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Syntheses and evaluation of organic electrical conduction materials with highly arranged by mixed coordinate bonds

Research Project

Project/Area Number 24560378
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionKyushu Institute of Technology

Principal Investigator

MORIGUCHI Tetsuji  九州工業大学, 大学院工学研究院, 助教 (40243985)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords錯体 / 有機材料 / 蛍光 / 半導体 / 金属錯体 / 有機半導体 / ランタノイド / 固体蛍光 / 濃度消光 / 縮環芳香族 / 結晶構造 / デバイス / 単結晶X線構造解析 / n型半導体 / p型半導体 / 平面型錯体
Outline of Final Research Achievements

Organic electrical conduction materials with highly arranged by mixed coordinate bondswere synthesized and evaluated.
Lanthanide and d metal complexes were synthesized with functional organic molecules as ligands using coordinate bonds. The molecullar structures were determined by X-ray single structure analyses, and the luminescentproperties were also measured.It was found that the orientation can be controlled by centered metal ion. It was revealed that it's also able to control luminescence properties by centered metal ion to do characteristic evaluation of rare earth ion complex in particular.
The functional organic molecules having lactone substituents were also synthesized.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (15 results)

All 2014 2013

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 5 results,  Acknowledgement Compliant: 3 results) Presentation (10 results)

  • [Journal Article] Synthesis and Molecular Structure of tert-Butyl 3-oxo-2-oxa-5-azabicyclo[2.2.2]octane-5-carboxylate2014

    • Author(s)
      Tetsuji Moriguchi, Suvratha Krishnamurthy, Toru Arai, Taisuke Matsumoto, Koji Araki, Akihiko Tsuge, and Norikazu Nishino
    • Journal Title

      Journal of Crystallography

      Volume: 2014 Pages: 1-6

    • DOI

      10.1155/2014/645079

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Molecular Structure and Crystal Packing of n-TypeSemiconducting Material 3',3'-(1,4-Phenylene)bis{2'-(4''-trifluoromethyl)phenyl}acrylonitrile2014

    • Author(s)
      Tetsuji Moriguchi, Shuichi Nagamatsu, Tatsuo Okauchi, Akihiko Tsuge, Wataru Takashima, and Shuji Hayase
    • Journal Title

      Journal of Crystallography

      Volume: 2014 Pages: 1-5

    • DOI

      10.1155/2014/257249

    • NAID

      120005868679

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis and Molecular Structure of Chiral (2S, 5S)-tert-Butyl 3-Oxo-2-oxa-5-azabicyclo[2.2.2]octane-5-carboxylate2014

    • Author(s)
      Tetsuji Moriguchi, Suvratha Krishnamurthy, Toru Arai, and Akihiko Tsuge
    • Journal Title

      Journal of Crystallography

      Volume: 2014 Pages: 1-6

    • DOI

      10.1155/2014/150796

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and Molecular Structure of 4',9',4'',9''-Tetra-tert-butyl-1',6',1'',6''-tetramethoxy-2,5-dioxa[3.3]metabiphenylophane2014

    • Author(s)
      Tetsuji Moriguchi, Tatsuya Egami, and Akihiko Tsuge
    • Journal Title

      Journal of Crystallography

      Volume: 2014 Pages: 1-7

    • DOI

      10.1155/2014/695701

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis, Characterization, and Crystal Structure of Pyridinium Tetrakis{1-trifluoromethyl-3-(1'-pyreno)-1,3-propanedionato}lanthanate(III) Complex2014

    • Author(s)
      Tetsuji Moriguchi, Kenji Yoza, and Akihiko Tsuge
    • Journal Title

      Journal of Crystallography

      Volume: 2014 Pages: 1-6

    • DOI

      10.1155/2014/271238

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Stable Hole Transfer Twisted Polynuclear Heteroaromatics (PHAs)2014

    • Author(s)
      T. Moriguchi, Y. Nishizawa, A. Tsuge, T. Okauchi, S. Nagamatsu, W. Takashima
    • Organizer
      20th International Conference on Photochemical Conversion and Storage of Solar Energy (IPS-20)
    • Place of Presentation
      Berlin, Germany
    • Year and Date
      2014-07-27 – 2014-08-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] 架橋部に水素結合部位を有するシクロファン類の合成とそれらのゲル化特性2014

    • Author(s)
      藤原続道・森口哲次・荒木孝司・柘植顕彦
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 長鎖アルキル基を有するシクロファン類の合成とそのロタキサン構造の特性評価2014

    • Author(s)
      岩本拓也・森口哲次・荒木孝司・柘植顕彦
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] クマリン骨格を有するゲル化剤の合成とその発光ゲル化剤としての特性に関する研究2014

    • Author(s)
      木登直弥・森口哲次・荒木孝司・柘植顕彦
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Novel Highly Twisted Polynuclear Heteroaromatics (PHAs)2013

    • Author(s)
      Tetsuji Moriguchi
    • Organizer
      44th IUPAC World Chemistry Congress
    • Place of Presentation
      イスタンブル
    • Related Report
      2013 Research-status Report
  • [Presentation] 亜鉛ポルフィリンの配位を利用したピリジノファンの動的特性制御2013

    • Author(s)
      田浦裕樹・森口哲次・荒木孝司・柘植顕彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 隈元康太・森口哲次・荒木孝司・柘植顕彦2013

    • Author(s)
      β-ジケトン体を基本骨格とする配位子のゲル化挙動に関する研究
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 池田脩・森口哲次・荒木孝司・柘植顕彦2013

    • Author(s)
      赤色発光型ユーロピウム錯体を用いたゲル化剤の開発
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 西沢悠生・山下哲央・森口哲次・永松秀一・柘植顕彦2013

    • Author(s)
      ピレン骨格を母体とする縮環芳香族化合物への置換基導入とその特性
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 小田晶美・森口哲次・荒木孝司・柘植顕彦2013

    • Author(s)
      無機物表面に親和性を有する強赤色発光Eu錯体の合成と評価
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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