(pyridine)2(CN)]2013

    • Author(s)
      Zhang, H.; Sasaki, Y.; Zhang, Y.; Ye, S.; Osawa, M.; Abe, M.; Uosaki, K.
    • Journal Title

      Inorg. Chem.

      Volume: 53 Issue: 3 Pages: 1288-1294

    • DOI

      10.1021/ic4012197

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preferential Adsorption of Solvents on Cathode Surface of Li-ion Batteries2013

    • Author(s)
      Yu, L.; Liu, H.; Wang, Y.; Kuwata, N.; Osawa, M.; Kawamura, J.; Ye, S.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 52 Issue: 22 Pages: 5753-5756

    • DOI

      10.1002/anie.201209976

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structure and Stability Studies of Mixed Monolayers of Saturated and Unsaturated Phospholipids under Low-level Ozone2013

    • Author(s)
      Qiao, L.; Ge, A.; Osawa, M.; Ye, S.
    • Journal Title

      Phys. Chem. Chem. Phys.,

      Volume: 15 Issue: 41 Pages: 17775-17785

    • DOI

      10.1039/c3cp52484a

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structure and Lateral Interaction in Mixed Monolayers of Dioctadecyldimethyl Ammonium Chloride (DOAC) and Stearyl Alcohol2013

    • Author(s)
      Ge, A.; Wu, H.; Darwish, T.; James, M.; Osawa, M.; Ye, S.
    • Journal Title

      Langmuir

      Volume: 29 Issue: 18 Pages: 5407-5417

    • DOI

      10.1021/la400143k

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Surface-enhanced infrared spectroscopic study of a CO-covered Pt electrode in room-temperature ionic liquid2013

    • Author(s)
      Y.-Y. Yang, L.-N. Zhang, M. Osawa, W.-B. Cai
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 4 Issue: 10 Pages: 1582-1586

    • DOI

      10.1021/jz400657t

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Stark effect on vibration frequencies of sulfate on Pt(111) electrode2013

    • Author(s)
      R. Jinnouchi, T. Hatanaka, Y. Morimoto, M. Osawa
    • Journal Title

      Electrochim. Acta

      Volume: 101 Pages: 254-261

    • DOI

      10.1016/j.electacta.2012.12.104

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural Changes of the KcsA Potassium Channel Upon Application of the Electrode Potential Studied by Surface-Enhanced IR Absorption Spectroscopy2013

    • Author(s)
      Akira Yamakata, Hirofumi Shimizu, Masatoshi Osawa, Shigetoshi Oiki
    • Journal Title

      Chemical Physics

      Volume: 419 Pages: 224-228

    • DOI

      10.1016/j.chemphys.2013.02.035

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Importance of acid-base equilibrium in electrocatalytic oxidation of formic acid on platinum2013

    • Author(s)
      J. Joo, T. Uchida, A. Cuesta, M. T. M. Koper, M. Osawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 27 Pages: 9991-9994

    • DOI

      10.1021/ja403578s

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Proton-Coupled Electron Transfer and Lewis Acid Recognition at Self-Assembled Monolayers of an Oxo-Bridged Diruthenium (III) Complex Functionalized with Two Disulfide Anchors2013

    • Author(s)
      Zhang,H.; Abe, M.; Zhang, Y.; Li, G.; Ye, S.; Osawa, M.; Sasaki, Y.
    • Journal Title

      Langmuir

      Volume: 29 Issue: 32 Pages: 10110-10119

    • DOI

      10.1021/la401736f

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Real-Time Observation of the Destruction of Hydration Shells2013

    • Author(s)
      Akira Yamakata, Eiji Soeta, Tatsuya Ishiyama, Masatoshi Osawa, and Akihiro Morita
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 40 Pages: 15033-15039

    • DOI

      10.1021/ja408326d

    • Related Report
      2013 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Adsorption and oxidation of glycine on Au electrode: An in situ surface-enhanced infrared study2013

    • Author(s)
      L.-C. Chen, T. Uchida, H.-C. Chang, M. Osawa
    • Journal Title

      Electrochem. Commun.

