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Control of Deep Ultra-violet Emission and Modulation Epitaxy of Nitride Semicondusturs.

Research Project

Project/Area Number 24560010
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionMie University

Principal Investigator

MIYAKE Hideto  三重大学, 工学(系)研究科(研究院), 准教授 (70209881)

Co-Investigator(Kenkyū-buntansha) HIRAMATU Kazumasa  三重大学, 大学院工学研究科, 教授 (50165205)
NAOI Hiroyuki  和歌山工業高等専門学校, 電気情報工学科, 准教授 (10373101)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords窒化物半導体 / GaN / AlN / 電子線励起 / 紫外光源 / 組成変調 / MOVPE / 窒化アルミニウム / AlGaN / 多重量子井戸 / 深紫外光源
Outline of Final Research Achievements

We have investigated the insertion of different lattice-relaxation layers between the AlGaN MQW layer and the AlN layer on sapphire. Lattice-relaxation layers using an AlN interlayer with a growth temperature of 1450 oC on two high-Al-mole-fraction AlGaN layers (structure (b)) presents the strongest emission intensity and also the highest crystal quality of AlGaN MQWs.
Using high temperature AlN films as the lattice-relaxation layer improved crystal quality and emission intensity in AlGaN MQWs. The detailed mechanism will be discussed in a future study.
A prototype ultraviolet-light-source tube was fabricated with an AlGaN film used as a target for electron-beam (EB) excitation. The deep-UV light output power and conversion efficiency of the AlGaN MQW target for EB pumping voltage of 10kV were investigated. The deep-UV light output power was 16 mW at a wavelength of 256 nm, when the EB input power of 2W, and that the conversion efficiency was 1% at the EB input power of 1W.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (42 results)

All 2015 2014 2013 2012 Other

All Journal Article (17 results) (of which Peer Reviewed: 17 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (21 results) (of which Invited: 12 results) Book (1 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Microscopic crystalline structure of a thick AlN film grown on a trench-patterned AlN/alpha-Al2O3 template2015

    • Author(s)
      D.Khan, S.Takeuchi, Y.Nakamura, K.Nakamura, T.Arauchi, H.Miyake, K.Hiramatsu, Y.Imai, S.Kimura, A.Sakai
    • Journal Title

      JOURNAL OF CRYSTAL GROWTH

      Volume: 411 Pages: 38-41

    • DOI

      10.1016/j.jcrysgro.2014.10.052

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Si concentration dependence of structural inhomogeneities in Si-doped AlxGa1-xN/AlyGa1-yN multiple quantum well structures (x=0.6) and its relationship with internal quantum efficiency2014

    • Author(s)
      S.Kurai, K.Anai, H.Miyake, K.Hiramatsu, Y.Yamada
    • Journal Title

      JOURNAL OF APPLIED PHYSICS

      Volume: 116 Issue: 23 Pages: 235703-235703

    • DOI

      10.1063/1.4904847

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Binding energy of localized biexcitons in AlGaN-based quantum wells2014

    • Author(s)
      Y.Hayakawa, T.Fukuno, K.Nakamura, H.Miyake, K.Hiramatsu, Y.Yamada
    • Journal Title

      APPLIED PHYSICS EXPRESS

      Volume: 7 Issue: 12 Pages: 122101-122101

    • DOI

      10.7567/apex.7.122101

    • NAID

      210000137325

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Vacuum ultraviolet ellipsometer using inclined detector as analyzer to measure stokes parameters and optical constants ― With results for AlN optical constants2014

    • Author(s)
      T.Saito, K.Ozaki, K.Fukui,H.Iwai,K.Yamamoto,H.Miyake, K.Hiramatsu
    • Journal Title

      Thin Solid Films

      Volume: 559 Pages: 517-521

    • DOI

      10.1016/j.tsf.2014.02.099

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-quality AlN growth on 6H-SiC substrate using three dimensional nucleation by low-pressure hydride vapor phase epitaxy2014

    • Author(s)
      S. Kitagawa, H. Miyake and K. Hiramatsu
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 5S1 Pages: 05FL03-05FL03

    • DOI

      10.7567/jjap.53.05fl03

    • NAID

      210000143863

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Selective-area growth of GaN on non- and semi-polar bulk GaN substrates2014

    • Author(s)
      S. Okada, H. Miyake, K. Hiramatsu, Y. Enatsu and S. Nagao
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 5S1 Pages: 05FL04-05FL04

