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Enhancement of magnetism and magneto-electric coupling in multiferroic structures with geometrical frustration caused by high tetragonality phases

Research Project

Project/Area Number 24560007
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

RICINSCHI Dan  東京工業大学, 総合理工学研究科(研究院), 准教授 (60403127)

Co-Investigator(Kenkyū-buntansha) 奥山 雅則  大阪大学, 基礎工学部, 名誉教授 (60029569)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsマルチフェロイック / 第1原理計算 / BiFeO3 / 強誘電性 / 強磁性 / 薄膜 / PLD
Outline of Final Research Achievements

The research project has investigated crystalline materials in which two important properties coexist: ferroelectricity (centers of positive and negative atomic charges are always separated, creating permanent electric dipoles or polarization that can be controlled by external electric field) and ferromagnetism (electrons of certain atoms in the crystal arrange themselves so that their magnetic dipole of spin are uncompensated and aligned). We have studied crystals in the family of BiFeO3. Our atomistic calculations have shown that we can control the atomic displacements (that yield a large/small polarization) by changing the way we fill up the electronic shells of Fe (thus creating a large/small magnetization). Our research revealed that for obtaining large magnetism and ferroelectricity, coupled to each other at room temperature, some exotic crystal symmetries or BiFeO3 (that are normally difficult to stabilize) should be promoted by careful selection of the fabrication conditions.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (36 results)

All 2015 2014 2013 2012 2011

All Journal Article (15 results) (of which Peer Reviewed: 15 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (21 results) (of which Invited: 6 results)

  • [Journal Article] Ab Initio Study of Tetragonal Co-Doped BiFeO3 with Low-Spin and Intermediate-Spin Co2014

    • Author(s)
      D. Ricinschi
    • Journal Title

      High Performance Computing Journal

      Volume: 4 Pages: 37-40

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of Spin Configurations on First-Principles-Calculated Structure and Magneto-Electric Properties of BiFeO32014

    • Author(s)
      D. Ricinschi, T. Kanashima and M. Okuyama
    • Journal Title

      AIP Conference Proceedings

      Volume: 1627 Pages: 87-91

    • DOI

      10.1063/1.4901663

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Columnar Growth of BiFeO3 Films Prepared by Magnetic-field-assisted Pulsed Laser Deposition2014

    • Author(s)
      T. Kanashima, J. M. Park, D. Ricinschi and M. Okuyama
    • Journal Title

      Ferroelectrics

      Volume: 466 Issue: 1 Pages: 63-73

    • DOI

      10.1080/00150193.2014.894869

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Current conduction in single-domain BiFeO3 thin films2014

    • Author(s)
      S. Nakashima, T. Ito, H. Fujisawa, T. Kanashima, M. Okuyama, M. Kobune and M. Shimizu
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 8S3 Pages: 08NA01-08NA01

    • DOI

      10.7567/jjap.53.08na01

    • NAID

      210000144373

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relationship between Source/Drain-Contact Structures and Switching Characteristics in Oxide-Channel Ferroelectric-Gate Thin-Film Transistors2014

    • Author(s)
      Ken-ichi Haga, Yuuki Nakada, Dan Ricinschi, and Eisuke Tokumitsu
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 53 Issue: 9S Pages: 09PA07-09PA07

    • DOI

      10.7567/jjap.53.09pa07

    • NAID

      210000144476

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic ferroelectric gate field-effect transistor memory using high-mobility rubrene thin film2014

    • Author(s)
      T. Kanashima, Y. Katsura and M. Okuyama
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 4S Pages: 04ED11-04ED11

    • DOI

      10.7567/jjap.53.04ed11

    • NAID

      210000143587

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Columnar growth of BiFeO3 films prepared by magnetic-field-assisted pulsed laser deposition2014

    • Author(s)
      T. Kanashima, J.M. Park, D. Ricinschi and M. Okuyama
    • Journal Title

      Ferroelectrics (accepted)

      Volume: in press

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Density functional theory study on how electron spin configuration of Co3+ ion affects the structure and magnetism of Co-doped bismuth ferrite2013

    • Author(s)
      D. Ricinschi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 9S1 Pages: 09KB01-09KB01

    • DOI

      10.7567/jjap.52.09kb01

    • NAID

      210000142831

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Repetition rate dependence of ferroelectric properties of polycrystalline BiFeO3 films prepared by pulsed laser deposition method2013

    • Author(s)
      J.M. Park, S. Nakashima, M. Sohgawa, T. Kanashima and M. Okuyama
    • Journal Title

      Ferroelectrics

      Volume: 453 Issue: 1 Pages: 1-7

    • DOI

      10.1080/00150193.2013.842064

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of epitaxial BiFeO3 thin films on La-SrTiO3 substrate by using magnetic-field-assisted pulsed laser deposition2013