      Volume: 34 Pages: 56-59

    • DOI

      10.1016/j.elecom.2013.05.016

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hysteresis of potential-dependent of an ionic liquid on a gold electrode: In situ observation by surface-enhanced infrared absorption spectroscopy2013

    • Author(s)
      K. Motobayashi, K. Minami, N. Nishi, T. Sakka, M. Osawa
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 4 Issue: 18 Pages: 3110-3114

    • DOI

      10.1021/jz401645c

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Functional Group on the Monolayer Structures of Biodegradable Quaternary Ammonium Surfactants.2013

    • Author(s)
      Ge, A.; Peng, Q.; Wu, H.; Liu, H.; Tong, Y.; Nishida, T.; Yoshida, N.; Suzuki, K.; Sakai, T.; Osawa, M.; Ye, S.
    • Journal Title

      Langmuir

      Volume: 29 Issue: 47 Pages: 14411-14420

    • DOI

      10.1021/la403502k

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enzyme-Catalyzed Hydrolysis of the Phospholipid Bilayers Studied by Atomic Force Microscopy2013

    • Author(s)
      Wu, H.; Yu, L.; Tong, Y.; Ge, A.; Yau, Y.; Osawa, M.; Ye, S.
    • Journal Title

      Biochimica et Biophysica Acta (BBA) - Biomembranes

      Volume: 1828 Issue: 2 Pages: 642-651

    • DOI

      10.1016/j.bbamem.2012.09.010

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrooxidation of formic acid on gold: An ATR-SEIRAS study of the role of adsorbed formate2013

    • Author(s)
      A. Cuesta, G. Cabello, F. W. Hartl, M. Escudero-Escribano, C. Vaz-Dominguez, L. A. Kibler, M. Osawa, C. Gutierrez
    • Journal Title

      Catalysis Today,

      Volume: 202 Pages: 79-86

    • DOI

      10.1016/j.cattod.2012.04.022

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Mechanism of the electrocatalytic oxidation of formic acid on metals2012

    • Author(s)
      A. Cuesta, G. Cabello, M. Osawa, and C. Gutierrez,
    • Journal Title

      ACS Catalysis

      Volume: 2 Issue: 5 Pages: 728-738

    • DOI

      10.1021/cs200661z

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] In-situ振動分光法による電極界面の観察2012

    • Author(s)
      大澤雅俊
    • Journal Title

      Electrochemistry

      Volume: 80 Pages: 654-659

    • Related Report
      2012 Research-status Report
  • [Presentation] 金電極表面におけるギ酸酸化反応のpH依存性2015

    • Author(s)
      矢口 桃、大澤 雅俊
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学(神奈川県横浜市)
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 炭素薄膜表面における有機溶媒分子の吸着構造の解析2015

    • Author(s)
      彭 奇齢、大澤 雅俊、叶 深
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学(神奈川県横浜市)
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] イオン液体|電極界面の構造とその電位応答:溶媒和Liイオンの影響2015

    • Author(s)
      本林 健太、南 和也、内田 権一、西 直哉、作花 哲夫、大澤 雅俊
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学(神奈川県横浜市)
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Probing electrochemical interface by time-resolved surface-enhanced infrared absorption spectroscopy2015

    • Author(s)
      M. Osawa
    • Organizer
      IMPRS Workshop “Micro to Macto
    • Place of Presentation
      Schloss Ringberg, Tegernsee (Germany)
    • Year and Date
      2015-02-09 – 2015-02-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Mechanistic study of formic acid/formate electrooxidationon Pt over a wide pH range2014

    • Author(s)
      J. Joo, T. Uchida, A. Cuesta, M.T.M. Koper and M. Osawa
    • Organizer
      3rd Ertl Symposium on Surface Aanalysis and Dynamics
    • Place of Presentation
      Harnack House, Berlin (Germany)
    • Year and Date
      2014-11-09 – 2014-11-12
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Effect of pH on the electrocatalytic oxidation of formic acid/formate on Pt2014

    • Author(s)
      J. Joo, T. Uchida, A. Cuesta, M.T.M. Koper, M. Osawa
    • Organizer
      ECAT 2014 Explorations of the volcano landscape
    • Place of Presentation
      Fairmont Chateau Whistler, Whistler (Canada)
    • Year and Date
      2014-10-26 – 2014-10-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Electrochemical oxidation of CO adsorbed on poly-crystalline Pt in alkaline media studied by surface-enhanced infrared absorption spectroscopy2014

    • Author(s)
      J. Joo, M.T.M. Koper and M. Osawa
    • Organizer
      1st Gerischer-Kolb Symposium
    • Place of Presentation
      Harnack House, Berlin (Germany)
    • Year and Date
      2014-10-15 – 2014-10-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Probing water molecules at the electrochemical interface by surface-enhanced infrared absorption spectroscopy2014

    • Author(s)
      M. Osawa
    • Organizer
      Electrochem 2014 - Electrochemical Horizons
    • Place of Presentation
      Loughborough University, Loughborough (United Kingdom)
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Spectroscopic approach to fast and ultrafast dynamics at the electrochemical interface”, 65th Annual Meeting of International Electrochemistry2014

    • Author(s)
      M. Osawa
    • Organizer
      65th Annual Meeting of International Electrochemistry
    • Place of Presentation
      ETH Lausanne, Lausanne (Switzerland)
    • Year and Date
      2014-08-31 – 2014-09-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Potential-dependent Structure of Ionic Liquid/Electrode Interfaces: Effect of Additives studied by Surface-Enhanced Infrared Spectroscopy2014

    • Author(s)
      K. Motobayashi , K. Minami, N. Nishi, T. Sakka, and M. Osawa
    • Organizer
      65th Annual Meeting of International Electrochemistry
    • Place of Presentation
      ETH Lausanne, Lausanne (Switzerland)
    • Year and Date
      2014-08-31 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of pH on the electrocatalytic oxidation of formic acid/formate on Pd electrode studied by cyclic voltammetry and surface-enhanced infrared spectroscopy2014

    • Author(s)
      M. Yaguchi and M. Osawa
    • Organizer
      65th Annual Meeting of International Electrochemistry
    • Place of Presentation
      ETH Lausanne, Lausanne (Switzerland)
    • Year and Date
      2014-08-31 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pt/ionomer interface analysis using in-situ SEIRAS with solid-state electrochemical cell2014

    • Author(s)
      K. Kodama, K. Motobayashi, A. Shinohara, N. Hasegawa, R. Jinnouchi, H. Murata, T. Hatanaka, Y. Morimoto, M. Osawa
    • Organizer
      65th Annual Meeting of International Electrochemistry
    • Place of Presentation
      ETH Lausanne, Lausanne (Switzerland)
    • Year and Date
      2014-08-31 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] In-situ surface spectroscopy in electrocatalysis2014

    • Author(s)
      M. Osawa
    • Organizer
      Surface Electrochemistry: Towards Energy Research
    • Place of Presentation
      Eurotel-Victoria Hotel , Villars-sur-Olin (Switzerland)
    • Year and Date
      2014-08-25 – 2014-08-29
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Surface(-enhanced) infrared absorption spectroscopy and its application to electrochemistry2014

    • Author(s)
      M. Osawa
    • Organizer
      2014 Xiamen University Summer School
    • Place of Presentation
      Xiamen University, Xiamen (China)
    • Year and Date
      2014-07-14 – 2014-07-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Water and ions at the electrochemical interface studied by surface-enhanced infrared absorption spectroscopy2014

    • Author(s)
      A. Yamakata, K. Motobayashi, T. Ishino, A. Morita, M. Osawa
    • Organizer
      15th Topical Meeting of International Society of Chemistry
    • Place of Presentation
      Crowne Plaza Niagara Falls, Niagara Falls (Canada)
    • Year and Date
      2014-04-27 – 2014-04-29
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Application of SEIRAS to electrocatalysis2014

    • Author(s)
      M. Osawa
    • Organizer
      Pittcon 2014
    • Place of Presentation
      MaCormick Place (Chicago, USA)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] A polarization difference technique for surface-enhanced infrared absorption spectroscopy2014

    • Author(s)
      T. Uchida, T. Hasegawa, N. Osawa
    • Organizer
      Pittcon 2014
    • Place of Presentation
      MaCormick Place (Chicago, USA)
    • Related Report
      2013 Research-status Report
  • [Presentation] 表面増強赤外分光で観た電極触媒反応2014

    • Author(s)
      大澤雅俊
    • Organizer
      平成25年度日本表面科学会東北・北海道支部学術講演会
    • Place of Presentation
      東北大学片平北門会館 (仙台市青葉区)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Electrocatalytic reactions as probed by surface-enhanced infrared absorption specrtroscopy2014

    • Author(s)
      M. Osawa
    • Organizer
      Electrochemical Conference on Energy & the Environment
    • Place of Presentation
      Intercontinental Shanghai Puxi 5 (Shanghai, China)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Pd電極表面におけるギ酸酸化反応のpH依存性2014

    • Author(s)
      矢口桃,大澤雅俊
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 表面増強赤外分光法によるイオン液体|金電極界面構造の研究:水分の影響2014

    • Author(s)
      南和也,西直哉,本林健太,作花哲夫,大澤雅俊
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 表面増強赤外分光法によるイオン液体|金電極界面構造の研究:リチウム塩添加の影響2014

    • Author(s)
      南和也,西直哉,本林健太,作花哲夫,大澤雅俊
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 高感度反射赤外分光法で電極-電解液界面の水の正しいスペクトルが得られるか?2013

    • Author(s)
      大澤雅俊
    • Organizer
      第73回分析化学討論会
    • Place of Presentation
      北海道大学函館キャンパス(北海道函館市)
    • Related Report
      2013 Research-status Report
  • [Presentation] イオン液体|金属電極界面におけるカチオンの構造に与えるアニオン種の影響:表面増強赤外分光による解析2013

    • Author(s)
      南 和也、本林健太、大澤雅俊、西 直哉、作花哲夫
    • Organizer
      第73回分析化学討論会
    • Place of Presentation
      北海道大学函館キャンパス(北海道函館市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 金表面におけるCaスルフォネートの吸着-脱離挙動の表面増強性がい分光による解析2013

    • Author(s)
      田巻匡基、長瀬直樹、内田太郎、大澤雅俊
    • Organizer
      第73回分析化学討論会
    • Place of Presentation
      北海道大学函館キャンパス(北海道函館市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Importance of decoupled proton-electron transfer in electrocatalytic oxidation of formic acid/formate ion on Pt2013

    • Author(s)
      J. Joo, T. Uchida, A. Cuesta, M.T.M. Koper, M. Osawa
    • Organizer
      13th International Conference on Electrified Interface
    • Place of Presentation
      Chateau Liblice (Czech Republic)
    • Related Report
      2013 Research-status Report
  • [Presentation] Mechanistic study on electrocatalytic oxidation of formic acid and formate ion on platinum by cyclic voltammetry and SEIRAS2013

    • Author(s)
      J. Joo, T. Uchida, A. Cuesta, M.T.M. Koper, M. Osawa
    • Organizer
      16th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis
    • Place of Presentation
      北海道大学学術交流会館(札幌市北区)
    • Related Report
      2013 Research-status Report
  • [Presentation] Surface Reorganization of Polyrotaxanes Dectected by SFG Spectroscopy2013

    • Author(s)
      A. Ge, M. Osawa, S. Ye
    • Organizer
      7th International Conference on Advanced Vibrational Spectroscopy
    • Place of Presentation
      神戸コンベンションセンター(神戸市中央区)
    • Related Report
      2013 Research-status Report
  • [Presentation] フェロセンと水ならびに対イオンとの相互作用:赤外分光解析2013

    • Author(s)
      内田太郎、池庄司民夫、大澤雅俊
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2013 Research-status Report
  • [Presentation] フェロセンと水ならびに対イオンとの相互作用:第一原理動力学計算2013

    • Author(s)
      池庄司民夫、内田太郎、大澤雅俊
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2013 Research-status Report
  • [Presentation] Pt電極に吸着したopd水素のPt-H振動数の電位依存性2013

    • Author(s)
      石野嵩弥,内田太郎,本林健太,陣内亮典,大澤雅俊
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2013 Research-status Report
  • [Presentation] 固体表面における有機薄膜の界面分子構造ー和周波発生(SFG)振動分光法による検討2013

    • Author(s)
      叶深,葛愛民,喬琳,彭奇齢,大澤雅俊
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2013 Research-status Report
  • [Presentation] 気液界面における脂質単分子膜の構造及びその安定性2013

    • Author(s)
      叶深,喬琳,葛愛民,大澤雅俊
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2013 Research-status Report
  • [Presentation] 金属電極との界面におけるイオン液体の電位応答ヒステリシスとその起源:表面増強赤外分光法による検討2013