    • DOI

      10.7567/jjap.53.05fl04

    • NAID

      210000143864

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Anisotropic crystalline morphology of epitaxial thick AlN films grown on triangular-striped AlN/sapphire template2014

    • Author(s)
      T.Arauchi, S.Takeuchi, K.Nakamura, K.Dinh, Y.Nakamura, H.Miyake, K.Hiramatsu, A. Sakai
    • Journal Title

      PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE

      Volume: 211 Issue: 4 Pages: 731-735

    • DOI

      10.1002/pssa.201300461

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transient photoluminescence of aluminum-rich (Al, Ga) N low-dimensional structures2014

    • Author(s)
      P.Lefebvre, C. Brimont, P.Valvin, B. Gil, H.Miyake, K.Hiramatsu
    • Journal Title

      PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE

      Volume: 211 Issue: 4 Pages: 765-768

    • DOI

      10.1002/pssa.201300505

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Impacts of Si-doping and resultant cation vacancy formation on the luminescence dynamics for the near-band-edge emission of Al0.6Ga0.4N films grown on AlN templates by metalorganic vapor phase epitaxy2013

    • Author(s)
      S. F. Chichibu, H. Miyake, Y. Ishikawa, M. Tashiro, T. Ohtomo, K. Furusawa, K. Hazu,K. Hiramatsu, A. Uedono
    • Journal Title

      Journal of Applied Physics

      Volume: 113 Issue: 21 Pages: 2135061-6

    • DOI

      10.1063/1.4807906

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Cross-sectional X-ray microdiffraction study of a thick AlN film grown on a trench-patterned AlN/alpha-Al2O3 template2013

    • Author(s)
      D.T. Khan, S. Takeuchi, J. Kikkawa, Y. Nakamura, H. Miyake, K. Hiramatsu, Y. Imai, S. Kimura, O. Sakata, A. Sakai
    • Journal Title

      Journal of Crystal Growth

      Volume: 381 Pages: 37-42

    • DOI

      10.1016/j.jcrysgro.2013.07.012

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Inhomogeneous distribution of defect-related emission in Si-doped AlGaN epitaxial layers with different Al content and Si concentration2013

    • Author(s)
      S. Kurai, F. Ushijima, H. Miyake, K. Hiramatsu, Y. Yamada
    • Journal Title

      Journal of Applied Physics

      Volume: 115 Issue: 5 Pages: 53509-53509

    • DOI

      10.1063/1.4864020

    • NAID

      120006364143

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] AlN Grown on a- and n-Plane Sapphire Substrates:by Low-Pressure Hydride Vapor Phase Epitaxy2013

    • Author(s)
      Naoki Goriki, Hideto Miyake, Kazumasa Hiramatsu, Toru Akiyama, Tomonori Ito, and Osamu Eryu
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 8S Pages: 08JB31-08JB31

    • DOI

      10.7567/jjap.52.08jb31

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Cathodoluminescence Study of Optical Inhomogeneity in Si-Doped AlGaN Epitaxial Layers Grown by Low-Pressure Metalorganic Vapor-Phase Epitaxy2013

    • Author(s)
      S. Kurai, F. Ushijima, Y. Yamada, H. Miyake, K. Hiramatsu
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 8S Pages: 08JL07-08JL07

    • DOI

      10.7567/jjap.52.08jl07

    • NAID

      210000142732

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effects of Si doping in high-quality AIN grown by MOVPE on trench-patterned template2013

    • Author(s)
      G. Nishio, Y. Shibo, H. Miyake and K. Hiramatsu
    • Journal Title

      Journal of Crystal Growth

      Volume: 370 Pages: 74-77

    • DOI

      10.1016/j.jcrysgro.2012.10.038

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Growth and Characterization of AlGaN Multiple Quantum Wells for Electron-Beam Target for Deep-Ultraviolet Light Sources2013

    • Author(s)
      F. Fukuyo, S. Ochiai, H. Miyake, K. Hiramatsu, H. Yoshida and Y. Kobayashi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 1S Pages: 01AF03-01AF03

    • DOI

      10.7567/jjap.52.01af03

    • NAID

      210000141776

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Growth and Characterization of AlGaN Multiple Quantum Wells for Electron-Beam Target for Deep-Ultraviolet Light Sources2013

    • Author(s)
      Fumitsugu Fukuyo, Shunsuke Ochiai, Hideto Miyake, Kazumasa Hiramatsu, Harumasa Yoshida, and Yuji Kobayashi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52

    • NAID

      210000141776

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effects of Si doping in high-quality AlN grown by MOVPE on trench-patterned template2012