    • Author(s)
      J.M. Park, M. Sohgawa, T. Kanashima, M. Okuyama and S. Nakashima
    • Journal Title

      Journal of the Korean Physical Society

      Volume: 62 Issue: 7 Pages: 1041-1045

    • DOI

      10.3938/jkps.62.1041

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Density functional theory and experimental study of the electronic structure and transport properties of La, V, Nb, and Ta doped SrTiO32013

    • Author(s)
      J. D. Baniecki, M. Ishii, H. Aso, K. Kurihara, and D. Ricinschi
    • Journal Title

      JOURNAL OF APPLIED PHYSICS

      Volume: 113 Issue: 1

    • DOI

      10.1063/1.4770360

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] FERROELECTRICS (accepted)2013

    • Author(s)
      J.M. Park, S. Nakashima, M. Sohgawa, T. Kanashima, and M. Okuyama
    • Journal Title

      Repetition Rate Dependence of Ferroelectric Properties of Polycrystalline BiFeO3 films prepared by using Pulsed Laser Deposition method

      Volume: in press

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] First-Principles Calculations of Structure and Magneto-Electric Properties of Co-Doped Bismuth Ferrite2012

    • Author(s)
      D. Ricinschi
    • Journal Title

      HIGH PERFORMANCE COMPUTER JOURNAL

      Volume: 2 Pages: 37-42

    • NAID

      120006502814

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ferroelectric and Piezoelectric Properties of Polycrystalline BiFeO3 Thin Films Prepared by Pulsed Laser Deposition under Magnetic Field2012

    • Author(s)
      J.M. Park, S. Nakashima, M. Sohgawa, T. Kanashima, and M. Okuyama
    • Journal Title

      JAPANESE JOURNAL OF APPLIED PHYSICS

      Volume: 51 Issue: 9S2 Pages: 09MD05-09MD05

    • DOI

      10.1143/jjap.51.09md05

    • NAID

      210000141294

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Pulse-controlled generation and characterization of partially-switched multiple-value polarization states in PZT ceramics2011

    • Author(s)
      D.Ricinschi, D.Nicastro, C.Harnagea, M.Okuyama
    • Journal Title

      Current Applied Physics

      Volume: 12 Issue: 3 Pages: 616-622

    • DOI

      10.1016/j.cap.2011.09.001

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] In-Situ Characterization of Electronic Structure and Energy Band Alignments at Interfaces between Stannate (CaSnO3, BaSnO3) and Titanate (SrTiO3) Epitaxial Thin Films for Energy Applications Using Photoelectron Spectroscopy2015

    • Author(s)
      J. D. Baniecki, T. Yamazaki, H. Aso, D. Ricinschi and Y. Imanaka
    • Organizer
      2015 MRS Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2015-04-06 – 2015-04-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Probing Electronic Properties during Interface Formation with In Situ Photoelectron Spectroscopy: Insights for the Oxygen Evolution Reaction on Thin Film Epitaxial Cobaltite Oxide Electrodes2015

    • Author(s)
      Q. Van Overmeere, J. D. Baniecki, T. Yamazaki, H. Aso, Y. Kitaoka, D. Ricinschi and Y. Imanaka
    • Organizer
      2015 MRS Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2015-04-06 – 2015-04-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Structure and magneto-electric properties of tetragonal BiFeO3 with high-spin, low spin and intermediate-spin Fe3+ under biaxial stress by first-principles calculations2014

    • Author(s)
      D. Ricinschi
    • Organizer
      75th Autumn Meeting of the Japan Society of Applied Physics
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Evolution and Prospect of Ferroelectric and its Thin Film Researches2014

    • Author(s)
      M. Okuyama
    • Organizer
      75th Autumn Meeting of the Japan Society of Applied Physics
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Research Evolution of Ferroelectric Thin Films2014

    • Author(s)
      M. Okuyama
    • Organizer
      10th Japan-Korea Conference on Ferroelectrics
    • Place of Presentation
      Hiroshima, Japan
    • Year and Date
      2014-08-17 – 2014-08-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Effect of Fe Spin Configurations on First-Principles-Calculated Structure and Magneto-Electric Properties of BiFeO32014

    • Author(s)
      D. Ricinschi and M. Okuyama
    • Organizer
      Electroceramics XIV
    • Place of Presentation
      Bucharest, Romania
    • Year and Date
      2014-06-15 – 2014-06-20
    • Related Report
      2014 Annual Research Report 2013 Research-status Report
  • [Presentation] Looking back on Ferroelectric Thin Film Study2014

    • Author(s)
      M. Okuyama
    • Organizer
      31st Meeting on Ferroelectric Materials and Their Applications
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2014-05-27 – 2014-05-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Density functional theory study on how electron spin configuration of Co3+ ion affects the structure and magnetism of Co-doped bismuth ferrite2013

