• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of Li-free self-cleaning glasses with quick pH response

Research Project

Project/Area Number 24560823
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionMie University

Principal Investigator

HASHIMOTO Tadanori  三重大学, 工学(系)研究科(研究院), 准教授 (10271016)

Co-Investigator(Kenkyū-buntansha) ISHIHARA Atsushi  三重大学, 大学院工学研究科, 教授 (60212908)
NASU Hiroyuki  三重大学, 大学院工学研究科, 准教授 (20189179)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
KeywordspH応答ガラス / Liフリー / 電子伝導ガラス / メンテナンスフリー / 光触媒活性 / 光誘起親水性 / 撥水性 / セルフクリーニングガラス / 元素戦略 / リチウムフリー / チタノリン酸塩ガラス / 鉄ビスマスホウ酸塩ガラス
Outline of Final Research Achievements

Commercially available pH electrodes (Li2O-SiO2-based glasses) have fatal problem that pH response is deteriorated by the accumulation of stain easily. In order to solve this problem, we developed two types of maintenance-free pH responsive glasses. The first one is Ti3+-containing TiO2-P2O5 (TP) glasses with self-cleaning property (photocatalytic activity and photo-induced hydrophilicity). The second one is Fe2O3-Bi2O3-B2O3 (FeBiB) glasses with anti-fouling property (hydrophobicity). In addition, we found that TP and FeBiB glasses show the quick pH response based on the electronic conduction as well as the high pH sensitivity.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (12 results)

All 2014 2013 2012 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (3 results) Remarks (1 results)

  • [Journal Article] Fe2O3-Bi2O3-B2O3 glasses as lithium-free nonsilicate pH responsive glasses - Compatibility between pH responsivity and hydrophobicity2014

    • Author(s)
      Tadanori Hashimoto, Mitsuaki Hamajima, Honami Ohta, Hiroyuki Nasu, Atsushi Ishihara, Yuji Nishio
    • Journal Title

      Materials Research Bulletin

      Volume: 50 Pages: 385-391

    • DOI

      10.1016/j.materresbull.2013.11.038

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of amorphous silica-alumina using polyethylene glycol and its role for matrix in catalytic cracking of n-dodecane2014

    • Author(s)
      Atsushi Ishihara, Takanori Wakamatsu, Hiroyuki Nasu, Tadanori Hashimoto
    • Journal Title

      Applied Catalysis A: General

      Volume: 478 Pages: 58-65

    • DOI

      10.1016/j.apcata.2014.03.016

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Catalytic Cracking of VGO by Hierarchical Y Zeolite-containing Mesoporous Silica–Alumina Catalysts Using Curie Point Pyrolyzer2014

    • Author(s)
      Atsushi ISHIHARA, Kentarou KIMURA, Tadanori HASHIMOTO, and Hiroyuki NASU
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 57 Issue: 1 Pages: 34-46

    • DOI

      10.1627/jpi.57.34

    • NAID

      130003392364

    • ISSN
      1346-8804, 1349-273X
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Titanophosphate Glasses as Lithium-Free Nonsilicate pH-responsive Glasses --- Compatibility between pH Responsivity and Self-Cleaning Properties2012

    • Author(s)
      T Hashimoto, M Wagu, K Kimura, H Nasu, A Ishihara, Y Nishio, Y Iwamoto
    • Journal Title

      Mater. Res. Bull.

      Volume: 47 Issue: 8 Pages: 1942-1949

    • DOI

      10.1016/j.materresbull.2012.04.030

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Facile morphology-controlled synthesis of Ba1-xSrxTiO3 (0 .LEQ. x < 1) crystals via a hydrothermal method2012

    • Author(s)
      H Nasu, S Ninagawa, K Inoue, T Hashimoto, A Ishihara
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 120 Issue: 1397 Pages: 43-46

    • DOI

      10.2109/jcersj2.120.43

    • NAID

      130002067688

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of hierarchical β and Y zeolite-containing mesoporous silica-aluminas and their properties for catalytic cracking of n-dodecane2012

    • Author(s)
      Atsushi Ishihara, Kentarou Inui, Tadanori Hashimoto, Hiroyuki Nasu
    • Journal Title

      Journal of Catalysis

      Volume: 295 Pages: 81-90

    • DOI

      10.1016/j.jcat.2012.07.027

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Large Mesopore Generation in an Amorphous Silica-Alumina by Controlling the Pore Size with the Gel Skeletal Reinforcement and Its Application to Catalytic Cracking2012

    • Author(s)
      A Ishihara, T Hashimoto, H Nasu
    • Journal Title

      Catalysts

      Volume: 2 Issue: 3 Pages: 368-385

    • DOI

      10.3390/catal2030368

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Catalytic Cracking of VGO by Hierarchical ZSM-5 Zeolite Containing Mesoporous Silica-Aluminas Using a Curie Point Pyrolyzer2012

    • Author(s)
      A Ishihara, K Kimura, A Owaki, K Inui, T Hashimoto, H Nasu
    • Journal Title

      Catal. Commun.

      Volume: 28 Pages: 163-167

    • DOI

      10.1016/j.catcom.2012.08.023

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Fe2O3-Bi2O3-B2O3ガラスのpH応答性能の組成依存性2014

    • Author(s)
      橋本忠範・村山文哉・那須弘行・石原 篤・西尾友志
    • Organizer
      第27回秋季シンポジウム
    • Place of Presentation
      鹿児島県鹿児島市鹿児島大学(郡元キャンパス)
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] pH応答性能と撥水性を有するFe2O3-Bi2O3-B2O3ガラスの開発2013

    • Author(s)
      橋本忠範、太田帆奈美、那須弘行、石原 篤、西尾友志
    • Organizer
      第26回秋季シンポジウム
    • Place of Presentation
      長野
    • Related Report
      2013 Research-status Report
  • [Presentation] pH応答性能とセルフクリーニング機能を有するチタノリン酸塩ガラスの開発2012

    • Author(s)
      橋本忠範 ・那須弘行 ・石原 篤 ・西尾友志 ・岩本恵和
    • Organizer
      第53回ガラスおよびフォトニクス材料討論会
    • Place of Presentation
      札幌
    • Related Report
      2012 Research-status Report
  • [Remarks] 三重大学工学研究科分子素材工学専攻無機素材化学講座のホームページ

    • URL

      http://www.inorg.chem.mie-u.ac.jp

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi