Development of functional system of syndiotactic polystyrene with organometallic compounds
Project/Area Number |
24550249
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Polymer/Textile materials
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Research Institution | Shizuoka University |
Principal Investigator |
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Co-Investigator(Kenkyū-buntansha) |
SAWATARI Chie 静岡大学, 教育学部, 教授 (70196319)
|
Project Period (FY) |
2012-04-01 – 2015-03-31
|
Project Status |
Completed (Fiscal Year 2014)
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Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
|
Keywords | 高分子構造・物性 / シンジオタクチックポリスチレン / ゲスト分子 / 共結晶 / 配向結晶化 / 偏光蛍光回転角度分布法 / 広角エックス線回折 / シリカナノ粒子 / 広角X線回折 / 偏光蛍光角度分布法 / 基底状態ダイマー / ポリマーブレンド / 物理ゲル / 有機金属錯体 / 偏光蛍光 |
Outline of Final Research Achievements |
First we clarified that guest organic molecules co-crystallized with syndiotactic polystyrene (SPS) were able to react with chemical species in a solvent including water. By reacting guest molecules clathrated in SPS crystalline phases, we have obtained some special SPS films such as films coated with silver through silver-mirror reaction or SPS co-crystalline films with organometallic compounds such as pyridine-copper chloride or pyridine-copper bromide. Moreover, we have developed the preparation method of SPS epsilon crystalline phase with high purity. Finally we have succeeded to orientate polymers having electrical conductivity such as polyaniline along with cavities of SPS epsilon crystalline phase.
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Report
(4 results)
Research Products
(62 results)
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[Presentation] カードラン化学架橋ゲルの特性2014
Author(s)
越野貴嗣 伊藤泰希 板垣秀幸
Organizer
第63回高分子学会年次大会
Place of Presentation
名古屋国際会議場(名古屋市)
Year and Date
2014-05-28 – 2014-05-30
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