    • Author(s)
      D. Ricinschi
    • Organizer
      The Meeting on Ferroelectric Materials and Applications (FMA-30)
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Structure and multiferroic properties of BiFeO3 crystals with mixed Fe3+ spin configurations studied by density functional theory calculations2013

    • Author(s)
      D. Ricinschi, T. Kanashima and M. Okuyama
    • Organizer
      13th International Meeting on Ferroelectricity (IMF-13)
    • Place of Presentation
      Krakow, Poland
    • Related Report
      2013 Research-status Report
  • [Presentation] First-Principles Calculation Study of BiFeO3 with mixed electronic configurations of Fe3+ ion2013

    • Author(s)
      D. Ricinschi and M. Okuyama
    • Organizer
      JSAP-MRS Joint Symposia
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Columnar growth of low-stressed BiFeO3 films prepared by magnetic-field assisted PLD2013

    • Author(s)
      T. Kanashima, J. Park, D. Ricinschi and M. Okuyama
    • Organizer
      13th International Meeting on Ferroelectricity (IMF-13)
    • Place of Presentation
      Krakow, Poland
    • Related Report
      2013 Research-status Report
  • [Presentation] Influence of Mn-Doping on Current Conduction in Single-Domain BiFeO3 Thin Films2013

    • Author(s)
      T. Ito, S. Nakashima, H. Fujisawa, M. Kobune, T. Kanashima, M. Okuyama and M. Shimizu
    • Organizer
      第23会日本MRS年次大会(MRS-J)
    • Place of Presentation
      横浜市開港記念会館
    • Related Report
      2013 Research-status Report
  • [Presentation] 磁場印加PLDで作製したBiFeO3薄膜のリーク電流解析2013

    • Author(s)
      金島 岳, 朴 正敏, 中嶋 誠二, D. Ricinschi, 野田 実, 奥山 雅則
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Ferroelectric Properties and Current Conduction in Single Domain BiFeO3 Thin Films2013

    • Author(s)
      S. Nakashima, T. Ito, H. Fujisawa, T. Kanashima, M. Okuyama, M. Kobune and M. Shimizu
    • Organizer
      The 2nd International Conference on Advanced Electromaterials ICAE2013
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2013 Research-status Report
  • [Presentation] 単一ドメインBiFeO3薄膜の電気伝導特性2013

    • Author(s)
      伊藤 太紀, 中嶋 誠二, 藤沢 浩訓, 小舟 正文, 金島 岳, 奥山 雅則, 清水 勝
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] First-Principles Study on How Electron Spin Configuration of Magnetic Ions Affects Structure and Magnetism of BiFeO3-Based Compounds2013

    • Author(s)
      D. Ricinschi
    • Organizer
      The Meeting on Ferroelectric Materials and Their Applications (FMA-30)
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Preparation of BiFeO3 Thin Films by Using Magnetic-Field-Assisted PLD and Dual Ion Beam Sputtering and Their Characterization2012

    • Author(s)
      M. Okuyama, J.M. Park, S. Nakashima, T. Kanashima, and D. Ricinschi
    • Organizer
      International Symposium on Integrated Functionalities
    • Place of Presentation
      Hong Kong, China
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Electronic Transport in Donor Doped Sr(x)Ti(y)O(3-δ) Thin Films and Bulk Single Crystals: Experimental and Density Functional Studies2012

    • Author(s)
      J.D. Baniecki, M. Ishii, H. Aso, K. Kurihara, D. Ricinschi, A. Vailionis and R. Schafranek
    • Organizer
      International Symposium on Integrated Functionalities
    • Place of Presentation
      Hong Kong, China
    • Related Report
      2012 Research-status Report
  • [Presentation] Preparation of epitaxial BiFeO3 thin films on La-SrTiO3 substrate by Magnetic Field Assisted Pulsed Laser Deposition2012

    • Author(s)
      J.M. Park, S. Nakashima, M. Sohgawa, T. Kanashima, and M. Okuyama
    • Organizer
      9-th Korea-Japan Conference on Ferroelectrics
    • Place of Presentation
      Ulsan, Korea
    • Related Report
      2012 Research-status Report
  • [Presentation] Multiferroic properties of BiFeO3-based materials with various spin state of magnetic ions2012

    • Author(s)
      D. Ricinschi and M. Okuyama
    • Organizer
      Asian Meeting on Ferroelectricity
    • Place of Presentation
      Pattaya, Thailand
    • Related Report
      2012 Research-status Report
  • [Presentation] Preparation of BiFeO3 Films by Magnetic-Field-Assisted Pulsed Laser Deposition and Their Characterization2012

    • Author(s)
      M. Okuyama, J.M. Park, T. Kanashima, and D. Ricinschi
    • Organizer
      Asian Meeting on Ferroelectricity
    • Place of Presentation
      Pattaya, Thailand
    • Related Report
      2012 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2021-04-07  

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