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Preparation and evaluation of functional carbon materials on metal substrates deposited with hydrocarbon pyrolysis method

Research Project

Project/Area Number 24560820
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionThe University of Electro-Communications

Principal Investigator

TANAKA Katsumi  電気通信大学, 情報理工学(系)研究科, 教授 (30155121)

Co-Investigator(Kenkyū-buntansha) CHOO Cheowkeong  電気通信大学, 国際交流センター, 准教授 (00323882)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
KeywordsDLC / ラマン分光法 / 炭化水素熱分解 / 炭素同素体 / カーボンナノチューブ / 界面構造 / Nドープ / 炭化水素熱分解法 / ラマン分析法 / DLC / Nドープ
Outline of Final Research Achievements

The DLC thin films were prepared on metal substrates at 1073 to 1373 K under 1 atm. of methane and argon mixture gas. As metal substrates two kinds of Fe substrates with different purity at 99.5 and 99.99 % and SCM 440 substrate as one of steel materials. The surface compounds were analyzed with micro-Raman spectroscopy, hardness measurements and film thickness measurements with SEM. It was found that oxygen atoms migrate to the surface and to form Fe3O4 thin film on the Fe substrates with 99.5 % purity. The DLC films were successfully prepared even on Fe substrates with 99.5 % purity under optimum conditions. The intermediate compound formed between a metal substrate and the surface covering DLC film was analyzed with Raman spectroscopy.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (7 results)

All 2014 2013 Other

All Presentation (4 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Presentation] 13C、1H固体NMRを用いたN-dopedDLC膜の構造解析2014

    • Author(s)
      村田悠馬、Choo Cheowkeong、小野 洋、桑原大介、田中勝己
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      札幌市、北大
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] CoドープSrTiO3の可視光下での光触媒活性2014

    • Author(s)
      市原文彦、小野 洋、Choo Cheowkeong,田中勝己
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      札幌市、北大
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Characterization of N-doped DLC thin films prepared by hydrocarbons pyrolysis method2014

    • Author(s)
      Y. Murata, C-K. Choo, H. Ono, Y. Nagai, K. Tanaka
    • Organizer
      International Conference on Diamond and Carbon Materials
    • Place of Presentation
      Spain, Madrid
    • Year and Date
      2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] 熱分解法によるNドープDLC薄膜の作製と評価2013

    • Author(s)
      村田悠馬、田中勝己、小野洋、チュウチャオキョン、永井豊
    • Organizer
      第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Remarks] 最近発表した論文・特許・報告

    • URL

      http://tanaka.ee.uec.ac.jp/publications.html

    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] ダイヤモンドライクカーボン膜の成膜装置および形成方法2014

    • Inventor(s)
      西永 泰隆, 田中 勝己, Choo Cheow Keong
    • Industrial Property Rights Holder
      西永 泰隆, 田中 勝己, Choo Cheow Keong
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-098357
    • Filing Date
      2014-05-11
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] Metal Object with Diamond-like Carbon and Method for Forming Diamond-like Carbon Film2014

    • Inventor(s)
      K. Tanaka, C-K. Choo
    • Industrial Property Rights Holder
      K. Tanaka, C-K. Choo
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-07-10
    • Related Report
      2014 Annual Research Report
    • Overseas

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Published: 2013-05-31   Modified: 2019-07-29  

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