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Study on MOCVD growth of InN-based semiconductors using NH3 decomposition catalysts

Research Project

Project/Area Number 24560370
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionUniversity of Fukui

Principal Investigator

YAMAMOTO Akio  福井大学, 産学官連携本部, 客員教授 (90210517)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords窒化インジウム / アンモニア / MOCVD / 触媒 / アンモニア分解触媒 / MOVPE成長 / 窒化物半導体 / MOCVD
Outline of Final Research Achievements

In the MOCVD using NH3 as a nitrogen source, the growth a high quality InN is expected if a high density of active nitrogen species such as NH2 is supplied at a low growth temperature (500 deg. C or less). In this study, the MOCVD growth of InN using NH3 decomposition catalyst is investigated. As a NH3 decomposition catalyst, the N134 ammonia decomposition catalysts produced by JGC Catalysts and Chemicals Ltd, Japan is employed in this study. It is found that single-crystalline InN can be grown even at 450 deg. C, which is much lower than the optimum growth temperature (600 deg. C) in the conventional MOCVD of InN. In addition, it is found that the migration of growing InN on GaN surface is highly enhanced at around 500 deg. C. Films of InGaN with InN content around 30 % is proved to be grown even at 480 deg. C. These results clearly indicate that the catalyst-assisted MOCVD can become a powerful method for film growth of high-quality InN-based materials in the near future.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (8 results)

All 2015 2013 2012

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (4 results) (of which Invited: 1 results)

  • [Journal Article] Growth temperature dependent critical thickness for phase separation in thick (~1 μm) InxGa1-xN (x = 0.2~0.4)2015

    • Author(s)
      A. Yamamoto, Tanvir Md Hasan, K. Kodama, N. Shigekawa, M. Kuzuhara
    • Journal Title

      Journal of Crystal Growth

      Volume: 419 Pages: 64-68

    • DOI

      10.1016/j.jcrysgro.2015.02.100

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalyst Temperature Dependence of NH3 Decomposition for InN Grown by Metal Organic Vapor Phase Epitaxy2013

    • Author(s)
      K. Sugita, D. Hironaga, A. Mihara, A. Hashimoto, A. Yamamoto
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 8S Pages: 08JD04-08JD04

    • DOI

      10.7567/jjap.52.08jd04

    • NAID

      210000142639

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Comparative Study on Metalorganic Vapor Phase Epitaxial InGaN with Intermediate In Compositions Grown on GaN/Sapphire Template and AlN/Si(111) Substrate2013

    • Author(s)
      A. Yamamoto, A. Mihara, Y. Zheng, N. Shigekawa
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 8S Pages: 08JB19-08JB19

    • DOI

      10.7567/jjap.52.08jb19

    • NAID

      210000142613

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Superconducting Properties of InN with Low Carrier Density near the Mott Transition2012

    • Author(s)
      T.Inushima, S.Kimura, 他6名
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 81 Issue: 4 Pages: 44704-44704

    • DOI

      10.1143/jpsj.81.044704

    • NAID

      210000109495

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] アンモニア分解触媒援用MOVPE法によるInNの低温成長2015

    • Author(s)
      山本あき勇,児玉和樹,野村裕之,葛原正明
    • Organizer
      第7回窒化物半導体結晶成長講演会(プレISGN-6)
    • Place of Presentation
      仙台市
    • Year and Date
      2015-05-07 – 2015-05-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] Reduction of In incorporation by Si-doping in MOVPE-grown InxGa1-xN (x~0.3)2013

    • Author(s)
      A. Mihara, N. Shigekawa, A. Yamamoto
    • Organizer
      10th International Conference on Nitride Semiconductors
    • Place of Presentation
      Washington DC (USA)
    • Related Report
      2013 Research-status Report
  • [Presentation] Catalyst temperature (RT-1000ºC) dependence of NH3 decomposition for MOVPE growth of InN2012

    • Author(s)
      K. Sugita, D. Hironaga, A. Mihara, A. Hashimoto, A. Yamamoto
    • Organizer
      International Workshop on Nitride Semiconductors 2012
    • Place of Presentation
      Sapporo, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Growth of InN by the conventional, ArF excimer laser-assisted, and Pt catalyst-assisted MOCVD methods2012

    • Author(s)
      Akio Yamamoto and Ken-ichi Sugita
    • Organizer
      Intensive Discussion on Growth of Nitride Semiconductors
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2012 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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