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Creation of powder and film-like graphene and periodic mesoporous silica nanocomposite with vertically aligned mesochannels

Research Project

Project/Area Number 24550170
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials chemistry
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

WANG ZhengMing  独立行政法人産業技術総合研究所, 環境管理技術研究部門, 上級主任研究員 (10356610)

Co-Investigator(Kenkyū-buntansha) KUBO Shiori  (国立研究法人)産業技術総合研究所, 環境管理研究部門, 主任研究員 (20435770)
YOSHIZAWA Noriko  (国立研究法人)産業技術総合研究所, 創エネルギー研究部門, グループ長 (10358327)
Co-Investigator(Renkei-kenkyūsha) KANEKO Katsumi  信州大学, 特別特任教授 (20009608)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsグラフェン / 規則性メソポーラスシリカ / サンドイッチタイプ複合体 / 垂直ポア配向 / メソポーラスシリカ / サンドイッチ型複合体 / シリカ / 規則性メソポア / サンドイッチ複合構造 / 国際情報交換
Outline of Final Research Achievements

We have succeeded in synthesizing a novel nanocomposite which puts together the conductive graphene and non-conductive periodic mesoporous silica with the mesochannels vertically aligned towards graphene surface and reveals a good electrical conductivity. However, the formation mechanism of the nanocomposite structure has not been elucidated. In this investigation, we attempted to uncover the self-assembling mechanism of surfactants and/or organic silicon precursor on the surface of graphene oxide in the three components mixed solution by changing the synthesis conditions and by direct analysis on the micelle structure on carbon surface. We successfully find synthesis approaches to obtain the nanocomposite in which the silica film thickness was controlled and mesopore size was tuned.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (19 results)

All 2015 2014 2013 2012 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (15 results) (of which Invited: 6 results) Book (1 results)

  • [Journal Article] Synergetic photocatalysts derived from porous organo TiO clusters pillared graphene oxide frameworks (GOFs)2014

    • Author(s)
      梁 建波、王 正明、孫 明超、吉澤 徳子、川島 裕之
    • Journal Title

      RSC ADVANCES

      Volume: 4 Issue: 105 Pages: 60729-60732

    • DOI

      10.1039/c4ra12312c

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quiescent hydrothermal synthesis of reduced graphene oxide-periodic mesoporous silica sandwich nanocomposites with perpendicular mesochannel alignments2014

    • Author(s)
      Zheng-Ming Wang, Noriko Yoshizawa, Katsunori Kosuge, Wendong Wang, Geoffrey A. Ozin
    • Journal Title

      Adsorption

      Volume: 20 Issue: 2-3 Pages: 267-274

    • DOI

      10.1007/s10450-013-9584-6

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Mobile Crystalline Material-41 Doped with Titanium and Iron2014

    • Author(s)
      Bao-Wang Lu, Zheng-Ming Wang, Takahiro Hirotsu
    • Journal Title

      Adsorption Science & Technology

      Volume: 32(1) Issue: 1 Pages: 13-22

    • DOI

      10.1260/0263-6174.32.1.13

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Graphene-Periodic Mesoporous Silica Nanocomposite Sandwiches with Vertically Aligned and Size Tunable Mesochannels2015

    • Author(s)
      Peng Wenqin、王 正明、吉澤 徳子、G.A.Ozin
    • Organizer
      4th Symposium on Future Challenges for Carbon-based Nanoporous Materials
    • Place of Presentation
      長野
    • Year and Date
      2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synergetic photocatalysts derived from porous organo TiO clusters pillared graphene oxide frameworks2015

    • Author(s)
      梁 建波、王 正明、呉 浩怡,吉澤 徳子
    • Organizer
      4th Symposium on Future Challenges for Carbon-based Nanoporous Materials
    • Place of Presentation
      長野
    • Year and Date
      2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] グラフェンナノ複合体・分散体及びこれからの展開2015

    • Author(s)
      王 正明
    • Organizer
      第4回埼玉県ナノカーボン部会
    • Place of Presentation
      大宮
    • Year and Date
      2015-02-09
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Recent Progress on Reduced Graphene Oxide-Periodic Mesoporous Silica Sandwich Nanocomposites with Perpendicular Mesochannel Alignment2014

    • Author(s)
      Peng Wenqin、王 正明
    • Organizer
      2014 MRS fall meeting
    • Place of Presentation
      アメリカ ボストン
    • Year and Date
      2014-12-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fabrication and Environmental Applications of Nanostructured Materials2014

