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Performance enhancement of thermoelectric material by composite and its mechanism investigation

Research Project

Project/Area Number 24560835
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Composite materials/Physical properties
Research InstitutionChiba University

Principal Investigator

LU Yun  千葉大学, 工学(系)研究科(研究院), 准教授 (50251179)

Co-Investigator(Kenkyū-buntansha) ITOI Takaomi  千葉大学, 工学研究科, 准教授 (50333670)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords複合効果 / 複合熱電材料 / 複合則 / 有効媒質理論 / 有限要素法 / 熱電材料 / 複合 / 酸化物 / 金属複合 / FEM / 複合モデル
Outline of Final Research Achievements

In this project, analysis by finite element method (FEM) and experimental investigation of composite thermoelectric materials were performed from the view of approach of the microstructure controlling for enhancing performance of thermoelectric materials by increasing electric conductivity, decreasing/keeping thermal conductivity and increasing thermopower. From the results, the electric conductivity, Seebeck coefficient and thermal conductivity are all able to be analyzed by the developed FEM model for composite thermoelectric materials. The electric conductivity was decreased by increasing the volume fraction of the composite metal in any of the FEM analysis and the experimental results. Also, volume fraction of the composite metal, in which the semiconductor behavior can be kept, decreased with temperature increase. The composite thermoelectric materials with high performance were obtained by the interaction between the factors and the mechanism was discassed.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (31 results)

All 2015 2014 2013 2012 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (12 results) (of which Invited: 1 results) Remarks (6 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Cu/TiO2-x複合熱電材料の特性解析-有限要素法および実験による高性能化の検討-2014

    • Author(s)
      相楽勝裕, 魯 云, 野末貴裕, 小椋 慧, 吉田浩之, 浅沼 博
    • Journal Title

      材料の科学と工学

      Volume: 51 Pages: 99-106

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ti1-xCrxOzの作製およびその組織と熱電特性の解析2014

    • Author(s)
      相楽勝裕, 魯 云, 菊池優汰, 小椋 慧, 吉田浩之, 浅沼 博
    • Journal Title

      日本金属学会誌

      Volume: 78 Pages: 109-116

    • NAID

      130004456414

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Improvement of Thermoelectric Properties of CuAlO2 by Excess Oxygen Doping in Annealing2013

    • Author(s)
      Yun Lu, Kazunari Maeda, Katsuhiro Sagara, Liang Hao and Yingrong Jin
    • Journal Title

      Materials Science Forum

      Volume: 750 Pages: 134-137

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] FEM Analysis on Thermoelectric Properties of Metal/TiO2 Composites with Random Metal Powder Distribution2013

    • Author(s)
      Katsuhiro Sagara, Yun Lu and Daocheng Luan
    • Journal Title

      Materials Science Forum

      Volume: 750 Pages: 130-133

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Cu powder addition on thermoelectric properties of Cu/TiO2-x composite2013

    • Author(s)
      Yun Lu, Katsuhiro Sagara, Yusuke Matsuda, Liang Hao, Yingrong Jin and Hiroyuki Yoshida
    • Journal Title

      Ceramics International

      Volume: 39 Pages: 6689-6694

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Improvement in Thermoelectric Properties of Non-Stoichiometric Titanium Dioxide by Reduction Treatment2013

    • Author(s)
      Yun Lu, Liang Hao, Katsuhiro Sagara, Hiroyuki Yoshida and Yingrong Jin
    • Journal Title

      Materials Transactions

      Volume: 54 Pages: 1981-1985

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Cu powder addition on properties of Cu/TiO2-x composite thermoelectric materials2013

    • Author(s)
      Yun Lu, Katsuhiro Sagara, Yusuke Matsuda, Liang Hao, Yingrong Jin and Hiroyuki Yoshida
    • Journal Title

      Ceramics International

      Volume: In press

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] FEM Analysis on Thermoelectric Properties of Metal/TiO2 Composites2013

    • Author(s)
      Katsuhiro Sagara, Yun Lu and Daocheng Luan
    • Journal Title

      Materials Science Forum

      Volume: 750 Pages: 130-133

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Improvement of thermoelectric properties of CuAlo2 by excess oxygen doping in annealing2013

    • Author(s)
      Yun Lu, Kazunari Maeda, Katsuhiro Sagara, Liang Hao and Yingrong Jin
    • Journal Title

      Materials Science Forum

      Volume: 750 Pages: 134-137

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] 有限要素法を用いた複合熱電材料の特性解析2012

    • Author(s)
      相楽勝裕,魯 云,松田雄大
    • Journal Title

      日本金属学会誌

      Volume: 76 Pages: 508-514

    • NAID

      10030953946

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Non-stoichiometric Titanium Dioxide by Spark Plasma Sintering and Its Thermoelectric Properties2012

    • Author(s)
      Yun Lu, Katsuhiro Sagara, Liang Hao, Ziwu Ji and Hiroyuki Yoshida
    • Journal Title

      Materials Transactions

      Volume: 53 Pages: 1208-1211

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Today and future trend on research and development of materials for new energy and environment - Thermoelectric and photocatalyst materials -2015

    • Author(s)
      Yun LU
    • Organizer
      International Forum for advanced materials
    • Place of Presentation
      Chengdu, China
    • Year and Date
      2015-09-12
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] SPSとin-situ還元によるナノTiO2-x熱電材料の作製とその熱電特性2015

    • Author(s)
      小椋 慧、魯 云、菊池 優汰、遠山 雄太、河原田 将史、吉田 浩之
    • Organizer
      日本金属学会2015年春期大会
    • Place of Presentation
      東京
    • Year and Date
      2015-03-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] 2族元素ドーピングしたCuAlO2熱電材料の作製と高性能化2014

    • Author(s)
      魯 云、野末貴裕、相楽勝裕、音光貴仁、吉田浩之
    • Organizer
      日本金属学会2014年春期大会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] Thermoelectric properties of Ni/TiO2-x composites2013

    • Author(s)
      Yun Lu, Katsuhiro Sagara, Yusuke Matsuda, Liang Hao, Hiroyuki Yoshida, Jin Xiang Chen
    • Organizer
      The 19th International Conference on composite materials (ICCM-19)
    • Place of Presentation
      Montreal (Canada)
    • Related Report
      2013 Research-status Report
  • [Presentation] Rule of mixture for composite thermoelectrics2013

    • Author(s)
      Yun Lu, Katsuhiro Sagara, Liang. Hao, Hiroyuki Yoshida, Zi Wu. Ji, Fan Sheng Pan
    • Organizer
      The 19th International Conference on composite materials (ICCM-19)
    • Place of Presentation
      Montreal (Canada)
    • Related Report
      2013 Research-status Report
  • [Presentation] 高密度CuAlO2酸化物熱電材料の作製と性能評価2013

    • Author(s)
      野末貴裕,魯 云,相楽勝裕,小椋慧,吉田浩之
    • Organizer
      第57回日本学術会議材料
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
  • [Presentation] 配向処理・高密度化によるCuAlO2熱電材料の創製と高性能化2013

    • Author(s)
      魯 云、神島 弾、相楽勝裕、野末貴裕、吉田浩之、浅沼 博
    • Organizer
      日本機械学会第21回機械材料・材料加工技術講演会(M&P2013)
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] 有限要素法を用いたMetal/TiO2-x複合熱電材料の性能の温度依存性の解析2013

    • Author(s)
      相楽勝裕、魯 云、松田雄大、吉田浩之
    • Organizer
      第4回日本複合材料合同会議(JCCM-4)
    • Place of Presentation
      東京
    • Related Report
      2012 Research-status Report
  • [Presentation] 配向CuAlO2の作製と熱電特性2013

    • Author(s)
      神島 弾、野末貴裕、魯 云、吉田浩之、相楽勝裕
    • Organizer
      日本金属学会2013年春期大会
    • Place of Presentation
      東京
    • Related Report
      2012 Research-status Report
  • [Presentation] FEM Analysis on Thermoelectric Properties of Metal/TiO2 Composites2012

    • Author(s)
      Katsuhiro Sagara, Yun Lu and Daocheng Luan
    • Organizer
      The 8th International Forum on Advanced Materials Scienceand Technology
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Effect of Cu powder addition on properties of Cu/TiO2-x composite thermoelectric materials2012

    • Author(s)
      Yun Lu, Katsuhiro Sagara, Yusuke Matsuda, Liang Hao, Yingrong Jin and Hiroyuki Yoshida
    • Organizer
      15th European Conference on Composite Materials (ECCM 15)
    • Place of Presentation
      Venice, Italy
    • Related Report
      2012 Research-status Report
  • [Presentation] 有限要素法による複合熱電材料の性能に及ぼす温度影響の解析2012

    • Author(s)
      相楽勝裕、魯 云、松田雄大、吉田浩之
    • Organizer
      第56回日本学術会議材料工学連合講演会
    • Place of Presentation
      京都
    • Related Report
      2012 Research-status Report
  • [Remarks] 千葉大学工学研究科材料工学研究室

    • URL

      http://apei.tu.chiba-u.jp/Luyun-HP.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 千葉大学工学研究科教員総覧

    • URL

      http://www.eng.chiba-u.ac.jp/outProfile.tsv?no=1026

    • Related Report
      2014 Annual Research Report
  • [Remarks] 千葉大学工学研究科材料工学研究室

    • URL

      http://apei.tu.chiba-u.jp/Luyun-HP.html

    • Related Report
      2013 Research-status Report
  • [Remarks] 千葉大学工学研究科教員総覧

    • URL

      http://www.eng.chiba-u.ac.jp/outProfile.tsv?no=1026

    • Related Report
      2013 Research-status Report
  • [Remarks] 千葉大学工学研究科材料工学研究室

    • URL

      http://apei.tu.chiba-u.jp/Luyun-HP.html

    • Related Report
      2012 Research-status Report
  • [Remarks] 千葉大学工学研究科教員総覧

    • URL

      http://www.eng.chiba-u.ac.jp/outProfile.tsv?no=1026

    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] 熱電変換材料及びその製造方法2014

    • Inventor(s)
      魯 云, 相楽勝裕, 菊池優汰, 吉田浩之、浅沼 博
    • Industrial Property Rights Holder
      魯 云, 相楽勝裕, 菊池優汰, 吉田浩之、浅沼 博
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-038954
    • Filing Date
      2014-04-01
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 熱電変換材料及びその製造方法2014

    • Inventor(s)
      魯 云, 相楽勝裕, 菊池優汰, 吉田浩之、浅沼 博
    • Industrial Property Rights Holder
      千葉大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-03-28
    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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