Preparation of hybrid-type monolith column reactor and its application
| Project/Area Number |
24550227
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic industrial materials
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| Research Institution | Osaka Municipal Technical Research Institute |
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Principal Investigator |
MATSUKAWA Kimihiro 地方独立行政法人大阪市立工業研究所, 電子材料研究部, 部長 (90416321)
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| Co-Investigator(Kenkyū-buntansha) |
MITAMURA Koji 地方独立行政法人大阪市立工業研究所, 電子材料研究部, 研究員 (90437054)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Keywords | モノリス / エポキシ樹脂 / パラジウムナノ粒子 / フロー有機合成 / シリカハイブリッド / 鈴木カップリング / 共連続多孔体 / 有機無機ハイブリッド / 水添反応 |
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| Outline of Final Research Achievements |
"Flow chemistry" is one of most attractive organic synthetic process in recent years. The porous materials are good candidates for substrates of flow column reactors. Epoxy monolith with various shapes was prepared by a spinodal decomposition during the polymerization of epoxy resins. We fabricated a flow reactor column of epoxy monolith in a stainless column, which palladium nano particles were immobilized on the surface of monolith. These column reactor which is immobilized palladium catalyst could be applied for flow chemical synthesis such as Suzuki-Miyaura Coupling, Heck reaction, and hydrogenation etc. These reaction conditions were optimized by using phosphine ligands. Furthermore, silica containing hybrid epoxy monolith was developed, in order to have high durability for pressure and temperature during reactions.
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Report
(4 results)
Research Products
(120 results)