    • Author(s)
      王 正明
    • Organizer
      Symposium on Advanced Technologyies for Waste Water Reclamation and Reuse
    • Place of Presentation
      中国 北京
    • Year and Date
      2014-08-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Application of Nanocomposites of Reduced Graphene Oxide and Periodic Mesoporous Silica with Vertically Aligned Mesochannels2013

    • Author(s)
      Zheng-Ming Wang, Shigeru Kurosawa, Katsunori Kosuge, Shiori Kubo, Noriko Yoshizawa, Geoffrey A. Ozin
    • Organizer
      11th International Conference on the Fundamentals of Adsorption (FOA11)
    • Place of Presentation
      アメリカ バルチモア
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis and Characterization of Fe-Doped Ti-MCM-412013

    • Author(s)
      Bao-Wan Lu, Zheng-Ming Wang, Takahiro Hirotsu
    • Organizer
      11th International Conference on the Fundamentals of Adsorption (FOA11)
    • Place of Presentation
      アメリカ バルチモア
    • Related Report
      2013 Research-status Report
  • [Presentation] 炭素表面状態による規則性メソポーラスシリカ-グラフェンナノ複合構造変化2013

    • Author(s)
      王正明、小菅勝典、吉澤徳子、G. A. Ozin
    • Organizer
      第27回日本吸着学会研究発表会
    • Place of Presentation
      千葉
    • Related Report
      2013 Research-status Report
  • [Presentation] Nanocomposites of Reduced Graphene Oxide and Periodic Mesoporous Silica with Vertically Aligned Mesochannels2013

    • Author(s)
      Z. -M. Wang, K. Kosuge, N. Yoshizawa, Wendong Wang, and G. A. Ozin
    • Organizer
      第23回 日本MRS年次大会
    • Place of Presentation
      横浜
    • Related Report
      2013 Research-status Report
  • [Presentation] 垂直細孔配列メソ多孔体・グラフェンサンドイッチ複合体の合成2012

    • Author(s)
      王 正明、Wang Wendong、Coombs Neil、Soheinia Navid、Ozin G. A.
    • Organizer
      第26回日本吸着学会研究発表会
    • Place of Presentation
      産総研つくば中央共用講堂(茨城)
    • Related Report
      2012 Research-status Report
  • [Presentation] Nanocomposite of Reduced Graphene Oxide-Periodic Mesoporous Silica with Vertically Aligned Mesochannels2012

    • Author(s)
      王 正明、久保 史織、小菅 勝典、Ozin G. A.
    • Organizer
      The 6th Pacific Basin Conference on Adsorption Science and Technology
    • Place of Presentation
      台湾大学国際会議場(台湾・台北)
    • Related Report
      2012 Research-status Report
  • [Presentation] Reduced Graphene Oxide-Periodic Mesoporous Silica Sandwich Nanocomposites with Vertically Aligned Mesochannels2012

    • Author(s)
      王 正明、久保 史織、小菅 勝典、Ozin G. A.
    • Organizer
      The Third Symposium on Future Challenges for Carbon-Based Nanoporous Materials:Adsorption and Energy (CBNM-3)
    • Place of Presentation
      信州大学工学部講堂(長野)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 環境分野へのナノ材料の応用

    • Author(s)
      王 正明
    • Organizer
      Tsinghua University-Kyoto University Symposium on Research and Education of Environmental Engineering - The 4th GCOE/EML Shenzhen Symposium
    • Place of Presentation
      清華大学シンセンキャンパス講堂(中国・シンセン)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Graphene Nanocomposite Materials

    • Author(s)
      王 正明
    • Organizer
      第2回環境先進技術及び応用シンポジウム
    • Place of Presentation
      清華大学シンセンキャンパス講堂(中国・シンセン)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Structural Control and functional applications of Graphene Nanocomposites

    • Author(s)
      王 正明
    • Organizer
      Tsinghua-UD Workshop on Nanotechnology for Energy and Environment
    • Place of Presentation
      清華大学シンセンキャンパス講堂(中国・シンセン)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Book] グラフェン・コンポジット-炭素原子1個の薄さのシートによる社会・産業基幹材料の強靭化・高性能化- (監修 新谷 紀雄)2014

    • Author(s)
      湿式法によるグラフェンシート複合体の合成と有機汚染物の吸着・除去
    • Total Pages
      11
    • Publisher
      S&T出版
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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