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Formation of infrared optical absorption band and intermediate band by hyperdoping of silicon

Research Project

Project/Area Number 24560020
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionKonan University

Principal Investigator

UMEZU IKUROU  甲南大学, 理工学部, 教授 (30203582)

Co-Investigator(Kenkyū-buntansha) YOSHIDA Takehito  阿南工業高等専門学校, 創造技術工学科, 教授 (20370033)
INADADA Mitsuru  関西大学, システム理工学部, 准教授 (00330407)
KOHNO Atsushi  福岡大学, 理学部, 教授 (30284160)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsレーザープロセッシング / 中間バンド / 過飽和ドーピング / 半導体 / 太陽電池 / 深い準位 / レーザーアニーリング / 金属非金属転移 / 赤外光吸収 / シリコン / 過飽和ドープ / 非平衡プロセス / パルスレーザーメルティング / 非平衡材料プロセス
Outline of Final Research Achievements

Hyperdoping of silicon with deep impurities is one of the candidates to improve efficiency of solar cells. We suggested appropriate conditions to prepare samples with less segregation keeping single crystal structure by pulsed laser processes. The results of optical absorption and electric conductivity are inconsistent, if we assume, as discussed previously, that both the metallic conductivity and large mid-infrared absorption are due to the formation of intermediate band. We proposed new candidates of the origin of these characters based on the experimental results.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (44 results)

All 2015 2014 2013 2012 Other

All Journal Article (9 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 3 results) Presentation (35 results)

  • [Journal Article] Correlation between crystallinity and mid-infrared optical absorption spectra of silicon supersaturated with sulfur2015

    • Author(s)
      Ikurou Umezu, Katsuki Nagao, Tatsuya Nakai, Muneyuki Naito, Mitsuru Inada, Tadashi Saitoh, Tamao Aoki and Akira Sugimura
    • Journal Title

      Mater. Res. Soc. Symp. Proc.

      Volume: 1738 Pages: 1-6

    • DOI

      10.1557/opl.2015.278

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structural properties of TiO2 nanocrystallites condensed in vapor-phase for photocatalyst applications2014

    • Author(s)
      Takehito Yoshida, Nobuyasu Yagi, Riki Nakagou, Akira Sugimura, kurou Umezu
    • Journal Title

      Appl. Phys. A

      Volume: 117 Issue: 1 Pages: 223-227

    • DOI

      10.1007/s00339-014-8378-3

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hyperdoping of silicon with deep-level impurities by pulsed YAG laser melting2014

    • Author(s)
      Ikurou Umezu, Muneyuki Naito, Daisuke Kawabe, Yusuke Koshiba, Katsuki Nagao, Akira Sugimura, Tamao Aoki, Mitsuru Inada, Tadashi Saitoh, Atsushi Kohno
    • Journal Title

      Appl. Phys. A

      Volume: 117 Issue: 1 Pages: 155-159

    • DOI

      10.1007/s00339-014-8313-7

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] パルスレーザー励起非平衡材料プロセスがもたらす階層構造形成 : 超新星爆発とのアナロジー2014

    • Author(s)
      梅津 郁 朗, 富永 望, 須佐 元, and 秋 宗 秀俊
    • Journal Title

      電気学会研究会資料 光・量子デバイス研究会

      Volume: OQD-14-005~014 Pages: 41-46

    • Related Report
      2013 Research-status Report
  • [Journal Article] Hierarchical Pattern Structure in TiO2 Nano-Aggregates Prepared by Pulsed Laser Ablation in Background Gas2013

    • Author(s)
      Ikurou Umezu, Akira Sugimura and Takehito Yoshida
    • Journal Title

      2013 Conference on Lasers and Electr-optics Pacific Rim (CLEO-PR)

      Volume: TuE3-4 Pages: 1-2

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Non-equilibrium Growth Processes of Porous TiO2 Nanocrystal-films during Pulsed Laser Ablation2013

    • Author(s)
      Ikurou Umezu, Nobuyasu Yagi, Akira Sugimura and Takehito Yoshida
    • Journal Title

      MRS Proceedings

      Volume: 1497

    • DOI

      10.1557/opl.2013.495

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fluid simulation of plume head-on collision dynamics during pulsed laser ablation2013

