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Reduction, sulfuration and nitridization of nano-sized phosphor by atmospheric pressure plasma for suppressing agglomeration and improving efficiency

Research Project

Project/Area Number 24560008
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionNagaoka University of Technology

Principal Investigator

KATO Ariyuki  長岡技術科学大学, 工学(系)研究科(研究院), 准教授 (10303190)

Co-Investigator(Kenkyū-buntansha) KIKUCHI Takashi  長岡技術科学大学, 大学院工学研究科, 准教授 (30375521)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords誘導結合型プラズマ / 蛍光体 / 還元処理 / 硫化処理 / 窒化処理 / プラズマ / 光物性 / ナノ材料
Outline of Final Research Achievements

Reduction treatment using inductively coupled plasma (ICP) has been demonstrated for KSrPO4:Eu phosphor synthesized by polymerized complex method. The emission of reduced divalent Eu ions was enhanced significantly by irradiating ICP using hydrogen mixed buffer gas. The amount of reduced Eu ions was increased with increasing hydrogen concentration, input power and irradiation time. Under the conditions of hydrogen concentration of 5%, input power of 80 W and irradiation time of 15 minutes, the amount of reduced Eu ions has been attained one third of that by conventional heating treatment (hydrogen concentration of 5%, 1000C, 3 hours). Temperature of the sample immediately after irradiation was less than 300C. From the result above, ICP was found to be a effective way to reduce the Eu ions in phosphor in very short time at low temperature.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (5 results)

All 2015 2014

All Presentation (5 results)

  • [Presentation] H2 Concentration Effect of Reduction Treatment of Eu Doped KSrPO4 Phosphor by Inductively Coupled Plasma and Its Plasma Spectroscopy2015

    • Author(s)
      Masuo Takachi, Kazumasa Takahashi, Toru Sasaki, Takashi Kikuchi and Ariyuki Kato
    • Organizer
      The 5th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2015)
    • Place of Presentation
      Niigata, Japan
    • Year and Date
      2015-06-16 – 2015-06-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 誘導結合プラズマによるEu添加KSrPO4蛍光体の還元効果の水素濃度依存性2015

    • Author(s)
      高地満寿雄,山上紘平,佐々木徹,菊池崇志,加藤有行
    • Organizer
      第62回 応用物理学会 春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Eu添加蛍光体還元処理のための誘導結合プラズマの分光2014

    • Author(s)
      高地満寿雄,佐々木徹,菊池崇志,加藤有行
    • Organizer
      平成26年度 日本物理学会新潟支部 第43回例会
    • Place of Presentation
      新潟大学
    • Year and Date
      2014-12-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Reduction Treatment of KSrPO4:Eu Phosphor by Inductively Coupled Plasma2014

    • Author(s)
      Masuo Takachi, Kohei Ymagami, Kazumasa Takahashi, Toru Sasaki, Takashi Kikuchi, Ariyuki Kato
    • Organizer
      8th International Conference on Reactive Plasmas and 31st Symposium on Plasma Processing (ICRP-8/SPP-31)
    • Place of Presentation
      Fukuoka Convention Center, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] 誘導結合プラズマによるKSrPO4:Eu蛍光体の還元処理2014

    • Author(s)
      高地満寿雄,山上紘平,高橋一匡,佐々木徹,菊池崇志,加藤有行
    • Organizer
      2014年 第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学
    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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