Molecular recognition by ditopic receptors based on asymmtric biaryl moieties
| Project/Area Number |
24550144
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Yamagata University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | 分子認識 / ビアリール / クロスカップリング / アニオン認識 / カチオン認識 / クロモフォア / フルオロフォア / 認識部位 |
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| Outline of Final Research Achievements |
We prepared 2,2’-binaphthalene derivatives bearing asymmetric recognition sites at 8- and 8’-positions and asymmetric biaryl derivatives bearing various recognition sites at each aryl groups by cross coupling reactions based on palladium chemistry to develop previously reported symmetric 2,2’-binaphthalene derivatives having two recognition sites at symmetrical positions. In particular, recognition of pyrophosphate by the receptor at neutral condition by fluorescence spectroscopy has been successfully achieved.
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Report
(4 results)
Research Products
(38 results)