    • Author(s)
      R. Fujii, K. Doi, Y. Yokoyama, H. Fukuoka, A. Sugimura, N. Tominaga, H. Susa, I. Umezu
    • Journal Title

      Journal of physics; conference series

      Volume: -

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Emergence of very broad infrared absorption band by hyperdoping of silicon with chalcogens2013

    • Author(s)
      Ikurou Umezu, Jeffrey M. Warrender, Supakit Charnvanichborikarn, Atsushi Kohno, James S. Williams, Malek Tabbal, Dimitris G. Papazoglou, Xi-Cheng Zhang, and Michael J. Aziz
    • Journal Title

      Journal of Applied Physics

      Volume: -

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Supersaturated doping of silicon with titanium by pulsed laser melting method2012

    • Author(s)
      Daisuke Kawabel, Shou Nakagawa, Yuuki Matsudal, Akira Sugimura, and Ikurou Umezu
    • Journal Title

      Mem. Konan Univ., Sci. & Eng. Ser.

      Volume: 58 Pages: 21-32

    • NAID

      110009573954

    • Related Report
      2012 Research-status Report
  • [Presentation] 硫黄を過飽和ドープしたSi単結晶の中赤外光吸収スペクトルの結晶構造依存性2015

    • Author(s)
      中井 達也、内藤 宗幸、小林 勇輝、長尾 克紀、青木 珠緒、杉村 陽、梅津 郁朗
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス (神奈川県平塚市)
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Correlation Between Crystallinity and Mid-Infrared Optical Absorption Spectra of Silicon Supersaturated with Sulfur2014

    • Author(s)
      Ikurou Umezu, Katsuki Nagao, Tatsuya Nakai, Mneyuki Naito, Mitsuru Inada, Tadashi Saitoh, Tamao Aoki, Akira Sugimura
    • Organizer
      2014 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, Massachusetts (USA)
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] 硫黄を過飽和ドープしたSi単結晶への熱アニーリングの効果2014

    • Author(s)
      長尾克紀,斎藤正,稲田貢,丹野裕貴,内藤宗幸,小林勇輝,青木珠緒,杉村陽,梅津郁朗
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス(北海道札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 硫黄を過飽和ドープしたSi単結晶の光吸収と電気伝導特性2014

    • Author(s)
      中井達也,内藤宗幸,小林勇輝,長尾克紀,青木珠緒,杉村陽,梅津郁朗
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス(北海道札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] パルスレーザアブレーション中の2つのプルームに衝撃波が与える影響2014

    • Author(s)
      萩原宏規,浜岡克佳,香下将希,福岡寛,梅津郁朗
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス(北海道札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] ダブルパルスレーザーアブレーション過程で生成したナノ結晶とデブリの堆積2014

    • Author(s)
      香下将希,福岡寛,杉村陽,青木珠緒,梅津郁朗
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス(北海道札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] パルスレーザーアブレーションで作製したTiO2ナノ結晶凝集体の表面構造と光触媒機能の相関2014

    • Author(s)
      若宮千司,渡辺てい,青木珠緒,梅津郁朗,杉村陽,吉田岳人
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス(北海道札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pulsed laser irradiation-induced microstructures in the Mn ion implanted Si2014

    • Author(s)
      Muneyuki Naito, Ryo Yamada, Nobuya Machida, Yusuke Koshiba, Akira Sugimura, Tamao Aoki, and Ikurou Umezu
    • Organizer
      19th International Conference on Ion Beam Modification of Materials
    • Place of Presentation
      Leuven (Belgium)
    • Year and Date
      2014-09-14 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Nanoparticle formation by interaction between laser ablated plume and shock waves2014

    • Author(s)
      Eri Ueno, Naoaki Fukuda, Hiroshi Fukuoka, Minoru Yaga, Ikurou Umezu Min Han and Toshio Takiya
    • Organizer
      International Symposium on Small Particles and Inorganic Clusters
    • Place of Presentation
      Fukuoka (Japan)
    • Year and Date
      2014-09-07 – 2014-09-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Hyperdoping of silicon with deep-level impurities by pulsed YAG laser melting2013

