• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Separation of ionic and electronic conductivity using all-solid-state thin-film battery techniques

Research Project

Project/Area Number 24550206
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials/Devices
Research InstitutionTohoku University

Principal Investigator

KUWATA Naoaki  東北大学, 多元物質科学研究所, 助教 (00396459)

Co-Investigator(Renkei-kenkyūsha) KAWAMURA Junichi  東北大学, 多元物質科学研究所, 教授 (50142683)
Research Collaborator KOBAYASHI Tetsuro  株式会社 豊田中央研究所, 環境・エネルギー2 部 固体イオニクス研究室, 室長
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywords混合伝導体 / リチウムイオン電池 / イオン伝導度 / 拡散係数 / 全固体電池 / 電子ブロッキング電極 / ノンストイキオメトリ / パルスレーザー堆積法 / 交流インピーダンス / 固体電解質 / 正極材料 / 不定比性 / インピーダンススペクトル / 固体イオニクス / 全固体リチウム電池 / コバルト酸リチウム / 薄膜電池
Outline of Final Research Achievements

We have developed electron-blocking electrodes using thin-film battery techniques to investigate ionic conductivity of thin-film cathode materials. The ionic conductivity of the cathode materials are essential factor which limits the performance of solid-state batteries. The electron-blocking electrodes were prepared from solid electrolytes and lithium thin films. The ionic and electronic conductivity of a thin-film lithium cobalt oxide were investigated. In addition, lithium deficient Li1-xCoO2 was prepared by chemical lithium extraction and the ionic and electronic conductivity was investigated by the same techniques.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (29 results)

All 2015 2014 2013 2012 Other

All Journal Article (10 results) (of which Peer Reviewed: 7 results,  Open Access: 4 results,  Acknowledgement Compliant: 1 results) Presentation (18 results) (of which Invited: 3 results) Book (1 results)

  • [Journal Article] Fabrication of solid-state thin-film batteries using LiMnPO4 thin films deposited by pulsed laser deposition2015

    • Author(s)
      Daichi Fujimoto, Naoaki Kuwata, Yasutaka Matsuda, Junichi Kawamura
    • Journal Title

      Thin Solid Films

      Volume: 579 Pages: 81-88

    • DOI

      10.1016/j.tsf.2015.02.041

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electrochemical effect of lithium tungsten oxide modification on LiCoO2 thin film electrode2015

    • Author(s)
      Tetsutaro Hayashi, Jiro Okada, Eiji Toda, Ryuichi Kuzuo, Yasutaka Matsuda, Naoaki Kuwata, Junichi Kawamura
    • Journal Title

      Journal of Power Sources

      Volume: 285 Pages: 559-567

    • DOI

      10.1016/j.jpowsour.2015.03.108

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of thin-film lithium batteries with 5-V-class LiCoMnO4 cathodes2014

    • Author(s)
      Naoaki Kuwata, Shota Kudo, Yasutaka Matsuda, Junichi Kawamura
    • Journal Title

      Solid State Ionics

      Volume: 262 Pages: 165-169

    • DOI

      10.1016/j.ssi.2013.09.054

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Nanoscale diffusion tracing by radioactive 8Li tracer2014

    • Author(s)
      H. Ishiyama, S.-C. Jeong, Y. Watanabe, Y. Hirayama, N. Imai, H. Miyatake, M. Oyaizu, I. Katayama, A. Osa, Y. Otokawa, M. Matsuda, K. Nishio, H. Makii, T. Sato, N. Kuwata, J. Kawamura, A. Nakao, H. Ueno, Y. H. Kim, S. Kimura, M. Mukai
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 11 Pages: 110303-110303

    • DOI

      10.7567/jjap.53.110303

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] The study of the lithium ion motion in β-alumina single crystal by NMR spectroscopy2014

    • Author(s)
      Mohammed Tareque Chowdhury, Reiji Takekawa, Yoshiki Iwai, Naoaki Kuwata, Junichi Kawamura
    • Journal Title

      Solid State Ionics

      Volume: 262 Pages: 482-485

    • DOI

      10.1016/j.ssi.2013.10.022

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Characterization of Lithium Borate and Lithium Silicate Thin-Films as a Solid Electrolyte for Thin-Film Battery2014

    • Author(s)
      Haruka Itabashi, Naoaki Kuwata, Daichi Fujimoto, Yasutaka Matsuda, Junichi Kawamura
    • Journal Title

      Proceedings of the 14th Asian Conference on Solid State Ionics (ACSSI 2014)

      Volume: 1 Pages: 587-594

    • DOI

      10.3850/978-981-09-1137-9_166

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Lithium ion diffusion in Li β-alumina single crystals measured by pulsed field gradient NMR spectroscopy2014

    • Author(s)
      Mohammed Tareque Chowdhury, Reiji Takekawa, Yoshiki Iwai, Naoaki Kuwata, Junichi Kawamura
    • Journal Title

      The Journal of chemical physics

      Volume: 140 (12) Issue: 12 Pages: 124509-124509

    • DOI

      10.1063/1.4869347

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preferential Adsorption of Solvents on the Cathode Surface of Lithium Ion Batteries2013

    • Author(s)
      Le Yu, Huijin Liu, Yan Wang, Naoaki Kuwata, Masatoshi Osawa, Junichi Kawamura, Shen Ye
    • Journal Title

      Angewandte Chemie

      Volume: 125 (22) Issue: 22 Pages: 5865-5868

    • DOI

      10.1002/ange.201209976

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Detection of Degradation in LiCoO2 Thin Films by in Situ Micro Raman Microscopy2013

    • Author(s)
      Naoaki Kuwata, Kazuki Ise, Yasutaka Matsuda, Junichi Kawamura, Takao Tsurui, Osamu Kamishima
    • Journal Title

      Solid State Ionics: Ionics for Sustainable World-Proceedings of the 13th Asian Conference.

      Volume: 1 Pages: 138-143

    • DOI

      10.1142/9789814415040_0017

    • ISBN
      9789814439909, 9789814415040
    • Related Report
      2013 Research-status Report
  • [Journal Article] DETECTION OF DEGRADATION IN LiCoO2 THIN FILMS BY IN SITU MICRO RAMAN MICROSCOPY2012

    • Author(s)
      Naoaki Kuwata, Kazuki Ise, Yasutaka Matsuda, Junichi Kawamura, Takao Tsurui, Osamu Kamishima
    • Journal Title

      Proceedings of the 13th Asian Conference on Solid State Ionics, Ionics for Sustainable World

      Volume: 2012 Pages: 138-143

    • Related Report
      2012 Research-status Report
  • [Presentation] 高電位正極を用いた全固体薄膜リチウム電池の作製2014

    • Author(s)
      桑田 直明, 藤本 大地, 工藤 将太, 松田 康孝, 河村 純一
    • Organizer
      第55回 電池討論会
    • Place of Presentation
      京都
    • Year and Date
      2014-11-19 – 2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] LiCoO2薄膜電極の表面修飾における電気化学的効果2014

    • Author(s)
      林徹太郎, 戸田英二, 西尾仁志, 松田康孝, 桑田直明, 河村純一
    • Organizer
      2014年電気化学秋季大会
    • Place of Presentation
      札幌
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 薄膜型固体電池の研究開発:5V級正極材料への適用2014

    • Author(s)
      桑田直明
    • Organizer
      光機能材料研究会 第 49回講演会, 次世代2次電池・太陽電池の材料開発と最新技術
    • Place of Presentation
      東京
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ホウ酸リチウム薄膜を固体電解質として用いた薄膜電池の特性2014

    • Author(s)
      板橋春佳, 松田康孝, 桑田直明, 河村純一
    • Organizer
      日本物理学会 2014年秋季大会
    • Place of Presentation
      愛知
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Solid-State Thin-Film Batteries with 5-V-Class Cathode Materials2014

    • Author(s)
      Naoaki Kuwata, Shota Kudo, Daichi Fujimoto, Yasutaka Matsuda, Junichi Kawamura
    • Organizer
      14th Asian Conference on Solid State Ionics (ACSSI-2014)
    • Place of Presentation
      Singapore, Singapore
    • Year and Date
      2014-06-24 – 2014-06-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Characterization of Lithium Borate and Lithium Silicate Thin-Films as a Solid Electrolyte for Thin-Film Battery2014

    • Author(s)
      Haruka Itabashi, Naoaki Kuwata, Daichi Fujimoto, Yasutaka Matsuda, Junichi Kawamura
    • Organizer
      14th Asian Conference on Solid State Ionics (ACSSI-2014)
    • Place of Presentation
      Singapore, Singapore
    • Year and Date
      2014-06-24 – 2014-06-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 5V級正極LiCoMnO4を用いた薄膜リチウム電池2013

    • Author(s)
      桑田 直明
    • Organizer
      第9回固体イオニクスセミナー
    • Place of Presentation
      下呂市
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] FABRICATION OF THIN-FILM LITHIUM BATTERY WITH 5V CLASS CATHODE LiCoMnO42013