    • Author(s)
      本林健太,南和也,西直哉,作花哲夫,大澤雅俊
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2013 Research-status Report
  • [Presentation] 表面増強赤外分光法を用いた金薄膜表面上のCaスルホネートの観察2013

    • Author(s)
      長瀬直樹,田巻匡基,内田太郎,大澤雅俊
    • Organizer
      トライボロジー会議2013秋 福岡
    • Place of Presentation
      アクロス福岡(福岡市中央区)
    • Related Report
      2013 Research-status Report
  • [Presentation] Hysteresis of Potential-Dependent Changes in Ion Density and Orientation of Ionic Liquids On An Au Electrode: An Surface-Enhanced Infrared Study2013

    • Author(s)
      K. Motobayashi, K. Minami, N. Nishi, T. Sakka, M. Osawa
    • Organizer
      224th Electrochemical Society Meeting,
    • Place of Presentation
      Hilton San Francisco Hotel (San Francisco, USA)
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of pH on the electrocatalytic oxidation of HCOOH/HCOO- on platinum: A mechanistic study2013

    • Author(s)
      J. Joo, T. Uchida, A. Cuesta, M.T.M. Koper, and M. Osawa
    • Organizer
      224th Electrochemical Society Meeting,
    • Place of Presentation
      Hilton San Francisco Hotel (San Francisco, USA)
    • Related Report
      2013 Research-status Report
  • [Presentation] イオン液体|金属電極界面で見られる電位応答ヒステリシスの解析:表面増強赤外分光法によるin situ観測2013

    • Author(s)
      本林健太、南和也、西直哉、作花哲夫、大澤雅俊
    • Organizer
      電気化学会第80回大会
    • Place of Presentation
      東北大学(仙台市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Pt電極表面におけるギ酸/ギ酸イオンの酸化反応機構(1):実験2013

    • Author(s)
      J. Joo、内田太郎、A. Cuesta, Marc T. M. Koper、大澤雅俊
    • Organizer
      電気化学会第80回大会
    • Place of Presentation
      東北大学(仙台市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Pt電極表面におけるギ酸/ギ酸イオンの酸化反応機構(2):シミュレーション2013

    • Author(s)
      J. Joo、内田太郎、A. Cuesta, Marc T. M. Koper、大澤雅俊
    • Organizer
      電気化学会第80回大会
    • Place of Presentation
      東北大学(仙台市)
    • Related Report
      2012 Research-status Report
  • [Presentation] 電極界面の構造と反応の物理化学的研究2013

    • Author(s)
      大澤雅俊
    • Organizer
      電気化学会第80回大会
    • Place of Presentation
      東北大学(仙台市)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Water at electrofied interface probed by surface-enhanced infrared absorption spectroscopy (SEIRAS)2012

    • Author(s)
      M. Osawa
    • Organizer
      Eurasia 2012
    • Place of Presentation
      Chandris Hotel (ギリシャ・コルフ島)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Probing electrocatalytic reactions with surface-enhanced infrared absorption spectroscopy (SEIRAS)2012

    • Author(s)
      M. Osawa
    • Organizer
      RISE III Symposium
    • Place of Presentation
      Gwangju Institute of Science and Technology(韓国光州市)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Electrocatalytic oxidation of formate on Pt in nuetral and alkaline media studied by surface-enhanced infrared absorption spectrscopy (SEIRAS)2012

    • Author(s)
      J. Joo, T. Uchida, A. Cuesta, Marc T. M. Koper and M. Osawa
    • Organizer
      2nd Ertl Symposium
    • Place of Presentation
      Stuttgart Engineering Park (ドイツ・シュトットッガルト)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Electrocatalytic oxidation of formate ion on Pt: A combined electrochemical and SEIRAS study2012

    • Author(s)
      J. Joo, T. Uchida, A. Cuesta, Marc T. M. Koper and M. Osawa
    • Organizer
      63rd Annual Meeting of the International Sosciety of Electrochemistry
    • Place of Presentation
      Clarion Congress Hotel (チェコ・プラハ)
    • Related Report
      2012 Research-status Report
  • [Presentation] Innovation in spectroelectrochemistry made by surface-enhanced infrared absorption spectroscopy (SEIRAS)2012

