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Improvement of the fuel cell performance by the ion transport number improvement of the rare earth doped ceria electrolyte

Research Project

Project/Area Number 24560828
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionKagoshima University

Principal Investigator

SAMESHIMA SOICHIRO  鹿児島大学, 理工学研究科, 准教授 (00274861)

Co-Investigator(Kenkyū-buntansha) HIRATA Yoshihiro  鹿児島大学, 大学院理工学研究科, 教授 (80145458)
MATSUNAGA Naoki  宮崎大学, 工学部, 准教授 (40405543)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords燃料電池 / 固体電解質 / イオン伝導 / セリア
Outline of Final Research Achievements

Cell performance for a thin Gd-doped ceria (GDC) electrolyte was measured for using a 3 vol% H2O-containing H2 fuel. Open circuit voltage and maximum power density of the GDC cell at 600-800 °C showed the maximum values at Gd-doped 0.1 in GDC. The excess oxygen vacancy, which did not contribute to the oxide ion conductivity, interacted with the H2 fuel to form electrons in GDC electrolyte, resulting in the decreased performance of GDC cells. The addition of proton conductor BaCe0.8Y0.2O3 into anode was not effective to improve the cell performance. The ball-milling of La0.8Sr0.2Co0.8Fe0.2O3 cathode powder decreased the charge transfer resistance at the cathode and increased the power density of the fuel cell due to increase triple phase boundary.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (9 results)

All 2014 2013 2012 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (5 results) (of which Invited: 2 results)

  • [Journal Article] Cell performance of SOFC using CH4-CO2 mixed gases2014

    • Author(s)
      Soichiro Sameshima, Naoki Furukawa, Yoshihiro Hirata, Taro Shimonosono
    • Journal Title

      Ceramics International

      Volume: 40 Issue: 4 Pages: 6279-6284

    • DOI

      10.1016/j.ceramint.2013.11.086

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of cathode on electric power of solid oxide fuel cells2014

    • Author(s)
      Naoki Furukawa, Soichiro Sameshima, Yoshihiro Hirata, Taro Shimonosono
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 122 Issue: 1423 Pages: 226-229

    • DOI

      10.2109/jcersj2.122.226

    • NAID

      130004480233

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Evaluation of Electric Power of SOFC Using Reformed Biogas2013

    • Author(s)
      Naoki Furukawa, Yoshihiro Hirata, Soichiro Sameshima, Naoki Matsunaga
    • Journal Title

      Materials Science Forum

      Volume: 761 Pages: 11-14

    • NAID

      130006982975

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of Composition of Gd-doped Ceria Electrolyte on Performance of Solid Oxide Fuel Cell2012

    • Author(s)
      Yuta Ibusuki, Yoshihiro Hirata, Soichiro Sameshima, Naoki Matsunaga
    • Journal Title

      Materials Science Forum

      Volume: 724 Pages: 389-392

    • DOI

      10.4028/www.scientific.net/msf.724.389

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Cell Performance of SOFC Using CH4-CO2 Mixed Gas2013

    • Author(s)
      S.Sameshima, N.Furukawa, Y.Hirata
    • Organizer
      The 10th Pacific Rim Conference on Ceramics anf Glass Technology
    • Place of Presentation
      San Diego, CA, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] Influence of Cathode on Electric Power of Solid Oxide Fuel Cell2013

    • Author(s)
      S. Sameshima, N. Furukawa, Y. Hirata
    • Organizer
      The 7th International Conference on the Science and Technology for Advance Ceramics
    • Place of Presentation
      Yokohama, Japan
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Influence of CH4 Composition of Biogas on Electric Power of Solid Oxide Fuel Cell2013

    • Author(s)
      S. Sameshima, N.Furukawa, Y. Hirata, T. Shimonosono
    • Organizer
      CJK2013 Jinju-Korea Conference
    • Place of Presentation
      Jinju, Korea
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Evaluation of electric power of SOFC using reformed biogas on Performance of Solid Oxide Fuel Cell

    • Author(s)
      Naoki Furukawa, YoshihiroHirata, Soichiro Sameshima, Naoki Matsunaga
    • Organizer
      The 14th International Symposium on Eco-materials Processing and Design, ISEPD2013
    • Place of Presentation
      Kagoshima, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] バイオガスを燃料とした固体酸化物形燃料電池の発電性能評価

    • Author(s)
      古川直樹,平田好洋,鮫島宗一郎
    • Organizer
      日本セラミックス協会2013年会
    • Place of Presentation
      東京
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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