    • Author(s)
      Naoaki Kuwata, Shota Kudo, Yasutaka Matsuda, Junichi Kawamura
    • Organizer
      The 19th International Conference on Solid State Ionics
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] SEPARATION OF ELECTRONIC AND IONIC CONDUCTIVITY IN LiCoO2 CATHODE BY AC IMPEDANCE ANALYSIS2013

    • Author(s)
      Erika Oki, Daichi Fujimoto, Yasutaka Matsuda, Naoaki Kuwata, Junichi Kawamura
    • Organizer
      6th Lithium Battery Discussion (LiBD-6 2013) – “Electrode Materials”
    • Place of Presentation
      Arcachon, France
    • Related Report
      2013 Research-status Report
  • [Presentation] Thin-film Lithium Battery with Amorphous Oxide Anode Fabricated by Pulsed Laser Deposition2013

    • Author(s)
      Taku Yoshida, Yasutaka Matsuda, Naoaki Kuwata, Junichi Kawamura
    • Organizer
      The 7th Asian Conference on Electrochemical Power Sources (ACEPS-7)
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] 5V級正極LiCoMnO4を用いた薄膜リチウム電池2013

    • Author(s)
      桑田直明, 工藤将太, 松田康孝, 河村純一
    • Organizer
      第63回 固体イオニクス研究会,第16回超イオン導電体物性研究会
    • Place of Presentation
      日立市
    • Related Report
      2013 Research-status Report
  • [Presentation] 透明電極を利用した全固体薄膜電池のin situ顕微ラマン分光2013

    • Author(s)
      桑田直明, 大川竜徳, 松田康孝, 河村純一
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島市
    • Related Report
      2013 Research-status Report
  • [Presentation] Diffusion Coefficient Measurement of Lithium Ion in β-Alumina Single Crystal by Pulsed Field Gradient NMR Spectroscopy2013

    • Author(s)
      M.T. Chowdhury, R. Takekawa, Y. Iwai, N. Kuwata, J. Kawamura
    • Organizer
      第39回 固体イオニクス討論会
    • Place of Presentation
      熊本市
    • Related Report
      2013 Research-status Report
  • [Presentation] SEPARATION OF ELECTRONIC AND IONIC CONDUCTIVITY IN LiCoO2 CATHODE BY AC IMPEDANCE ANALYSIS2012

    • Author(s)
      Daichi Fujimoto, Erika Oki, Yasutaka Matsuda, Naoaki Kuwata, Junichi Kawamura, Tetsuro Kobayashi, Takahiko Asaoka
    • Organizer
      13th Asian Conference on Solid State Ionics (ACSSI-2012)
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] DETECTION OF DEGRADATION IN LiCoO2 THIN FILMS BY IN SITU RAMAN MICROSCOPY2012

    • Author(s)
      Naoaki Kuwata, Kazuki Ise, Yasutaka Matsuda, Junichi Kawamura, Takao Tsurui, Osamu Kamishima
    • Organizer
      13th Asian Conference on Solid State Ionics (ACSSI-2012)
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] 正極薄膜LiCoO2のLi脱離とそのイオン伝導度測定2012

    • Author(s)
      沖 英里香, 藤本大地, 松田康孝, 桑田直明, 河村純一
    • Organizer
      日本物理学会 2012年秋季大会
    • Place of Presentation
      横浜
    • Related Report
      2012 Research-status Report
  • [Presentation] In-situ顕微ラマン分光法によるLiMn2O4薄膜のリチウム挿入脱離反応の研究2012

    • Author(s)
      大川 竜徳, 伊勢 一樹, 松田 康孝, 桑田 直明, 河村 純一
    • Organizer
      第38回 固体イオニクス討論会
    • Place of Presentation
      京都
    • Related Report
      2012 Research-status Report
  • [Presentation] 薄膜リチウム電池の作製とin situ測定

    • Author(s)
      桑田 直明
    • Organizer
      第25回 GREENオープンセミナー
    • Place of Presentation
      つくば
    • Related Report
      2012 Research-status Report
    • Invited
  • [Book] 高性能リチウムイオン電池開発最前線 5V級正極材料開発の現状と高エネルギー密度化への挑戦,第1編 高性能蓄電池開発のための基盤研究、第4章 リチウムイオン電池の in situ 劣化診断技術と高密度・高電圧蓄電池への応用2013

    • Author(s)
      河村 純一, 桑田 直明, 岩井 良樹, 水崎 純一郎, 佐藤 一永, 叶 深
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi