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Development of tunable luminescent materials consisting of liquid-crystalline gold complexes

Research Project

Project/Area Number 24550217
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials/Devices
Research InstitutionRitsumeikan University

Principal Investigator

TSUTSUMI OSAMU  立命館大学, 生命科学部, 教授 (00313370)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords錯体 / 発光 / 液晶 / 金錯体 / サーモクロミズム / 親金相互作用
Outline of Final Research Achievements

In this study, luminescent materials with tunable functions have been developed. Especially, gold(I) complexes with liquid crystallinity were and the structure of molecular aggregation in the material was controlled to enhance the functions. It became clear that we can design the materials with liquid crystallinity in wide temperature range by optimization of the aspect ration of molecules. Furthermore, we found that in this gold complete system the luminescence was enhanced in an order aggregation (Order Enhanced Emission), and that the luminescence was also enhanced in aggregation with helical structure (Helicity Enhanced Emission).

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (58 results)

All 2015 2014 2013 2012 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (43 results) (of which Invited: 10 results) Remarks (4 results)

  • [Journal Article] Tuning the photoluminescence of condensed-phase cyclic trinuclear Au(I) complexes through control of their aggregated structures by external stimuli2015

    • Author(s)
      Kaori Fujisawa, Shigeyuki Yamada, Yukihiro Yanagi, Yasunori Yoshioka, Ayumi Kiyohara, Osamu Tsutsumi
    • Journal Title

      Sci. Rep.

      Volume: 5 Issue: 1 Pages: 79341-79347

    • DOI

      10.1038/srep07934

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effects of molecular structure and aggregated structure on photoluminescence properties of liquid-crystalline gold(I) complexes with various aromatic rings2015

    • Author(s)
      Osama Younis, Yuki Rokusha, Nana Sugimoto, Kaori Fujisawa, Shigeyuki Yamada, Osamu Tsutsumi
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 印刷中

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Tuning the photoluminescence of condensed-phase cyclic trinuclear Au(I) complexes through control of their aggregated structures by external stimuli2015

    • Author(s)
      Kaori Fujisawa, Shigeyuki Yamada, Yukihiro Yanagi, Yasunori Yoshioka, Ayumi Kiyohara, Osamu Tsutsumi
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 印刷中

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Reversible thermal-mode control of luminescence from liquid-crystalline gold(I) complexes2014

    • Author(s)
      Kaori Fujisawa, Yuki Okuda, Yuichi Izumi, Akira Nagamatsu, Yuki Rokusha, Yusuke Sadaike, Osamu Tsutsumi
    • Journal Title

      J. Mater. Chem. C

      Volume: 2 Issue: 18 Pages: 3549-3555

    • DOI

      10.1039/c3tc31973c

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photoluminescent Gold(I) Complex with Biphenyl Acetylene Ligand Showing Stable Nematic Liquid-Crystalline Phase2014

    • Author(s)
      Nana Sugimoto, Sho Tamai, Kaori Fujisawa, Osamu Tsutsumi
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 601 Pages: 97-106

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, liquid-crystalline behavior, and photoluminescence properties of novel Au(I) complex with naphthalene ring in a mesogenic core2014

    • Author(s)
      Yuki Rokusha, Nana Sugimoto, Shigeyuki Yamada, Osamu Tsutsumi
    • Journal Title

      Proc. SPIE

      Volume: 9182 Pages: 9182061-9182069

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoluminescent Gold(I) Complex with Biphenyl Acetylene Ligand Showing Stable Nematic Liquid-Crystalline Phase2014

    • Author(s)
      NANA SUGIMOTO, SHO TAMAI, KAORI FUJISAWA, OSAMU TSUTSUMI
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 印刷中

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Morphological Control of Gold Nanoparticle Aggregates via Photoisomerization of Azobenzene Liquid Crystals.2013

    • Author(s)
      Kaori Fujisawa, Asuna Kuranari, Koji Ota, Osamu Tsutsumi.
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 583 Issue: 1 Pages: 21-28

    • DOI

      10.1080/15421406.2013.843817

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photoluminescent Properties of Liquid Crystalline Gold(I) Isocyanide Complexes with a Rod-Like Molecular Structure2013

    • Author(s)
      Kaori Fujisawa, Naoya Kawakami, Yusuke Onishi, Yuichi Izumi, Sho Tamai, Nana Sugimoto, and Osamu Tsutsumi
    • Journal Title

