Development and functionalization of polymer film possessing periodic structure

• Project/Area Number: 24550167
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Functional materials chemistry
• Research Institution: Sojo University
• Principal Investigator: TAMARU Shun-ichi 崇城大学, 工学部, 准教授 (10454951)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000); Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
• Keywords: 超分子化学 / 高分子膜 / 階層構造 / 多糖 / 刺激応答 / 界面重合 / 規則性高分子 / 電荷移動錯体 / 機能性高分子 / 界面化学 / 分子集積 / 分子センサ

Outline of Final Research Achievements

The interfacial Huisgen condensation between a hydrophilic viologen derivative and a hydrophobic porphyrin derivative gave an unique polymer film possessing well-defined square shape. The film was composed of the stacked thin films and had 100 nm thickness. Same reaction between a hydrophilic biphenyl derivative and a hydrophobic porphyrin derivative gave a thin film having large area. The thickness of the thin film found to be less than 20 nm.

Research Products

• [Journal Article] Supramolecular Assembly of Achiral Alkynylplatinum(II) Complexes and Carboxylic β-1,3-Glucan into Different Helical Handedness Stabilized by Pt-Pt and/or π-π Interactions (2015)
  • Author(s): Chung, Clive Yik-Sham; Tamaru, Shun-ichi; Shinkai, Seiji; Yam, Vivian Wing-Wah,
  • Journal Title: Chemistry A European journal Volume: 21 Issue: 14 Pages: 5447-5458
  • DOI: 10.1002/chem.201405035
  • Peer Reviewed
• [Journal Article] Creation of Circularly Polarized Luminescence from an Achiral Polyfluorene Derivative through Complexation with Helix-Forming Polysaccharides : Importance of the meta-Linkage Chain for Helix Formation (2014)
  • Author(s): Tomohiro SHIRAKI, Youichi TSUCHIYA, Takao NOGUCHI, Shun-ichi TAMARU, Mozomu SUZUKI, Makoto TAGUCHI, Michiya FUJIKI, Seiji SHINKAI
  • Journal Title: Chemistry- An Asian Journal Volume: 9 Issue: 1 Pages: 218-222
  • DOI: 10.1002/asia.201301216
  • Peer Reviewed
• [Journal Article] Giant Amino Acids Designed on the Polysaccharide Scaffold and Their Protein-Like Structural Interconversion (2014)
  • Author(s): Shun-ichi TAMARU, Daisuke TOKUNAGA, Kaori HORI, Sayaka MATSUDA, Seiji SHINKAI
  • Journal Title: Organic & Biomolecular Chemistry Volume: 12 Issue: 5 Pages: 815-822
  • DOI: 10.1039/c3ob41845f
  • Peer Reviewed
• [Journal Article] Dye-sensitized Preparation of Chiral Plasmonic Ag Nanoparticles on Helical Polysaccharides (2013)
  • Author(s): Youichi TSUCHIYA, Takao NOGUCHI, Daisuke YOSHIHARA, Tatsuhiro YAMAMOTO, Tomohiro SHIRAKI, Shun-ichi TAMARU, Seiji SHINKAI
  • Journal Title: Supramolecular Chemistry Volume: 25 Issue: 9-11 Pages: 748-755
  • DOI: 10.1080/10610278.2013.835049
  • Peer Reviewed
• [Journal Article] Creation of Chiral Thixotropic Gels through a Crown-Ammonium Interaction and their Application to a Memory-Erasing Recycle System (2012)
  • Author(s): Sobczuk, Adam A.; Tsuchiya, Youichi; Shiraki, Tomohiro; Tamaru, Shun-ichi; Shinkai, Seiji
  • Journal Title: Chemistry-A European Journal Volume: 18 Issue: 10 Pages: 2832-2838
  • DOI: 10.1002/chem.201103249
  • Peer Reviewed
• [Presentation] 規則性構造を持つ高分子薄膜の創成の試み (2015)
  • Author(s): 石田拓己・田丸俊一・新海征治
  • Organizer: 第64回高分子学会年次大会
  • Place of Presentation: 札幌コンベンションセンター（北海道、札幌市）
  • Year and Date: 2015-05-27 – 2015-05-29
• [Presentation] Study on preparation of highly ordered 2D polymer film by using liquid/liquid interfacial condensation (2014)
