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Basic technology development of organic transistors for high-frequency-operating organic CMOS circuits

Research Project

Project/Area Number 24550211
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials/Devices
Research InstitutionKobe University

Principal Investigator

KITAMURA Masatoshi  神戸大学, 工学(系)研究科(研究院), 准教授 (10345142)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords有機トランジスタ / 薄膜トランジスタ / 移動度 / 閾値電圧 / 仕事関数 / 表面処理 / 表面修飾 / 有機半導体 / 単分子膜 / 電極表面修飾 / 界面制御
Outline of Final Research Achievements

The basic technology development for realization of high-frequency operating organic-transistor circuits leaded to the following achievement. Surface treatment for contact electrodes and optimization of fabrication process realized a high mobility of 3.3 cm2/Vs in organic transistors with bottom contact configuration that is easily applied to short channel transistors. Also, threshold voltage control in the range of a few V was demonstrated by oxygen plasma treatment. Furthermore, the work function and the thermal stability of surface-modified electrodes for low contact resistance were investigated. As a result, work functions in the range of 4.3 to 5.5 eV were obtained.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (35 results)

All 2015 2014 2013 2012

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 2 results) Presentation (30 results) (of which Invited: 4 results)

  • [Journal Article] Wettability Control of Gold Surfaces Modified with Benzenethiol Derivatives: Water Contact Angle and Thermal Stability2015

    • Author(s)
      Shingo Tatara, Yasutaka Kuzumoto, and Masatoshi Kitamura
    • Journal Title

      Journal of Nanoscience and Nanotechnology

      Volume: -

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structural and Electrical Properties of Fluorinated Copper Phthalocyanine toward Organic Photovoltaics: Post-Annealing Effect under Pressure2014

    • Author(s)
      Yasutaka Kuzumoto, Hirotaka Matsuyama, and Masatoshi Kitamura
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 4S Pages: 04ER16-04ER16

    • DOI

      10.7567/jjap.53.04er16

    • NAID

      210000143725

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Partially Fluorinated Copper Phthalocyanine toward Band Engineering for High-Efficiency Organic Photovoltaics2014

    • Author(s)
      Yasutaka Kuzumoto, Hirotaka Matsuyama, and Masatoshi Kitamura
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 1S Pages: 01AB03-01AB03

    • DOI

      10.7567/jjap.53.01ab03

    • NAID

      210000143261

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Work Function of Gold Surfaces Modified using Substituted Benzenethiols: Reaction Time Dependence and Thermal Stability2014

    • Author(s)
      Yasutaka Kuzumoto, Hirotaka Matsuyama, and Masatoshi Kitamura
    • Journal Title

      Applied Physics Express

      Volume: 7 Issue: 3 Pages: 35701-35701

    • DOI

      10.7567/apex.7.035701

    • NAID

      210000137038

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Short-Channel, High-Mobility Organic Thin-Film Transistors with Alkylated Dinaphthothienothiophene2013

    • Author(s)
      Masatoshi Kitamura, Yasutaka Kuzumoto, and Yasuhiko Arakawa
    • Journal Title

      physica status solidi (c)

      Volume: 10 Issue: 11 Pages: 1632-1635

    • DOI

      10.1002/pssc.201300245

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Operational Stability in Pentacene Thin-Film Transistors with Threshold Voltages Tuned by Oxygen Plasma Treatment2015

    • Author(s)
      Yoshinari Kimura, Masatoshi Kitamura, and Yasuhiko Arakawa
    • Organizer
      5th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies
    • Place of Presentation
      Niigata, Japan
    • Year and Date
      2015-06-16 – 2015-06-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] ベンゼンチオール誘導体による修飾表面の濡れと安定性2015

    • Author(s)
      鈩 信吾,北村 雅季
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機薄膜トランジスタの研究開発と実用化に向けた展望2015

    • Author(s)
      北村雅季
    • Organizer
      電子情報通信学会総合大会
    • Place of Presentation
      滋賀
    • Year and Date
      2015-03-10 – 2015-03-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Wettability Control of Gold Surfaces Modified with Benzenethiol Derivatives2014

    • Author(s)
      Shingo Tatara and Masatoshi Kitamura
    • Organizer
      11th International Conference on Nano-Molecular Electronics
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      2014-12-17 – 2014-12-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機薄膜トランジスタの閾値電圧制御:集積回路応用に向けて2014

    • Author(s)
      木村由斉,北村雅季,荒川泰彦
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] ベンゼンチオール誘導体を用いた金属表面の濡れ性制御2014

    • Author(s)
      鈩信吾,葛本恭崇,北村雅季
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] ジナフトチエノチオフェン骨格を有するn型有機トランジスタ材料の設計2014

    • Author(s)
      見塚翔太, 北村 雅季
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pentacene Thin-Film Transistors with Controlled Threshold Voltages and Their Application to Pseudo CMOS Inverters2014

    • Author(s)
      Yoshinari Kimura, Masatoshi Kitamura, and Yasuhiko Arakawa
    • Organizer
      International conference on Solid State Devices and Materials
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Annealing Effect on Field-Effect Mobilities in Bottom-Contact Alkylated Dinaphthothienothiophene Transistors2014

    • Author(s)
      Masatoshi Kitamura, Yasutaka Kuzumoto, and Yasuhiko Arakawa
    • Organizer
      International conference on Solid State Devices and Materials
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Threshold voltage control in organic thin-film transistors by oxygen plasma treatment2014

    • Author(s)
      Yoshinari Kimura, Masatoshi Kitamura, and Yasuhiko Arakawa
    • Organizer
      第33回電子材料シンポジウム
    • Place of Presentation
      静岡
    • Year and Date
      2014-07-09 – 2014-07-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Solution-processed organic thin-film transistors2014

    • Author(s)
      Masatoshi Kitamura
    • Organizer
      6th Asian Coating Workshop
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      2014-05-08 – 2014-05-09
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 閾値電圧制御された有機トランジスタから成る擬似CMOS回路2014

    • Author(s)
      木村 由斉,北村 雅季,荒川泰彦
    • Organizer
      第61応用物理学関係連合講演会
    • Place of Presentation
      神奈川
    • Related Report
      2013 Research-status Report
  • [Presentation] 表面処理電極を有するボトムコンタクト型アルキルDNTTトランジスタ2014

    • Author(s)
      北村 雅季, 木村 由斉, 荒川泰彦
    • Organizer
      第61応用物理学関係連合講演会
    • Place of Presentation
      神奈川
    • Related Report
      2013 Research-status Report
  • [Presentation] フッ素化銅フタロシアニンの膜構造および電気的特性へのアニール効果2014

    • Author(s)
      葛本 恭崇,松山 弘賢,北村 雅季
    • Organizer
      第61応用物理学関係連合講演会
    • Place of Presentation
      神奈川
    • Related Report
      2013 Research-status Report
  • [Presentation] Fine tuning of energy levels in partially fluorinated copper phthalocyanine for organic photovoltaics2013

    • Author(s)
      Yasutaka Kuzumoto, Hirotaka Matsuyama, and Masatoshi Kitamura
    • Organizer
      40th Int. Sym. on Compound Semiconductors
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Threshold Voltage Control in Pentacene Thin-Film Transistors by Oxygen Plasma Treatment2013

    • Author(s)
      Yoshinari Kimura, Kazuma Katsuki, Masatoshi Kitamura, and Yasuhiko Arakawa
    • Organizer
      40th Int. Sym. on Compound Semiconductors
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Short-Channel, High-Mobility Organic Thin-Film Transistors with Alkylated Dinaphthothienothiophene2013

    • Author(s)
      Masatoshi Kitamura, Yasutaka Kuzumoto, and Yasuhiko Arakawa
    • Organizer
      40th Int. Sym. on Compound Semiconductors
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Structural and Electrical Properties of Fluorinated Copper Phthalocyanine for Organic Photovoltaics2013

    • Author(s)
      Yasutaka Kuzumoto, Hirotaka Matsuyama, and Masatoshi Kitamura
    • Organizer
      International Conference on Solid State Devices and Materials
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Thermal Stability of Short Channel, High-Mobility Organic Thin-Film Transistors having Bottom-Contact Configuration2013

    • Author(s)
      Masatoshi Kitamura and Yasuhiko Arakawa
    • Organizer
      International Conference on Solid State Devices and Materials
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機トランジスタは実用化されるか ~ 若手研究者に向けて~2013

    • Author(s)
      北村雅季
    • Organizer
      第4回 有機分子・バイオエレクトロニクスの未来を拓く若手研究者討論会
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] ボトムコンタクト型アルキルDNTT 薄膜トランジスタの安定性評価2013

    • Author(s)
      北村雅季,荒川泰彦
    • Organizer
      第74回応用物理学会学術講演会
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
  • [Presentation] 酸素プラズマ処理による有機トランジスタの閾値電圧精密制御2013

    • Author(s)
      木村 由斉, 香月 一真, 北村 雅季, 荒川 泰彦
    • Organizer
      第74回応用物理学会学術講演会
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
  • [Presentation] 擬似CMOS 回路への応用に向けた有機薄膜トランジスタの閾値電圧制御2013

    • Author(s)
      木村 由斉, 北村 雅季, 荒川 泰彦
    • Organizer
      薄膜材料デバイス研究会 第10回研究集会
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
  • [Presentation] Dinaphthothienothiophene Thin-Film Transistors with Aluminum/Molybdenum Oxide Electrodes2013

    • Author(s)
      Masatoshi Kitamura and Yasuhiko Arakawa
    • Organizer
      7th Int. Conf. Molecular Electronics and Bioelectronics (M&BE7)
    • Place of Presentation
      Fukuoka
    • Related Report
      2012 Research-status Report
  • [Presentation] 酸素プラズマ処理による有機薄膜トランジスタの閾値電圧制御2013

    • Author(s)
      木村由斉,香月一真,田中翼,北村雅季,荒川泰彦
    • Organizer
      第60応用物理学関係連合講演会
    • Place of Presentation
      神奈川
    • Related Report
      2012 Research-status Report
  • [Presentation] 酸化モリブデン/アルミ電極を有するアルキルDNTT薄膜トランジスタ2013

    • Author(s)
      香月一真,木村由斉,田中翼,北村雅季,荒川泰彦
    • Organizer
      第60応用物理学関係連合講演会
    • Place of Presentation
      神奈川
    • Related Report
      2012 Research-status Report
  • [Presentation] Dinaphtho Thieno Thiophene Thin-Film Transistors with Modified Platinum Electrodes in Bottom-Contact Configuration2012

    • Author(s)
      Masatoshi Kitamura, Yoku Tanaka, Woogun Kang, Yasuhiko Arakawa
    • Organizer
      International Conference on Solid State Devices and Materials (SSDM 2012)
    • Place of Presentation
      Kyoto
    • Related Report
      2012 Research-status Report
  • [Presentation] 高移動度ボトムコンタクト型アルキルDNTT薄膜トランジスタ2012

    • Author(s)
      北村雅季,田中 翼,康 宇建,荒川泰彦
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Related Report
      2012 Research-status Report
  • [Presentation] ボトムコンタクト型DNTT薄膜トランジスタの大気安定性2012

    • Author(s)
      田中 翼,北村雅季,康 宇建,荒川泰彦
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Related Report
      2012 Research-status Report
  • [Presentation] 高性能有機CMOS回路-高速動作はどこまで可能か-2012

    • Author(s)
      北村雅季,荒川泰彦
    • Organizer
      薄膜材料デバイス研究会 第9回研究集会「薄膜デバイスの未来」
    • Place of Presentation
      奈良
    • Related Report
      2012 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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