      J. Mater. Chem. C

      Volume: 1 Issue: 34 Pages: 5359-5366

    • DOI

      10.1039/c3tc31105h

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure and Phase Transition Behavior of Dioctadecyldimethylammonium Chloride Monohydrate.2012

    • Author(s)
      Kenjiro Uno, and Osamu Tsutsumi.
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 563 Pages: 58-66

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Liquid-Crystalline Behavior and Photoluminescence Properties of Gold(I) Complex with Isocyanide Ligand: Relationship between Aggregation Structure and Properties.2012

    • Author(s)
      Kaori Fujisawa, Yuichi Izumi, Akira Nagamatsu, Kenjiro Uno, and Osamu Tsutsumi.
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 563 Pages: 50-57

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 環状金錯体のポリモルフィズムを利用した発光サーモクロミック特性2014

    • Author(s)
      中里仁哉,山田重之,堤 治
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      タワーホール船掘(東京都・江戸川区)
    • Year and Date
      2014-10-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Photoluminescence Behavior of Liquid-Crystalline Copolymer Containing Gold Complexes2014

    • Author(s)
      Osama Younis, Shigeyuki Yamada, Osamu Tsutsumi
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      タワーホール船掘(東京都・江戸川区)
    • Year and Date
      2014-10-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] ポリオキソメタレートとデンドリマー型有機分子を用いた新規複合材料の創製と評価2014

    • Author(s)
      渡邉亮平,山田重之,堤 治
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      タワーホール船掘(東京都・江戸川区)
    • Year and Date
      2014-10-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] 4-(4-アルキルピペラジン)フェニルイソシアニド配位子を有する液晶性金錯体の発光挙動2014

    • Author(s)
      六車有貴,山田重之,堤 治
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      タワーホール船掘(東京都・江戸川区)
    • Year and Date
      2014-10-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Emission Behavior of Liquid-Crystalline Copolymers Containing Cyanobiphenyl Mesogen and Gold Complexes in Side Chain2014

    • Author(s)
      Osama Younis, Shigeyuki Yamada, Osamu Tsutsumi
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス(長崎県・長崎市)
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] デンドリマー型有機分子を導入したポリオキソメタレートの相転移挙動2014

    • Author(s)
      渡邉亮平,山田重之,堤 治
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス(長崎県・長崎市)
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Full-Color Luminescence from a Single Liquid-Crystalline Gold Complex2014

    • Author(s)
      Osamu Tsutsumi, Osama M. Younis, Masakazu Tamaru, Sho Tamai, Nana Sugimoto, Kaori Fujisawa
    • Organizer
      2014 SPIE Optics + Photonics
    • Place of Presentation
      San Diego (USA)
    • Year and Date
      2014-08-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Full-Color Luminescence from Liquid Crystalline Gold Complexes: Reversible Control of Luminescent Color.

    • Author(s)
      Osamu Tsutsumi, Masakazu Tamaru, Sho Tamai, Nana Sugimoto, Kaori Fujisawa.
    • Organizer
      International Workshop on Soft and Flexible Micro/Nano Systems Technology (SF-MINAS2013)
    • Place of Presentation
      Gold Coast, QLD, Australia
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Color-Tunable Photoluminescence Emitted from Liquid Crystalline Gold Complexes

    • Author(s)
      Osamu Tsutsumi, Masakazu Tamaru, Sho Tamai, Nana Sugimoto, Kaori Fujisawa.
    • Organizer
      The 17th International Symposium
on Advanced Display Materials and Devices (ADMD2013)
    • Place of Presentation
      Shanghai, China
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Reversible Control of Luminescent Color from Liquid–Crystalline Gold(I) Complexes

    • Author(s)
      Osamu Tsutsumi
    • Organizer
      2013 International Symposium on Nano Science and Technology, Southern Taiwan University of Science and Technology
    • Place of Presentation
      台南,Taiwan
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 光駆動液晶材料のアクチュエータへの展開

    • Author(s)
      堤治
    • Organizer
      第1回調和ナノマイクロシステム技術研究会
    • Place of Presentation
      キャンパスプラザ京都(京都府)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] キラル液晶相における金錯体の発光特性

    • Author(s)
      杉本菜々,玉井翔,藤澤香織,堤治
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館(京都府)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Tunable Full-Color Luminescence from Liquid-Crystalline Gold Complexes

    • Author(s)
      Osamu Tsutsumi
    • Organizer
      Photophysique et Photochimie Supramoleculaires et Macromolecularies (PPSM) Seminar
    • Place of Presentation
      Cachan, France
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Liquid-Crystalline Gold Complexes as a Full-Color Luminescent Material

    • Author(s)
      Osamu Tsutsumi
    • Organizer
      UDS-IPCMS-JSPS Joint Seminar
    • Place of Presentation
      Strasbourg, France
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] ソフト・ハード融合材料の階層的構造制御による高機能化

    • Author(s)
      堤 治
    • Organizer
      資源研セミナー
    • Place of Presentation
      東京工業大学資源化学研究所, 神奈川県
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Full Color Luminescence from a Single Material: Photoluminescence Behavior of Liquid-Crystalline Gold Complexes

    • Author(s)
      Osaum Tsutsumi, Masakazu Tamaru, Sho Tamai, Kaori Fujisawa
    • Organizer
      XXV International Conference on Organometallic Chemistry (XXV ICOMC)
    • Place of Presentation
      Lisbon, Portugal
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 大環状ポリオキソモリブデートと液晶性有機分子の融合による凝集構造制御

    • Author(s)
      津守達啓,堤治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス,滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] 大環状ポリオキソモリブデート/有機分子複合体の電気化学特性評価

    • Author(s)
      清原亜祐実,西田匠汰,津守達啓,堤治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス,滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] 共有結合により有機分子を導入したポリオキソタングステートの合成と機能

    • Author(s)
      柴田佳典,河田悠紀夫,堤治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス,滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] 液晶性環状三核金錯体の相転移を利用した発光色制御

    • Author(s)
      田丸雅一,藤澤香織,堤治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス,滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] 大環状ポリオキソモリブデート/液晶性有機分子の複合体薄膜の電気化学的挙動

    • Author(s)
      西田匠汰,清原亜祐実,堤治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス,滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] スメクチック液晶性を発現する金(I)錯体の発光挙動

    • Author(s)
      藤澤香織,泉裕一,奥田雄騎,堤治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス,滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] 棒状金錯体をメソゲンに用いた側鎖型高分子液晶の発光挙動

    • Author(s)
      玉井翔,藤澤香織,堤治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス,滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] キラル部位を導入した金錯体の液晶挙動と発光特性

    • Author(s)
      杉本菜々,玉井翔,藤澤香織,堤治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス,滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] Aggregation Structures of Gold Nanoparticles with Azobenzen Liquid Crystals on Solid Surfaces

    • Author(s)
      Kaori Fujisawa, Asuna Kuranari, Osamu Tsutsumi
    • Organizer
      The 16th International Symposium on Advanced Display Materials and Devices (ADMD 2012)
    • Place of Presentation
      Cheju, Korea
    • Related Report
      2012 Research-status Report
  • [Presentation] 液晶性環状三核金錯体の発光特性と分子間相互作用

    • Author(s)
      田丸雅一,藤澤香織,堤治
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学,愛知県
    • Related Report
      2012 Research-status Report
  • [Presentation] 大環状ポリオキソモリブデート/液晶性有機分子複合体の構造と物性の相関

    • Author(s)
      津守達啓,清原亜祐実,堤治
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学,愛知県
    • Related Report
      2012 Research-status Report
  • [Presentation] 側鎖に棒状金錯体を導入した高分子液晶の発光挙動

    • Author(s)
      玉井翔,藤澤香織,堤治
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学,愛知県
    • Related Report
      2012 Research-status Report
  • [Presentation] 発光性棒状単核金錯体の合成と液晶性

    • Author(s)
      藤澤香織,泉祐一,大西佑亮,堤治
    • Organizer
      2012年日本液晶学会討論会
    • Place of Presentation
      千葉大学西千葉キャンパス,千葉県
    • Related Report
      2012 Research-status Report
  • [Presentation] 有機分子/ポリオキソモリブデート複合体の凝集構造と物性

    • Author(s)
      清原 亜祐実,津守 達啓,宇野 健二朗, 堤治
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学五福キャンパス,富山県
    • Related Report
      2012 Research-status Report
  • [Presentation] 三核金錯体の凝集構造に伴う発光挙動変化

    • Author(s)
      藤澤 香織,堤 治
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学五福キャンパス,富山県
    • Related Report
      2012 Research-status Report
  • [Presentation] メソゲンとして棒状金錯体を導入した高分子液晶の発光挙動

