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Crystallization control of topological blend polymer which consists of cyclic polymer as a component

Research Project

Project/Area Number 24550256
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionOkayama University

Principal Investigator

YAMAZAKI Shinichi  岡山大学, 環境生命科学研究科, 准教授 (40397873)

Co-Investigator(Renkei-kenkyūsha) KIMURA Kunio  岡山大学, 大学院環境生命科学研究科, 教授 (40274013)
Research Collaborator UCHIDA Tetsuya  岡山大学, 大学院自然科学研究科, 准教授 (90284083)
OKIHARA Takumi  岡山大学, 大学院自然科学研究科, 講師 (70243491)
KOBAYASHI Keiko  岡山大学, 大学院環境生命科学研究科
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords高分子構造・物性 / 高分子材料物性
Outline of Final Research Achievements

The purpose of this work is to clarify the role of entanglement species on the crystallization of polymers through observation of crystallization of a topological blend polymer which consists of cyclic polymer. Topological blend polymer means the mixing of cyclic and linear polymers. The following issues were investigated. (1) Several kinds of cyclic and linear polyethylene with different molecular weight were prepared. Crystallization at the quiescent state and under the flow were observed by means of polarizing optical microscope. The degree of supercooling, flow rate and strain dependence of the crystallization behavior were made clear. (2) Observation by a scanning electron microscope and crystal structure analysis by wide angle X-ray diffraction measurement were performed for various blends samples.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (6 results)

All 2015 2014 2013 2012

All Presentation (6 results) (of which Invited: 2 results)

  • [Presentation] Role of entanglement species in the formation of shish-kebab -Effect of blend ratio and molecular weight in cyclic and linear polyethylene blend-2015

    • Author(s)
      Shinichi Yamazaki
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15 – 2015-12-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Shear induced crystallization of cyclic and linear polyethylene blend -Role of entanglement formed by combination of cyclic and linear polymer-2014

    • Author(s)
      Shinichi Yamazaki
    • Organizer
      ICR Symposium on Polymer Crystals 2014 (International Symposium on Fiber Science and Technology 2014 Post-Symposium)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2014-10-02 – 2014-10-03
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] シシケバブ構造形成に及ぼす絡み合い種類の役割―環状・直鎖状高分子ブレンド系における両成分の分子量の効果―2013

    • Author(s)
      小林慧子・山崎慎一・木村邦生
    • Organizer
      第62回高分子学会高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 環状ポリエチレンの静置下等温・非等温結晶化挙動に及ぼす直鎖状ポリエチレンの添加効果2013

    • Author(s)
      小林慧子・山崎慎一・木村邦生
    • Organizer
      第28回中国四国地区高分子若手研究会
    • Place of Presentation
      アークホテル岡山
    • Related Report
      2013 Research-status Report
  • [Presentation] 環状ポリエチレンの静置下結晶化挙動に及ぼす直鎖状ポリエチレンの添加効果2013

    • Author(s)
      小林慧子・山崎慎一・木村邦生
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館
    • Related Report
      2013 Research-status Report
  • [Presentation] シシケバブ構造形成に及ぼす絡み合い種類の役割-環状・直鎖状高分子ブレンド系における直鎖状高分子の添加量および分子量の効果-2012

    • Author(s)
      小林 慧子・斉藤 裕也・山崎 慎一・木村 邦生
    • Organizer
      第61回高分子学会高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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