Development of a Shottky-barrier organic thin-film solar cell having a very large internal electric field
| Project/Area Number |
24560012
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Applied materials science/Crystal engineering
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| Research Institution | Shimane University |
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Principal Investigator |
HIROMITSU ICHIRO 島根大学, 総合理工学研究科(研究院), 教授 (40199138)
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| Co-Investigator(Kenkyū-buntansha) |
HANDA Makoto 島根大学, 総合理工学部, 教授 (70208700)
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| Co-Investigator(Renkei-kenkyūsha) |
TANAKA Senku 島根大学, 総合理工学部, 助教 (20397855)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | 有機太陽電池 / 内部電場 / ショットキー障壁 / 電場変調 |
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| Outline of Final Research Achievements |
Internal electric field and photovoltaic performance of the Schottky-barrier solar cells made of a Zn-phthalocyanine(ZnPc) thin film were studied. By an insertion of a NTCDA buffer layer between the ZnPc film and transparent electrode, the short-circuit current increased to a 6 times larger value. When PTCBI was used for the buffer layer, an interesting phenomenon was observed, i.e. the photocarrier-generation efficiency in the PTCBI layer was anomalously high. A new experimental technique, Electroabsorption under White Light Illumination(EAWL), was developed, which enabled the measurement of the internal electric field in the device under operation.
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Report
(4 results)
Research Products
(14 results)
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[Journal Article] Synthesis and magnetic properties of an annulated dinuclear copper(II) phthalocyanine peripherally having 2,6-dimethylphenoxy substituents2014
Author(s)
Takahisa Ikeue, Naoko Sawada Naomi Matsumoto, Ayaka Miyazaki, Tamotsu Sugimori, Masayuki Koikawa, Ichiro Hiromitsu, Katsumi Yoshino, Masahiro Mikuriya, Yusuke Kataoka, Makoto Handa
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Journal Title
Journal of Porphyrins and Phthalocyanines
Volume: 18
Issue: 08n09
Pages: 708-714
DOI
Related Report
Peer Reviewed / Open Access
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