    • Author(s)
      玉井 翔,藤澤 香織,堤 治
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学五福キャンパス,富山県
    • Related Report
      2012 Research-status Report
  • [Presentation] 液晶性環状三核金錯体の凝集構造と発光特性

    • Author(s)
      田丸 雅一,藤澤 香織,堤 治
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学五福キャンパス,富山県
    • Related Report
      2012 Research-status Report
  • [Presentation] 単一化合物で白色発光を示す高分子液晶性金錯体

    • Author(s)
      玉井翔,藤澤香織,堤治
    • Organizer
      第2回CSJ化学フェスタ2012
    • Place of Presentation
      東京工業大学 大岡山キャンパス,東京都
    • Related Report
      2012 Research-status Report
  • [Presentation] 液晶性有機分子を利用した大環状ポリオキソモリブデートの自己組織化

    • Author(s)
      津守達啓,清原亜祐実,堤治
    • Organizer
      第2回CSJ化学フェスタ2012
    • Place of Presentation
      東京工業大学 大岡山キャンパス,東京都
    • Related Report
      2012 Research-status Report
  • [Presentation] 液晶分子を利用した金ナノ材料の配列制御

    • Author(s)
      永松彰,倉成亜沙,堤治
    • Organizer
      第2回CSJ化学フェスタ2012
    • Place of Presentation
      東京工業大学 大岡山キャンパス,東京都
    • Related Report
      2012 Research-status Report
  • [Presentation] 単一化合物でフルカラー発光を示す液晶性金錯体

    • Author(s)
      田丸雅一,藤澤香織,堤治
    • Organizer
      第2回CSJ化学フェスタ2012
    • Place of Presentation
      東京工業大学 大岡山キャンパス,東京都
    • Related Report
      2012 Research-status Report
  • [Presentation] White-Color Emission from a Single Material: Photoluminescence Behavior and Liquid Crystallinity of Calamitic Gold Complexes

    • Author(s)
      Tamai Sho, Fujisawa Kaori, Tsutsumi Osamu
    • Organizer
      8th International Workshop on Supramolecular Nanoscience of Chemically Programed Pigments (SNCPP12)
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス,滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] Full-Color Emission from a Single Material: Correlation between Emission Color and Aggregation Structure in Liquid-Crystalline Gold Complexes

    • Author(s)
      Tamaru Masakazu, Fujisawa Kaori, Tsutsumi Osamu
    • Organizer
      8th International Workshop on Supramolecular Nanoscience of Chemically Programed Pigments (SNCPP12)
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス,滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis and Properties of Organic-Inorganic Hybrid Materials Containing Giant-Ring-Shaped Polyoxomolybdate and Liquid-Crystalline Molecules

    • Author(s)
      Tsumori Tatsuhiro, Kiyohara Ayumi, Tsutsumi Osamu
    • Organizer
      8th International Workshop on Supramolecular Nanoscience of Chemically Programed Pigments (SNCPP12)
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス,滋賀県
    • Related Report
      2012 Research-status Report
  • [Presentation] ピラゾール配位子をもつ環状三核金錯体の液晶性と発光特性

    • Author(s)
      田丸雅一,宇野健二朗,藤澤香織,堤治
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜,神奈川県
    • Related Report
      2012 Research-status Report
  • [Presentation] 単核棒状金錯体の液晶性と発光特性

    • Author(s)
      玉井翔,泉裕一,藤澤香織,宇野健二朗,堤 治
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜,神奈川県
    • Related Report
      2012 Research-status Report
  • [Presentation] 環状三核金錯体の凝集構造と発光挙動の相関

    • Author(s)
      藤澤香織,宇野健二朗,堤治
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜,神奈川県
    • Related Report
      2012 Research-status Report
  • [Remarks] 高分子材料化学研究室

    • URL

      http://www.ritsumei.ac.jp/lifescience/achem/tsutsumi/Tsutsumi_Group/Top.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 立命館大学 ソフト・ハード融合材料の階層的構造制御による新材料の創発

    • URL

      http://www.soft-hard-ritsumei.jp

    • Related Report
      2014 Annual Research Report
  • [Remarks] 立命館大学 生命科学部 応用化学科 高分子材料化学研究室

    • URL

      http://www.ritsumei.ac.jp/lifescience/achem/tsutsumi/Tsutsumi_Group/Top.html

    • Related Report
      2012 Research-status Report
  • [Remarks] 立命館大学- ソフト・ハード融合材料の階層的構造制御による新材料の創発

    • URL

      http://www.soft-hard-ritsumei.jp

    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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