| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Outline of Final Research Achievements |
We prepared 2,2’-binaphthalene derivatives bearing asymmetric recognition sites at 8- and 8’-positions and asymmetric biaryl derivatives bearing various recognition sites at each aryl groups by cross coupling reactions based on palladium chemistry to develop previously reported symmetric 2,2’-binaphthalene derivatives having two recognition sites at symmetrical positions. In particular, recognition of pyrophosphate by the receptor at neutral condition by fluorescence spectroscopy has been successfully achieved.
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