    • Author(s)
      Ikurou Umezu, Muneyuki Naito, Daisuke Kawabe, Yusuke Koshiba, Katsuki Nagao, Akira Sugimura, Tamao Aoki, Mitsuru Inada, Tadashi Saitoh, Atsushi Kohno
    • Organizer
      The 12th International Conference on Laser Ablation
    • Place of Presentation
      Ischia,Italy
    • Related Report
      2013 Research-status Report
  • [Presentation] Structural properties of TiO2 nanocrystallites condensed in vapor-phase for photocatalyst applications2013

    • Author(s)
      Takehito Yoshida, Nobuyasu Yagi, Riki Nakagou, Akira Sugimura, Ikurou Umezu
    • Organizer
      The 12th International Conference on Laser Ablation
    • Place of Presentation
      Ischia,Italy
    • Related Report
      2013 Research-status Report
  • [Presentation] Effects of Shock Wave on Plume by Double Pulsed Laser Ablation2013

    • Author(s)
      Hiroki Hagihara, Yasuhiro Yokoyama, Yusuke Hashiguchi, Hiroshi Fukuoka, Ikurou Umezu
    • Organizer
      The 12th International Conference on Laser Ablation
    • Place of Presentation
      Ischia,Italy
    • Related Report
      2013 Research-status Report
  • [Presentation] 硫黄を過飽和ドープしたSi単結晶の光吸収と電気伝導特性の濃度依存性2013

    • Author(s)
      松田祐樹,長尾克己,香野 淳,杉村 陽,梅津郁朗
    • Organizer
      レーザー学会学術講演会第33回年次大会
    • Place of Presentation
      姫路商工会議所
    • Related Report
      2012 Research-status Report
  • [Presentation] パルスレーザーメルティングによるSiへの Tiの過飽和ドープと赤外光吸収のTi濃度依存性2013

    • Author(s)
      川邊大介,松田祐樹,小柴悠資,杉村 陽,梅津郁朗
    • Organizer
      レーザー学会学術講演会第33回年次大会
    • Place of Presentation
      姫路商工会議所
    • Related Report
      2012 Research-status Report
  • [Presentation] ダブルレーザーアブレーション法によるプルームの挙動と複合ナノ結晶の作成2013

    • Author(s)
      横山泰寛,橋口友亮,杉村 陽,梅津郁朗,福岡 寛
    • Organizer
      レーザー学会学術講演会第33回年次大会
    • Place of Presentation
      姫路商工会議所
    • Related Report
      2012 Research-status Report
  • [Presentation] ガス中レーザーアブレーション過程でのナノ結晶集合体の階層構造形成2013

    • Author(s)
      梅津郁朗,杉村陽,吉田岳人
    • Organizer
      第60回応用物理学会春期学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 反応性パルスレーザーアブレーション法によるNiOyナノ結晶堆積膜の構造と光学特性2013

    • Author(s)
      吉田岳人,廣田政人,田中潤,杉村陽,梅津郁朗
    • Organizer
      第60回応用物理学会春期学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Research-status Report
  • [Presentation] パルスレーザーメルティング法によるSiへのMnの過飽和ドープ2012

    • Author(s)
      小柴悠資,川邊大介,松田祐樹,杉村 陽,梅津郁朗
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] ダブルレーザーアブレーション法による複合ナノ結晶形成に対するパルスディレイの効果2012

    • Author(s)
      橋口友亮,福岡 寛,横山泰寛,杉村 陽,梅津郁朗
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 反応性パルスレーザーアブレーション法によるTiO2ナノ構造体の光触媒活性制御2012

    • Author(s)
      吉田岳人,八木信賢,中郷 力,近藤雅斗,杉村 陽,梅津郁朗
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] パルスレーザーメルティングによるSiへのTiの過飽和ドープII2012

    • Author(s)
      川邊大介,杉村 陽,梅津郁朗
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Fluid simulation of plume head-on collision dynamics during pulsed laser ablation2012

    • Author(s)
      R. Fujii, K. Doi, Y. Yokoyama, H. Fukuoka, A. Sugimura, N. Tominaga, H. Susa, I. Umezu
    • Organizer
      Conference on Computational Physics (CCP2012)
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Formation of Silicon Supersaturated with deep Impurities by Pulsed Laser Melting Method2012