    • Author(s)
      G. Nishio, S. Yang, H. Miyake and K. Hiramatsu
    • Journal Title

      Journal of Crystal Growth

      Volume: 370 Pages: 74-77

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Study on Surface Thermal Stability of Free-Standing GaN Substrates2015

    • Author(s)
      Shunsuke Okada, Hideto Miyake, Kazumasa Hiramatsu, Reina Miyagawa, Osamu Eryu, Tamotsu Hashizume
    • Organizer
      ISPlasma/IC-PLANTS
    • Place of Presentation
      名古屋大学 (名古屋)
    • Year and Date
      2015-03-26 – 2015-03-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fabrication of high quality AlN on sapphire for deep-UV-LED substrate2014

    • Author(s)
      H. Miyake, S. Suzuki, G. Nishio, K. Hiramatsu
    • Organizer
      ISSLED2014
    • Place of Presentation
      Kaohsiung(Taiwan)
    • Year and Date
      2014-12-14 – 2014-12-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Formation of atomic steps on sapphiresubstrates for AlN epitaxy2014

    • Author(s)
      C.-H. Lin, S. Suzuki, H. Miyake, K. Hiramatsu
    • Organizer
      ISSLED2014
    • Place of Presentation
      Kaohsiung(Taiwan)
    • Year and Date
      2014-12-14 – 2014-12-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] MOVPE growth of high-quality AlGaN for Deep-ultraviolet Light Source2014

    • Author(s)
      H. Miyake, F. Fukuyo, Y. Kobayashi, K. Hiramatsu
    • Organizer
      2014 Asia Communications and Photonics Conference
    • Place of Presentation
      Shanghai(China)
    • Year and Date
      2014-11-09 – 2014-11-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Fabrication of high quality AlN on sapphire for deep-UV-LED substrate2014

    • Author(s)
      H. Miyake, S. Suzuki, G. Nishio, K. Hiramatsu, H. Fukuyama
    • Organizer
      2nd Intensive Discussion on Growth of Nitride Semiconductor
    • Place of Presentation
      東北大学 (仙台)
    • Year and Date
      2014-10-30 – 2014-10-31
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Effects of thermal cleaning on surface of free-standing GaN substrates2014

    • Author(s)
      Shunsuke Okada, Hideto Miyake, Kazumasa HIramatsu,
    • Organizer
      The 15th IUMRS-ICA (International Union of Materials Research Societies, International Conference in Asia)
    • Place of Presentation
      福岡大学 (福岡)
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Study on AlN growth conditions for hydride vapor phase epitaxy2014

    • Author(s)
      Daiki YASUI, Hideto MIYAKE, Kazumasa HIRAMATSU
    • Organizer
      The 15th IUMRS-ICA (International Union of Materials Research Societies, International Conference in Asia)
    • Place of Presentation
      福岡大学 (福岡)
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Growth of high-quality AlN on sapphire with thermally annealed AlN buffer layer in N2-CO2014

    • Author(s)
      H. Miyake, G. Nishio, S. Suzuki, K. Hiramatsu, and H. Fukuyama
    • Organizer
      The International Workshop on Nitride Semiconductors (IWN2014)
    • Place of Presentation
      Wroclaw (Poland)
    • Year and Date
      2014-08-24 – 2014-08-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Thermal treatment of HVPE-grown GaN substrate surface2014

    • Author(s)
      Hideto Miyake, Shunsuke Okada, Kazumasa HIramatsu,
    • Organizer
      WUPP 2014
    • Place of Presentation
      Bath (UK)
    • Year and Date
      2014-08-20 – 2014-08-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] AlGaN Growth for Electron-Beam-Excitation Ultraviolet Light Source2014

    • Author(s)
      H. MIYAKE, F. Fukuyo, K. Hiramatsu, Y. Kobayashi
    • Organizer
      CIMTEC2014
    • Place of Presentation
      Montecatini Terme (Italy)
    • Year and Date
      2014-06-15 – 2014-06-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] HVPE Homoepitaxy on Freestanding AlN Substrate with Trench Pattern2014

    • Author(s)
      Yoshinobu Watanabe, Hideto Miyake, Kazumasa Hiramatsu, Yosuke Iwasaki, Shunro Nagata
    • Organizer
      5th International Symposium on Growth of III-Nitrides
    • Place of Presentation
      Atlanta (USA)
    • Year and Date
      2014-05-19 – 2014-05-22
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fabrication of AlGaN multiple quantum wells on sapphire with lattice-relaxation layer2014