  • Author(s): Takumi Ishida, Shun-ichi Tamaru, Seiji Shinkai
  • Organizer: The 4th SOJO-UTP Joint Seminar on Nano and Bio Research
  • Place of Presentation: Perak (Malaysia)
  • Year and Date: 2014-08-21
• [Presentation] 界面Huisgen環化反応による二次元高分子膜形成に及ぼす分子の対称性の影響 (2014)
  • Author(s): 石田拓己・田丸俊一・新海征治
  • Organizer: 第５１回化学関連支部合同九州大会
  • Place of Presentation: 北九州国際会議場（福岡県、北九州市）
  • Year and Date: 2014-06-28
• [Presentation] 刺激応答ユニットを導入したカードラン誘導体の開発 (2014)
  • Author(s): 田丸俊一・新海征治・堀華織
  • Organizer: 日本化学会第94春期年会
  • Place of Presentation: 名古屋大学、愛知県名古屋市
• [Presentation] 側鎖修飾カードランの自己組織化挙動 (2014)
  • Author(s): 堀華織・石田拓己・田丸俊一・新海征治
  • Organizer: 日本化学会第94春期年会
  • Place of Presentation: 名古屋大学、愛知県名古屋市
• [Presentation] 水/イオン液体界面を利用した自己組織化 (2014)
  • Author(s): 片山理沙・石田拓己・新海征治・田丸俊一
  • Organizer: 日本化学会第94春期年会
  • Place of Presentation: 名古屋大学、愛知県名古屋市
• [Presentation] らせん性半人工分岐多糖の開発とその自己組織化挙動 (2014)
  • Author(s): 本崎弥夜美・田丸俊一・新海征治
  • Organizer: 日本化学会第94春期年会
  • Place of Presentation: 名古屋大学、愛知県名古屋市
• [Presentation] Giant amino acids designed on the polysaccharide scaffold and their protein-like structural interconversion (2013)
  • Author(s): Shun-ichi Tamaru, Seiji Shinkai
  • Organizer: New Trends of Nano- or Bio-materials Design in Supramolecular Chemistry
  • Place of Presentation: Kyushu University Centinial Hall, Fukuoka, Japan
  • Invited
• [Presentation] Self-assembling properties of semi-artificial curdlan derivatives (2013)
  • Author(s): Kaori Hori, Shun-ichi Tamaru, Seiji Shinkai
  • Organizer: The 26th International Symposium on Chemical Engineering
  • Place of Presentation: BEXCO, Busan, Koria
• [Presentation] 側鎖修飾カードランの自己組織化挙動 (2013)
  • Author(s): 堀 華織、田丸 俊一、新海 征治
  • Organizer: 日本化学会第９３春季年会
  • Place of Presentation: 草津
• [Presentation] 水/イオン液体界面を利用した自己組織化 (2013)
  • Author(s): 片山 理沙、田丸 俊一、 新海 征治
  • Organizer: 日本化学会第９３春季年会
  • Place of Presentation: 草津
• [Presentation] 含イミダゾリウム双頭型界面活性剤の自己組織化 (2012)
  • Author(s): 中垣 貴史、田丸 俊一、新海 征治
  • Organizer: 第49回化学関連支部合同九州大会
  • Place of Presentation: 福岡
• [Presentation] イオン液体複合型ナノ材料の開発研究 (2012)
  • Author(s): 片山 理沙、田丸 俊一、新海 征治
  • Organizer: 第49回化学関連支部合同九州大会
  • Place of Presentation: 福岡
• [Presentation] 界面重合反応を利用した機能性二次元高分子膜の研究開発 (2012)
  • Author(s): 平尾 みなみ、田丸 俊一、新海 征治
  • Organizer: 第49回化学関連支部合同九州大会
  • Place of Presentation: 福岡
• [Presentation] Self-assembly strategies for the construction of a hierarchical superstructure (2012)
  • Author(s): 田丸 俊一
  • Organizer: The 2nd SOJO-UTP Joint Seminar on NANO&BIO RESEARCH
  • Place of Presentation: マレーシア
• [Presentation] Development of nano materials containing ionic liquid (2012)
  • Author(s): R.Katayama,S.-i.Tamaru,S.Shinkai
  • Organizer: The 2nd SOJO-UTP Joint Seminar on NANO&BIO RESEARCH
  • Place of Presentation: マレーシア
• [Presentation] 自己組織化に基づく階層性超構造の構築 (2012)
  • Author(s): 田丸 俊一、新海 征治
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋
• [Presentation] 側鎖修飾カードランの自己組織化挙動
  • Author(s): 堀華織・田丸俊一・新海征治
  • Organizer: 高分子学会支部特別講演会
  • Place of Presentation: 鹿児島大学、鹿児島県鹿児島市
  • Invited
• [Presentation] イオン液体内包型ナノ超分子材料の開発研究
  • Author(s): 水野雄太・田丸俊一・新海征治
  • Organizer: 第50回化学関連支部合同九州大会
  • Place of Presentation: 北九州国際会議場、福岡県北九州市
• [Presentation] 側鎖修飾カードランの自己組織化挙動
  • Author(s): 堀華織・田丸俊一・新海征治
  • Organizer: 第50回化学関連支部合同九州大会
  • Place of Presentation: 北九州国際会議場、福岡県北九州市