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Analytical study on carbonaceous sensing layers to chemical impulses based on gas-sorption dynamics

Research Project

Project/Area Number 24560863
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionTokyo University of Technology

Principal Investigator

SUGIMOTO Iwao  東京工科大学, コンピュータサイエンス学部, 教授 (70350501)

Co-Investigator(Kenkyū-buntansha) TAKAHASHI Kazuhiko  同志社大学, 理工学部, 教授 (90332808)
Co-Investigator(Renkei-kenkyūsha) MURAMATSU Hiroshi  東京工科大学, 応用生物学部, 教授 (20373045)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords膜表面 / ガス吸着 / 感応膜 / 過渡応答 / 数理モデル / 表面 / 炭素質薄膜 / ニオイセンサ / ガス拡散シミュレーション / プローブ顕微鏡
Outline of Final Research Achievements

The surface potentials and interaction forces of chemical sensing layers have been evaluated by scanning probe microscopy, which can identify the shape-oriented changes induced by chemical impulses. The pectin-sputtered films composed of the densely packed columns have the amphiphilic characteristics with carbonaceous structure. These surface characters of the films are sensitively affected by the polar chemical species. Based on an electric equivalent circuit, impedance analysis revealed that the elasticity of the films has been increased by the sorption of polar species. On the contrary, the non-polar species tend to slightly change the surface characteristics. We can recognize that the sensor responses can be simulated by a combination of the sorption processes, such as a diffusion, adsorption, and solvation, using the structural parameters of the films.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (14 results)

All 2015 2014 2013 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Open Access: 2 results,  Acknowledgement Compliant: 4 results) Presentation (5 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Remarks on Parameter Estimation for Computational Model of Plasma-Organic-Polymer-Film-Coated QCR Sensor2015

    • Author(s)
      Kazuhiko Takahashi, Ryousuke Kita, Iwao Sugimoto
    • Journal Title

      Proceedings of the 3rd International Conference on Industrial Application Engineering 2015

      Volume: - Pages: 234-238

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Scanning Probe Microscopy Analysis of the Adsorption of Volatile Organic Compounds on Carbonaceous Films with Microcolumnar Structure2015

    • Author(s)
      Iwao Sugimoto, Yoriko Suda, Hiroshi Muramatsu, Kazuhiko Takahashi
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 13 Issue: 0 Pages: 195-200

    • DOI

      10.1380/ejssnt.2015.195

    • NAID

      130005066303

    • ISSN
      1348-0391
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Low-Vacuum Deposition of Glutamic Acid and Pyroglutamic Acid: A Facile Methodology for Depositing Organic Materials beyond Amino Acids2014

    • Author(s)
      Iwao Sugimoto, Shunsaku Maeda, Yoriko Suda, Kenji Makihara,Kazuhiko Takahashi
    • Journal Title

      Journal of Amino Acids

      Volume: - Pages: 1-10

    • DOI

      10.1155/2014/434056

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Computational Model of Plasma-Organic-Polymer-Film-Coated QCR Sensor For Analysing Its Dynamic Response2014

    • Author(s)
      Kazuhiko Takahashi, Naoki Nishiwaki, Iwao Sugimoto
    • Journal Title

      Proceedings of the 8th International Conference on Sensing Technology

      Volume: - Pages: 85-88

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Computational Analysis of the Dynamics of Plasma-Organic-Polymer-Film-Coated QCR Sensors Using Numerical Inversion of a Laplace Transform2014

    • Author(s)
      Kazuhiko. Takahashi, Yoshie Kawanobe, Iwao Sugimoto
    • Journal Title

      Proceedings of the Second International Conference on Computing, Measurement, Control and Sensor Network

      Volume: -

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Remarks on a Computational Model of a Mass-Sensitive Chemical Sensor with Plasma-Organic-Polymer-Film-Coated Quartz Crystal Resonators'2014

    • Author(s)
      Kazuhiko Takahashi, Yoshie Kawanobe, Naoki Nishiwaki, Iwao Sugimoto
    • Journal Title

      Proceedings of 2014 IEEE/SICE International Symposium on System Integration

      Volume: - Pages: 558-563

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Analysis of dynamic response of plasma polymer film-coated quartz crystal resonator sensor2013

    • Author(s)
      Kazuhiko Takahashi, Yusuke Iwamuro, Iwao Sugimoto
    • Journal Title

      International Journal of Applied Electromagnetics and Mechanics

      Volume: 41 Issue: 1 Pages: 39-49

    • DOI

      10.3233/jae-121625

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 炭素質ガス吸着膜における表面電位の過渡現象 炭素質ガス吸着膜における表面電位の過渡現象 炭素質ガス吸着膜における表面電位の過渡現象2015

    • Author(s)
      須田順子、杉本岩雄、村松宏、高橋和彦
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学(神奈川県平塚市)
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Scanning Probe Microscopy Analysis of Volatile Organic Compounds on Carbonaceous Films with a Microcolumar Layer2014

    • Author(s)
      Iwao Sugimoto, Yoriko Suda, Hiroshi Muramatsu, Kazuhiko Takahashi
    • Organizer
      The 7th International Symposium on Surface Science
    • Place of Presentation
      くにびきメッセ(島根県松江市)
    • Year and Date
      2014-11-02 – 2014-11-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] 表面電位顕微鏡 KFM によるガス吸着現象の解明2014

    • Author(s)
      須田順子、杉本岩雄、村松宏、高橋和彦
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス(神奈川県)
    • Related Report
      2013 Research-status Report
  • [Presentation] ペクチン由来炭素質薄膜の吸着試験による表面形状の変化

    • Author(s)
      須田 順子,杉本 岩雄,牧原 健二
    • Organizer
      第60 回応用物理学会春季学術講演
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] プローブ顕微鏡による有機スパッタ膜の表面吸着水の評価

    • Author(s)
      大林 正史,杉本 岩雄, 須田 順子
    • Organizer
      第60 回応用物理学会春季学術講演
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Book] Human Olfactory Displays and Interfaces2013

    • Author(s)
      Iwao Sugimoto, Michiko Seyama (Takamichi Nakamoto ed.)
    • Publisher
      IGI Global
    • Related Report
      2012 Research-status Report
  • [Remarks] 東京工科大学コンピュータサイエンス学部杉本研究室HP

    • URL

      http://www2.teu.ac.jp/sugimoto/

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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