Syntheses and evaluation of organic electrical conduction materials with highly arranged by mixed coordinate bonds

• Project/Area Number: 24560378
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Electronic materials/Electric materials
• Research Institution: Kyushu Institute of Technology
• Principal Investigator: MORIGUCHI Tetsuji 九州工業大学, 大学院工学研究院, 助教 (40243985)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000); Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
• Keywords: 錯体 / 有機材料 / 蛍光 / 半導体 / 金属錯体 / 有機半導体 / ランタノイド / 固体蛍光 / 濃度消光 / 縮環芳香族 / 結晶構造 / デバイス / 単結晶Ｘ線構造解析 / ｎ型半導体 / ｐ型半導体 / 平面型錯体

Outline of Final Research Achievements

Organic electrical conduction materials with highly arranged by mixed coordinate bondswere synthesized and evaluated.
Lanthanide and d metal complexes were synthesized with functional organic molecules as ligands using coordinate bonds. The molecullar structures were determined by X-ray single structure analyses, and the luminescentproperties were also measured.It was found that the orientation can be controlled by centered metal ion. It was revealed that it's also able to control luminescence properties by centered metal ion to do characteristic evaluation of rare earth ion complex in particular.
The functional organic molecules having lactone substituents were also synthesized.

Research Products

• [Journal Article] Synthesis and Molecular Structure of tert-Butyl 3-oxo-2-oxa-5-azabicyclo[2.2.2]octane-5-carboxylate (2014)
  • Author(s): Tetsuji Moriguchi, Suvratha Krishnamurthy, Toru Arai, Taisuke Matsumoto, Koji Araki, Akihiko Tsuge, and Norikazu Nishino
  • Journal Title: Journal of Crystallography Volume: 2014 Pages: 1-6
  • DOI: 10.1155/2014/645079
  • Peer Reviewed / Open Access
• [Journal Article] Molecular Structure and Crystal Packing of n-TypeSemiconducting Material 3',3'-(1,4-Phenylene)bis{2'-(4''-trifluoromethyl)phenyl}acrylonitrile (2014)
  • Author(s): Tetsuji Moriguchi, Shuichi Nagamatsu, Tatsuo Okauchi, Akihiko Tsuge, Wataru Takashima, and Shuji Hayase
  • Journal Title: Journal of Crystallography Volume: 2014 Pages: 1-5
  • DOI: 10.1155/2014/257249
  • NAID: 120005868679
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Synthesis and Molecular Structure of Chiral (2S, 5S)-tert-Butyl 3-Oxo-2-oxa-5-azabicyclo[2.2.2]octane-5-carboxylate (2014)
  • Author(s): Tetsuji Moriguchi, Suvratha Krishnamurthy, Toru Arai, and Akihiko Tsuge
  • Journal Title: Journal of Crystallography Volume: 2014 Pages: 1-6
  • DOI: 10.1155/2014/150796
  • Peer Reviewed / Open Access
• [Journal Article] Synthesis and Molecular Structure of 4',9',4'',9''-Tetra-tert-butyl-1',6',1'',6''-tetramethoxy-2,5-dioxa[3.3]metabiphenylophane (2014)
  • Author(s): Tetsuji Moriguchi, Tatsuya Egami, and Akihiko Tsuge
  • Journal Title: Journal of Crystallography Volume: 2014 Pages: 1-7
  • DOI: 10.1155/2014/695701
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Synthesis, Characterization, and Crystal Structure of Pyridinium Tetrakis{1-trifluoromethyl-3-(1'-pyreno)-1,3-propanedionato}lanthanate(III) Complex (2014)
  • Author(s): Tetsuji Moriguchi, Kenji Yoza, and Akihiko Tsuge
  • Journal Title: Journal of Crystallography Volume: 2014 Pages: 1-6
  • DOI: 10.1155/2014/271238
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Presentation] Stable Hole Transfer Twisted Polynuclear Heteroaromatics (PHAs) (2014)
  • Author(s): T. Moriguchi, Y. Nishizawa, A. Tsuge, T. Okauchi, S. Nagamatsu, W. Takashima
  • Organizer: 20th International Conference on Photochemical Conversion and Storage of Solar Energy (IPS-20)
  • Place of Presentation: Berlin, Germany
  • Year and Date: 2014-07-27 – 2014-08-01
• [Presentation] 架橋部に水素結合部位を有するシクロファン類の合成とそれらのゲル化特性 (2014)
  • Author(s): 藤原続道・森口哲次・荒木孝司・柘植顕彦
  • Organizer: 日本化学会第94春季年会(2014)
  • Place of Presentation: 名古屋大学
• [Presentation] 長鎖アルキル基を有するシクロファン類の合成とそのロタキサン構造の特性評価 (2014)
  • Author(s): 岩本拓也・森口哲次・荒木孝司・柘植顕彦
  • Organizer: 日本化学会第94春季年会(2014)
  • Place of Presentation: 名古屋大学
• [Presentation] クマリン骨格を有するゲル化剤の合成とその発光ゲル化剤としての特性に関する研究 (2014)
  • Author(s): 木登直弥・森口哲次・荒木孝司・柘植顕彦
  • Organizer: 日本化学会第94春季年会(2014)
  • Place of Presentation: 名古屋大学
• [Presentation] Novel Highly Twisted Polynuclear Heteroaromatics (PHAs) (2013)
  • Author(s): Tetsuji Moriguchi
  • Organizer: 44th IUPAC World Chemistry Congress
  • Place of Presentation: イスタンブル
• [Presentation] 亜鉛ポルフィリンの配位を利用したピリジノファンの動的特性制御 (2013)
  • Author(s): 田浦裕樹・森口哲次・荒木孝司・柘植顕彦
  • Organizer: 日本化学会第９３春季年会
  • Place of Presentation: 立命館大学
• [Presentation] 隈元康太・森口哲次・荒木孝司・柘植顕彦 (2013)
  • Author(s): β-ジケトン体を基本骨格とする配位子のゲル化挙動に関する研究
  • Organizer: 日本化学会第９３春季年会
  • Place of Presentation: 立命館大学
• [Presentation] 池田脩・森口哲次・荒木孝司・柘植顕彦 (2013)
  • Author(s): 赤色発光型ユーロピウム錯体を用いたゲル化剤の開発
  • Organizer: 日本化学会第９３春季年会
  • Place of Presentation: 立命館大学
• [Presentation] 西沢悠生・山下哲央・森口哲次・永松秀一・柘植顕彦 (2013)
  • Author(s): ピレン骨格を母体とする縮環芳香族化合物への置換基導入とその特性
  • Organizer: 日本化学会第９３春季年会
  • Place of Presentation: 立命館大学
• [Presentation] 小田晶美・森口哲次・荒木孝司・柘植顕彦 (2013)
  • Author(s): 無機物表面に親和性を有する強赤色発光Ｅｕ錯体の合成と評価
  • Organizer: 日本化学会第９３春季年会
  • Place of Presentation: 立命館大学