| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Outline of Final Research Achievements |
A molecular tripod consisting of a rigid adamantane core and three thiol legs undergoes three-point adsorption on gold surface to form a well-ordered self-assembled monolayer. Elongation of the adsorbed molecules of this monolayer was examined through cross-coupling reactions. The elongated molecules are capped with a terminal ferrocene or TEMPO group, which was electrochemically analyzed to determine the yield of the reaction. Yields of 80% and 30% were attained for the connection of ferrocene by single- and two-step Sonogashira coupling reactions, respectively.
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