Experimental verification of interaction mechanism between adjacent semiconductor nanoparticles and their optical functions
| Project/Area Number |
24560015
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Applied materials science/Crystal engineering
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| Research Institution | Osaka City University |
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Principal Investigator |
KIM DAEGWI 大阪市立大学, 大学院工学研究科, 教授 (00295685)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | ナノ粒子 / 積層構造 / 共鳴相互作用 / 半導体ナノ粒子 / 光物性 |
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| Outline of Final Research Achievements |
Semiconductor quantum dot (QD) superlattices, which are periodically ordered three dimensional (3D) array structures of QDs, are expected to exhibit novel photo-optical properties arising from the resonant interactions between adjacent QDs. Since the resonant interactions such as long-range dipole-dipole Coulomb coupling and short-range quantum resonance strongly depend on inter-QD nano-space, precise control of the nano-space is essential for physical understanding of the superlattice. Here, we have investigated the pure quantum resonance in the 3D QD superlattice deposited by a layer-by-layer assembly of positively charged polyelectrolytes and negatively charged QDs. The lowest excitation energy decreases exponentially with decreasing the nano-space between the QD layers and also with decreasing the QD size, which is apparently indicative of the quantum resonance between the QDs rather than a dipole-dipole Coulomb coupling.
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Report
(4 results)
Research Products
(30 results)