    • Author(s)
      M. Osawa
    • Organizer
      International Symposium on Spectroelectrochemistry
    • Place of Presentation
      Hotel Konigshof Dresden (ドイツ・ドレスデン)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Surface-enhanced infrared absorption spectroscopy (SEIRAS) for in situ, real-time monotoring of electrocatalytic reactions2012

    • Author(s)
      M. Osawa
    • Organizer
      Vibrations at Surfaces 14
    • Place of Presentation
      ニチイ学館神戸ポートアイランドセンター(神戸市)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Interfacial Structures of Polyelectrolyte Multilayers –A Sum Frequency Generation (SFG) Vibrational Spectroscopy Study–2012

    • Author(s)
      A. Ge, K. Kadowaki, M. Matsusaki, M. Osawa, M. Akashi, S. Ye
    • Organizer
      Vibrations at Surfaces 14
    • Place of Presentation
      ニチイ学館神戸ポートアイランドセンター(神戸市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Slow Relaxation of Ionic Liquids at Metal Electrode Interfaces Studied by SEIRAS2012

    • Author(s)
      K. Motobayashi, N. Nishi, T. Kakiuchi, and M. Osawa
    • Organizer
      Vibrations at Surfaces 14
    • Place of Presentation
      ニチイ学館神戸ポートアイランドセンター(神戸市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Sum Frequency Generation (SFG) Study on Mixed Monolayers of Saturated and Unsaturated Phospholipids2012

    • Author(s)
      L. Qiao, M. Osawa, S. Ye
    • Organizer
      Vibrations at Surfaces 14
    • Place of Presentation
      ニチイ学館神戸ポートアイランドセンター(神戸市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Effect of pH on electrooxidation of formic acid/formate on platinum2012

    • Author(s)
      J. Joo, T. Uchida, A. Cuesta, Marc T. M. Koper and M. Osawa
    • Organizer
      PRiME 2012
    • Place of Presentation
      Hawaii Convention Center(アメリカ合衆国・ホノルル)
    • Related Report
      2012 Research-status Report
  • [Presentation] Electro-Oxidation of CO on Pt in Alkaline Media Studied by In Situ Surface-Enhanced Infrared Absorption Spectroscopy2012

    • Author(s)
      J. Joo, T. Uchida, A. Cuesta, Marc T. M. Koper and M. Osawa
    • Organizer
      PRiME 2012
    • Place of Presentation
      Hawaii Convention Center(アメリカ合衆国・ホノルル)
    • Related Report
      2012 Research-status Report
  • [Presentation] 表面増強赤外分光法を用いたイオン液体/金属電極界面の構造とダイナミクスの観測2012

    • Author(s)
      本林健太、南和也、西直哉、垣内隆、大澤雅俊
    • Organizer
      第32回表面科学学術講演会
    • Place of Presentation
      東北大学(仙台市)
    • Related Report
      2012 Research-status Report
  • [Presentation] 表面増強赤外分光法を用いた金属表面におけるシンコニジンの吸着構造の解明2012

    • Author(s)
      冨岡亮太、本林健太、内田太郎、大澤雅俊
    • Organizer
      第32回表面科学学術講演会
    • Place of Presentation
      東北大学(仙台市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Electrocatalytic reactionsstudied by surface-enhanced infrared absorption spectroscopy (SEIRAS)2012

    • Author(s)
      M. Osawa
    • Organizer
      International Symposium of Spectroscopical Society of Japan
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 表面増強赤外分光法で見たイオン液体|金電極界面の電位応答挙動2012

    • Author(s)
      本林健太、南和也、西直哉、垣内隆、大澤雅俊
    • Organizer
      第3回イオン液体討論会
    • Place of Presentation
      沖縄男女共同参画センター(那覇市)
    • Related Report
      2012 Research-status Report
  • [Remarks] 北海道大学触媒化学研究センター表面分子化学研究部門大澤研究室

    • URL

      http://www.cat.hokudai.ac.jp/osawa/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 北海道大学触媒化学研究センター表面分子化学部門大澤研究室

    • URL

      http://www.cat.hokudai.ac.jp/osawa/

    • Related Report
      2013 Research-status Report
  • [Remarks] 北海道大学触媒化学研究センター表面分子化学研究部門

    • URL

      http://www.cat.hokudai.ac.jp/osawa/

    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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