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White oxide coating on titanium alloys having high exfoliation resistance

Research Project

Project/Area Number 24560857
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionUniversity of Hyogo

Principal Investigator

MIURA-FUJIWARA Eri  兵庫県立大学, 工学(系)研究科(研究院), 准教授 (70315258)

Co-Investigator(Kenkyū-buntansha) OBATA Akiko  名古屋工業大学, 工学研究科, 助教 (40402656)
YAMASAKI Tohru  兵庫県立大学, 工学研究科, 教授 (30137252)
Co-Investigator(Renkei-kenkyūsha) KIKUCHI Takeyuki  兵庫県立大学, 工学研究科, 准教授 (50316048)
WATANABE Yoshimi  名古屋工業大学, 工学研究科, 教授 (50231014)
KASUGA Toshihiro  名古屋工業大学, 工学研究科, 教授 (30233729)
NIINOMI Mitsuo  東北大学, 金属材料研究所, 教授 (50126942)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywordsチタン合金 / バイオマテリアル / 歯科補綴材料 / 界面強度 / コーティング / 酸化物 / 界面制御 / 生体材料 / 歯科材料 / 審美性 / 高温酸化 / 傾斜機能
Outline of Final Research Achievements

In addition to the strength or living body safety, the recovery of the appearance is also important for the charge for dentistries of the hard tissue alternate material. In this study, white oxidized-film was fabricated on CP Ti, which is used for dentistries, and Ti-Nb-Ta-Zr alloys, which is developed for biomedical use. The oxide film formation conditions, color tone, peel resistance, cellular affinity of the film were investigated. Based on the obtained experimental results, oxidation mechanisms were also discussed. Finally, test models such as a crown, denture base, and orthodontic arch wire were fabricated using this technique.
Any Ti alloy was able to form the white film which consisted of rutile type TiO2 as the main composition on the alloy surface by the treatment. The white film had about the same adhesiveness as epoxy adhesive, the whiteness was equivalent to the Japanese crown colour, or the value of the further was acquired.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (23 results)

All 2015 2014 2013 2012 Other

All Journal Article (5 results) (of which Peer Reviewed: 4 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (15 results) (of which Invited: 4 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] Color Tone and Interfacial Microstructure of White Oxide Layer on CP Ti and Ti-Nb-Ta-Zr Alloys2014

    • Author(s)
      Eri Miura-Fujiwara, Keisuke Mizushima, Yoshimi Watanabe, Toshihiro Kasuga, and Mitsuo Niinomi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 11S Pages: 1-8

    • DOI

      10.7567/jjap.53.11rd02

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 白い金属-Ti-Nb-Ta-Zr 合金の高温酸化皮膜による白色化の検討-2014

    • Author(s)
      三浦永理
    • Journal Title

      チタン

      Volume: 62 Pages: 286-292

    • NAID

      40020242936

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] White-ceramic conversion on Ti-29Nb-13Ta-4.6Zr surface for dental applications2013

    • Author(s)
      Akiko Obata, Eri Miura-Fujiwara, Akimitsu Shimizu, Hirotaka Maeda, Masaaki Nakai, Yoshimi Watanabe, Mitsuo Niinomi, Toshihiro Kasuga
    • Journal Title

      Advances in Materials Science and Engineering

      Volume: 1

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Aesthetic and Mechanical Properties of Oxide Coated Ti-Nb-Ta-Zr Alloys as a Dental Material2013

    • Author(s)
      Eri Miura-Fujiwara, Keisuke Mizushima, Soichiro Yamada, Yoshimi Watanabe, Toshihiro Kasuga, Mitsuo Niinomi, Tohru Yamasaki
    • Journal Title

      Proceedings of PRICM8

      Volume: 1 Pages: 1543-1550

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Oxidation behavior and effect of layer thickness on whiteness and exfoliation behavior of oxide film formed on Ti-Nb-Ta-Zr alloy2012

    • Author(s)
      E. Miura-Fujiwara, S. Yamada, A. Obata, H. Sato, Y. Watanabe, T. Kasuga and M. Niinomi
    • Journal Title

      Proceedings of Ti-2011 conference

      Volume: 3 Pages: 2116-2120

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Color tone and exfoliation resistance of white oxide layer formed on Ti-Nb-Ta-Zr alloys2015

    • Author(s)
      Eri Miura-Fujiwara, Yoshimi Watanabe, Toshihiro Kasuga, Mitsuo Niinomi
    • Organizer
      2015 TMS Annual Meeting & Exhibition
    • Place of Presentation
      Walt Disney World Swan and Dolphin Resort, Orlando, FL USA
    • Year and Date
      2015-03-14 – 2015-03-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ti合金の白色皮膜による色調制御と耐剥離性2014

    • Author(s)
      三浦永理
    • Organizer
      日本金属学会・日本鉄鋼協会中国四国支部 第120回 金属物性研究会
    • Place of Presentation
      香川大学
    • Year and Date
      2014-10-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Ti-Nb-Ta-Zr合金の白色化による審美性の改善2014

    • Author(s)
      三浦永理,渡辺義見,春日敏宏,新家光雄
    • Organizer
      東北大学金属材料研究所共同研究ワークショップ日本バイオマテリアル学会東北ブロック講演会,産官学連携による金属系バイオマテリアルの研究開発の最前線
    • Place of Presentation
      東北大学金属材料研究所
    • Year and Date
      2014-10-06 – 2014-10-07
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Ti-Nb-Ta-Zr合金ワイヤの白色化と曲げ変形能への酸素の影響2014

    • Author(s)
      三浦永理,奥林宏彰,渡辺義見,春日敏宏,新家光雄
    • Organizer
      2014年日本金属学会秋期講演大会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 「白い金属」:安全で目立ちにくい歯科矯正・補綴材料2014

    • Author(s)
      三浦永理
    • Organizer
      イノベーションジャパン2014
    • Place of Presentation
      東京ビッグサイト
    • Year and Date
      2014-09-11 – 2014-09-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ti-29Nb-13Ta-4.6Zr合金高温酸化被膜の色調と剥離強度2014

    • Author(s)
      三浦永理,渡辺義見,春日敏宏,新家光雄
    • Organizer
      第25回新構造・機能制御と傾斜機能材料シンポジウム
    • Place of Presentation
      郡山ユラックス熱海
    • Year and Date
      2014-07-10 – 2014-07-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Color tone, Peeling stress and interfacial microstructure of white oxide layer on Ti-Nb-Ta-Zr alloys2014

    • Author(s)
      E. Miura-Fujiwara, Akiko Obata, Yoshimi Watanabe, Toshihiro Kasuga, Mitsuo Niinomi, Tohru Yamasaki
    • Organizer
      ISPlasma2014
    • Place of Presentation
      名城大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Ti-Nb-Ta-Zr合金酸化膜の被膜剥離強度と界面組織2013

    • Author(s)
      三浦永理,水嶋恵介,塚本英明,佐藤尚,渡辺義見,春日敏宏,新家光雄
    • Organizer
      第124回軽金属学会講演会
    • Place of Presentation
      富山大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Aesthetic and mechanical properties of oxide coated Ti-Nb-Ta-Zr alloy as a dental material2013

    • Author(s)
      E. Miura-Fujiwara, K. Mizushima, S. Yamada, Y. Watanabe, T. Kasuga, M. Niinomi
    • Organizer
      PRICM8
    • Place of Presentation
      Waikoloa, HI, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] Aesthetic and Mechanical properties of oxide coating on Ti-Nb-Ta-Zr Alloys as a dental material2013

    • Author(s)
      E. Miura-Fujiwara, A. Obata, Y. Watanabe, T. Kasuga, M. Niinomi
    • Organizer
      Thermec2013
    • Place of Presentation
      Las Vegas, NV, USA
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Ti-Nb-Ta-Zr合金高温酸化膜の界面組織と密着強度2013

    • Author(s)
      三浦永理,水嶋恵介,山田宗一郎,塚本英明,佐藤尚,渡辺義見,春日敏宏,新家光雄
    • Organizer
      日本金属学会春期大会
    • Place of Presentation
      東京理科大神楽坂キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] CP Ti ならびにTi-Nb-Ta-Zr合金の酸化皮膜形成による審美性向上と剥離強度に関する研究2012

    • Author(s)
      水嶋恵介,三浦永理,菊池丈幸,山崎徹,渡辺義見,春日敏宏,新家光雄
    • Organizer
      日本金属学会秋期大会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Oxidation Behavior and Evaluations of Aesthetic and Mechanical Properties of Oxide Coating on Ti-base Biomedical Alloy2012

    • Author(s)
      Eri Miura-Fujiwara, Yoshimi Watanabe, Toshihiro Kasuga, Mitsuo Niinomi
    • Organizer
      Materials Science and Engineering (MSE2012)
    • Place of Presentation
      Darmstadt Germany
    • Related Report
      2012 Research-status Report
  • [Presentation] CP Tiおよび TNTZの表面酸化膜の色調に及ぼす熱処理条件の影響2012

    • Author(s)
      三浦永理,水嶋恵介,渡辺義見,春日敏宏,新家光雄
    • Organizer
      軽金属学会秋期大会
    • Place of Presentation
      千葉工大津田沼キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] 生体用Ti系材料の複合化による機能性改善-ポーラスTiと白色被膜コーティング

    • Author(s)
      三浦永理
    • Organizer
      本鉄鋼協会・日本金属学会関西支部 材料開発研究会 平成24年度第2回研究会
    • Place of Presentation
      関西大学吹田キャンパス
    • Related Report
      2012 Research-status Report
    • Invited
  • [Book] Chapter; Functionally Graded Metallic Biomaterials(Advances in Metallic Biomaterials Technology)2015

    • Author(s)
      Yoshimi Watanabe, Hisashi Sato, Eri Miura-Fujiwara
    • Total Pages
      28
    • Publisher
      Springer Beijing
    • Related Report
      2014 Annual Research Report
  • [Remarks] Home page of Eri Miura-Fujiwara

    • URL

      http://www.eng.u-hyogo.ac.jp/msc/emiura/

    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] Composite material for dental prosthesis and method manufacturing the same2012

    • Inventor(s)
      三浦永理,山田宗一郎,渡辺義見,佐藤尚,春日敏宏,新家光雄
    • Industrial Property Rights Holder
      三浦永理,山田宗一郎,渡辺義見,佐藤尚,春日敏宏,新家光雄
    • Industrial Property Rights Type
      特許
    • Filing Date
      2012-09-04
    • Related Report
      2012 Research-status Report
    • Overseas

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Published: 2013-05-31   Modified: 2019-07-29  

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