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Creation of electromagnetic model for vulcanization reaction in rubbers by terahertz spectroscopy

Research Project

Project/Area Number 24560056
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Applied optics/Quantum optical engineering
Research InstitutionKurume National College of Technology

Principal Investigator

HIRAKAWA Yasuyuki  久留米工業高等専門学校, 電気電子工学科, 教授 (80238344)

Co-Investigator(Kenkyū-buntansha) TONOUCHI Masayoshi  大阪大学, レーザーエネルギー学研究センター, 教授 (40207593)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsテラヘルツ / ゴム / エラストマー / 加硫反応 / 非破壊検査 / 等価回路 / テラヘルツ計測 / 非破壊計測 / ゴム評価
Outline of Final Research Achievements

In this study, a vulcanization reaction of rubbers was investigated by both electrical measurements and terahertz (THz) spectroscopy. As a tradition model of rubbers, a parallel circuit consist of a resistance and a capacitance was proposed, however, we found that a series circuits of a few parallel circuits can be consistent with the temporal variation of electrical characteristics including impedance, resistance and reactance. As for THz measurements, it was found that the THz absorbance indicated the minimum values near the optimum cure time of T90 decided by the conventional torque-cure time curve, and also found that the THz characteristics was so unstable under the existence of filler material of carbon black. This instability probably caused by some scattering inside rubber samples or surface plasmon effects. In order to clarify this instability, further investigation is necessary.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (14 results)

All 2014 2013 2012 Other

All Presentation (10 results) Remarks (4 results)

  • [Presentation] テラヘルツ分光によるゴム練り行程中の配合剤分析2014

    • Author(s)
      平川靖之、権藤豊彦、渡邊勝宏、森 哲夫、藤 道治
    • Organizer
      平成26年度応用物理学会九州支部学術講演会
    • Place of Presentation
      大分大学
    • Year and Date
      2014-12-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] テラヘルツ光によるゴム加硫反応評価の可能性2014

    • Author(s)
      平川靖之、権藤豊彦、渡邊勝宏、森 哲夫、藤 道治
    • Organizer
      日本ゴム協会第26回エラストマー討論会
    • Place of Presentation
      愛知工業大学
    • Year and Date
      2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Temporal measurements of electric impedance of rubber during vulcanization2013

    • Author(s)
      R. Miratsu, Y. Hirakawa, T. Gondoh, K. Watanabe, T. Mori
    • Organizer
      3rd Thailand-Japan Rubber Symposium
    • Place of Presentation
      Tokyo National College of Technology, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] ゴムの加硫時における電気物性測定2012

    • Author(s)
      見良津黎、税田祐毅、平川靖之、権藤豊彦、渡邊勝宏、森 哲夫
    • Organizer
      日本ゴム協会2012年年次大会研究発表会
    • Place of Presentation
      京都大学 桂キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Detection of Additives Localization in Rubber Vulcanizates by Terahertz Spectroscopy2012

    • Author(s)
      Y. Saita, Y. Hirakawa, Y. Ohno, T. Gondoh, T. Mori, M. Tonouchi, H. Ohtake, T. Hirosumi
    • Organizer
      The 2nd International Symposium on Terahertz Nanoscience (TeraNano 2012)
    • Place of Presentation
      (独)情報通信研究機構 沖縄電磁波技術センター
    • Related Report
      2012 Research-status Report
  • [Presentation] Changes of Electric Characteristics of Rubber Compounds during Vulcanization Reaction2012

    • Author(s)
      R. Miratsu, Y. Hirakawa, T. Gondoh, K. Watanabe, T. Mori
    • Organizer
      2012 International Symposium on Technology for Sustainability (ISTS2012)
    • Place of Presentation
      Swissotel Le Concorde, Bankok, Thailand
    • Related Report
      2012 Research-status Report
  • [Presentation] Visualization of Progress of Vulcanization Reaction in Rubbers by Terahertz Time-domain Spectroscopy

    • Author(s)
      T. Eguchi, Y. Saita, Y. Hirakawa, T. Gondoh, T. Mori, M. Tonouchi, H. Ohtake, T. Hirosumi
    • Organizer
      International Workshop on Optical Terahertz Science and Technology 2013(OTST2013)
    • Place of Presentation
      Kyoto Terrs, Kyoto, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Distribution Variation of Carbon Black in Tensile-Tested Rubbers Estimated by Terahertz Time-Domain Spectroscopy

    • Author(s)
      Y. Hirakawa, Y. Ohno, T. Gondoh, T. Mori, M. Tonouchi, H. Ohtake, T. Hirosumi
    • Organizer
      The 10th Conference on Lasers and Electro-Optics Pacific Rim (CLEO-PR 2013)
    • Place of Presentation
      Kyoto International Conference Center, Kyoto, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] テラヘルツ光吸収特性によるゴム評価の可能

    • Author(s)
      平川靖之, 税田祐毅, 大野義智, 権藤豊彦, 森 哲夫, 野口 剛, 斗内政吉, 大竹秀幸
    • Organizer
      日本ゴム協会 第25回事例発表会
    • Place of Presentation
      JR博多シティ, 福岡
    • Related Report
      2013 Research-status Report
  • [Presentation] テラヘルツ分光を用いたエラストマー内のフィラー分散評価

    • Author(s)
      青栁 美里, 見良津 黎, 平川 靖之, 野口 剛, 斗内 政吉, 大竹 秀幸
    • Organizer
      日本ゴム協会 第25回エラストマー討論会
    • Place of Presentation
      京都大学、京都
    • Related Report
      2013 Research-status Report
  • [Remarks] 研究:THz分光法

    • URL

      http://apollo.cc.kurume-nct.ac.jp/~hirakawa/world/Lab_Files/index.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 研究シーズ

    • URL

      http://www101.cc.kurume-nct.ac.jp/profile/Es26-hirakawa.pdf

    • Related Report
      2014 Annual Research Report
  • [Remarks] 研究:THz分光法

    • URL

      http://apollo.cc.kurume-nct.ac.jp/~hirakawa/world/Lab_Files/sub6.html

    • Related Report
      2013 Research-status Report
  • [Remarks] 研究シーズ

    • URL

      http://www101.cc.kurume-nct.ac.jp/profile/EE/hirakawa.html

    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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