    • Author(s)
      Kazuhiro Nakahama, Fumitsugu Fukuyo, Hideto Miyake, Kazumasa Hiramatsu, Harumasa Yoshida, Yuji Kobayashi
    • Organizer
      5th International Symposium on Growth of III-Nitrides
    • Place of Presentation
      Atlanta (USA)
    • Year and Date
      2014-05-19 – 2014-05-22
    • Related Report
      2014 Annual Research Report
  • [Presentation] MOVPE growth of AlN and AlGaN multiple-quantum wells on sapphire for electron-beam-excitation UV light source2014

    • Author(s)
      H. Miyake, G. Nishio, S. Suzuki, F. Fukuyo, K. Hiramatsu, H. Yoshida, Y. Kobayashi, H. Fukuyama, Y. Tokumoto
    • Organizer
      International Conference on Metamaterials and Nanophysics
    • Place of Presentation
      Varadera(Cuba)
    • Year and Date
      2014-04-22 – 2014-05-01
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Fabrication of high Al content AlGaN MQWs on AlN/sapphire by MOVPE2013

    • Author(s)
      H. Miyake, F. Fukuyo, S. Ochiai, M. Takagi, K. Hiramatsu, H. Yoshida, Y.Kobayashi
    • Organizer
      European Materials Research Society
    • Place of Presentation
      ストラスブール
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Epitaxy of AlGaN Multiple-Quantum Wells by MOVPE and Its Application of Ultraviolet Light Source2013

    • Author(s)
      H. Miyake, F. Fukuyo, S. Ochiai, K. Hiramatsu, H. Yoshida, Y. Kobayashi
    • Organizer
      SPIE Photonics West
    • Place of Presentation
      サンフランシスコ(米国)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Epitaxy of AlGaN Multiple-Quantum Wells by MOVPE and Its Application of Ultraviolet Light Source2012

    • Author(s)
      H.Miyake, S.Ochiai1,Y.Shimahara, K. Hiramatsu, F.Fukuyo, H.Yoshida, Y.Kobayashi
    • Organizer
      Collaborative Conference on Crystal Growth (3CG)
    • Place of Presentation
      フロリダ
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Fabrication of high Al content AlGaN MQWs on AlN/sapphire by MOVPE

    • Author(s)
      H. Miyake, F. Fukuyo, S. Ochiai, M. Takagi, K. Hiramatsu, H. Yoshida, Y.Kobayashi
    • Organizer
      E-MRS
    • Place of Presentation
      Strasbourg, France
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] MOVPE法による高品質AlGaNの成長

    • Author(s)
      三宅秀人、平松和政
    • Organizer
      CRESTパワー・先端素子半導体に関するシンポジウム
    • Place of Presentation
      北海道大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] MOVPE法によるAlGaN成長とその深紫外光源への応用

    • Author(s)
      三宅秀人、平松和政 、福世文嗣、吉田治正、小林祐二
    • Organizer
      日本学術振興会「結晶加工と評価技術」第145委員会
    • Place of Presentation
      明治大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Improvement of Light Extraction Efficiency with Periodic Light-extraction Structures on Sapphire Substrate for Electron-beam-pumped Deep-ultraviolet Light Sources

    • Author(s)
      F. Fukuyo, H. Miyake, K. Hiramatsu, H. Yoshida, Y. Kobayashi
    • Organizer
      ISPlasma 2014
    • Place of Presentation
      名城大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] サファイア上AlGaN 多重量子井戸構造における格子緩和層の影響

    • Author(s)
      中濵和大,福世文嗣,三宅秀人,平松和政,吉田治正,小林祐二
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学、神奈川
    • Related Report
      2013 Research-status Report
  • [Book] III-nitride semiconductors and their modern devices2013

    • Author(s)
      Hideto Miyake
    • Total Pages
      619
    • Publisher
      Oxford University Press
    • Related Report
      2012 Research-status Report
  • [Remarks] 准教授 三宅 秀人,(博士(工学))

    • URL

      http://www.elec.mie-u.ac.jp/lab/miyake.html

    • Related Report
      2014 Annual Research Report
  • [Remarks]

    • URL

      http://kyoin.mie-u.ac.jp/profile/1851.html

    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 窒化アルミニウム(AlN)膜を有する基板および窒化アルミニウム(AlN)膜の製造方法2013

    • Inventor(s)
      福山博之、三宅秀人
    • Industrial Property Rights Holder
      福山博之、三宅秀人
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-174057
    • Filing Date
      2013-08-28
    • Related Report
      2013 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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