    • Author(s)
      D. Kawabe, Y. Matsuda, A. Sugimura and I. Umezu
    • Organizer
      MNC 2012, 25th International Microprocesses and Nanotechnology Conference
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Effect of Collision of Plumes on Formation of Compound Nanocrystal by Double Laser Ablation2012

    • Author(s)
      Y. Hashiguchi, H. Fukuoka, N. Sakamoto, Y. Yokoyama, A. Sugimura and I. Umezu
    • Organizer
      MNC 2012, 25th International Microprocesses and Nanotechnology Conference
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Non-equilibrium Growth Processes of Porous TiO2 Nanocrystal-films during Pulsed Laser Ablation2012

    • Author(s)
      Ikurou Umezu, Nobuyasu Yagi, Akira Sugimura, Takehito Yoshida
    • Organizer
      2012 MRS Fall Meeting
    • Place of Presentation
      Boston, Massachusetts,USA
    • Related Report
      2012 Research-status Report
  • [Presentation] Possibility to Form Intermediate Band by Hyperdoping of Silicon with Deep Level Impurities

    • Author(s)
      Ikurou Umezu, Katsuki Nagao, Daisuke Kawabe, Yusuke Koshiba, Akira Sugimura, Mitsuru Inada, Tadashi Saitoh and Atsushi Kohno
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Hierarchical Pattern Structure in TiO2 Nano-Aggregates Prepared by Pulsed Laser Ablation in Background Gas

    • Author(s)
      Ikurou Umezu, Akira Sugimura, and Takehito Yoshida
    • Organizer
      2013 Conference on lLasers and Electr-optics Pacific Rim (CLEO-PR)
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] パルスレーザーアブレーション法でのプルーム衝突によるデブリの軽減

    • Author(s)
      香下将希,横山泰寛,福岡寛,杉村陽,梅津郁朗
    • Organizer
      応用物理学会
    • Place of Presentation
      同志社大学 京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 硫黄を過飽和ドープしたSi単結晶の光吸収と電気伝導特性の相関

    • Author(s)
      長尾克紀,齊藤正,稲田貢,杉村陽,梅津郁朗
    • Organizer
      応用物理学会
    • Place of Presentation
      同志社大学 京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] パルスレーザーメルティング法によるSi中でのMnの拡散と偏析

    • Author(s)
      小柴悠資,川邊大介,杉村陽,梅津郁朗
    • Organizer
      応用物理学会
    • Place of Presentation
      同志社大学 京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] パルスレーザーアブレーション過程でのTiO2ナノ結晶の網目構造凝集体形成とその光吸収特性

    • Author(s)
      若宮千司,梅津郁朗,杉村陽,吉田岳人
    • Organizer
      応用物理学会
    • Place of Presentation
      同志社大学 京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] ダブルレーザーアブレーション法による複合ナノ結晶形成に対するプルーム衝突の効果

    • Author(s)
      橋口友亮,香下将希,福岡 寛,坂本直道,青木珠緒,杉村 陽,梅津郁朗
    • Organizer
      レーザー学会学術講演会第34回年次大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] パルスレーザーメルティング法によりMnを過飽和ドープしたSiの電気伝導特性

    • Author(s)
      小柴悠資,山田涼,内藤宗幸,青木珠緒,杉村陽,梅津郁朗
    • Organizer
      応用物理学会
    • Place of Presentation
      青山学院大学 相模原キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] ダブルレーザーアブレーション法による複合ナノ結晶形成に対するプルーム衝突の効果

    • Author(s)
      橋口友亮,福岡寛,香下将希,坂本直道,青木珠緒,杉村陽,梅津郁朗
    • Organizer
      応用物理学会
    • Place of Presentation
      青山学院大学 相模原キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] パルスレーザーメルティング法を用いて硫黄を過飽和ドープしたSi単結晶の光吸収と電気伝導特性のフルーエンス依存性

    • Author(s)
      長尾克紀,稲田貢,内藤宗幸,則村憲吾,中井達也,青木珠緒,杉村陽,梅津郁朗
    • Organizer
      応用物理学会
    • Place of Presentation
      青山学院大学 相模原キャンパス
    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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