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Rheology control of non-polar and low-polar solvents by using reverse wormlike micelles

Research Project

Project/Area Number 24550149
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials chemistry
Research InstitutionYokohama National University

Principal Investigator

ARAMAKI Kenji  横浜国立大学, 環境情報研究科(研究院), 准教授 (80313469)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords逆ひも状ミセル / 分子集合体 / 界面活性剤 / ブロックコポリマー / 粘弾性 / 小角X線散乱 / 増粘剤
Outline of Final Research Achievements

When dissolving the surafactant molecules in a non-polar or low-polar solvent, the reverse micelles are formed by aggregation of the hydrophilic group therein. It is possible to form reverse wormlike micelles having a length of μm order by changing the molecular structure of the surfactant used. When the reverse wormlike micelles are formed, thickening, gelation of the solution occurs. In this study, we used nonionic surfactants with which few studies have been done with respect to reverse wormlike micelles. We used rheological measurements and small-angle X-ray scattering measurements to understand the conditions of thickning or gelling of non-polar or low-polar solvents. As a result, we found that the molecular weight of surfactant and solubilization of a small amount of water are the important factors for the reverse wormlike micelle formation. The achievement of this research will be applicable for pharmaceutical and cosmetic formulation, fluid transport, lubrication and so on.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (4 results)

All 2014 2013

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (3 results) (of which Invited: 1 results)

  • [Journal Article] Manipulation of the viscosity behavior of wormlike micellar gels by changing the molecular structure of added perfumes2014

    • Author(s)
      Miho Kamada, Soichiro Shimizu, Kenji Aramaki
    • Journal Title

      Colloids and Surfaces A

      Volume: 458 Pages: 110-116

    • DOI

      10.1016/j.colsurfa.2014.01.003

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Preparation of Oil Gels with Polyoxybutylene Polyoxyethylene Pentaerythrityl Ether2014

    • Author(s)
      Kaoru Ohishi, Miho Kamada, Kenji Aramaki
    • Organizer
      1st Asian Conference on Oleo Science
    • Place of Presentation
      Royton Sapporo Hotel, Sapporo
    • Year and Date
      2014-09-08 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Manipulating Viscosity Behavior of Wormlike Micellar Solutions in Mixed Surfactant Systems2013

    • Author(s)
      Kenji Aramaki
    • Organizer
      5th Asian Conference on Colloid and Interface Science
    • Place of Presentation
      North Bengal University, India
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] ジペンタエリスリトール脂肪酸エステルの油中での逆ミセル形成2013

    • Author(s)
      大石郁, Lok Kumar Shrestha, 荒牧賢治
    • Organizer
      日本油化学会第52回年会
    • Place of Presentation
      東北大学
    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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